The Interannual Variation of Transboundary Contributions from Chinese Emissions of PM_(2.5) to South Korea

In recent years,several studies pointed out that anthropogenic emission sources in China which significantly contribute to the PM_2.5mass burden was an important cause of particulate pollution in South Korea.However,most studies generally focused upon a single pollution event.It is rare to see comprehensive research that captures those features prone to interannual variations concerning the transboundary pollutant contribution in South Korea using a unified method.In this paper,we establish the emission inventories covering East Asia in 2010,2015,and 2017,and then conduct the source apportionment by applying a coupled regional air quality model called the Integrated Source Apportionment Module(ISAM).Comparison of simulated and observed PM_2.5mass concentration at 165 CNEMC(China National Environmental Monitoring Center)sites suggests that the PM_2.5concentrations are well represented by the modeling system.The model is used to quantitatively investigate the contribution from emission sources in China to PM_2.5concentrations over South Korea and those features found to be prone to interannual variations are then discussed.The results show that the average annual contribution of PM_2.5has dropped significantly from 28.0%in 2010 to 15.7%in 2017,which strongly suggests that China has achieved remarkable results in the treatment of atmospheric particulates.     

梁柱组合节点的拟动力试验研究

本文主要介绍了所开展的梁柱组合节点的拟动力试验,梁柱连接采用高强度螺栓平端板形式。试验采用经过调幅的具有不同地震加速度峰值的Ispara地震动作为激励进行加载,对试件在地震作用下的加速度反应、位移反应、滞回性能、刚度和耗能进行分析,对试验现象和结果进行了比较详细的阐述和分析。     

Post-depositional modification of NO-3 in snow layers at EastAntarctica and at the headwater of ürumqi River

Acidic species, such as Nitrate, in polar snow and firn layers are “reversibly” deposited, and are sufficiently volatile to undergo significant postdepositional exchange between snow/firn and the atmosphere. Through comparison of the snowpit and snowpack nitrate concentrations from central East Antarctica and the headwater of ürumqi River, we conclude that the nitrate peaks in the uppermost surface snow layers in central Antarctica are not related to an atmospheric signal and must account for post-depositional effects. Such effects, however, are not found in the surface snowpack nitrate profiles from the headwater of ürumqi River. Two reasons may account for the post-depositional difference. At first, nitrate in the polar snow and firn layers appears to be hydrated ion, which can be taken up by the atmosphere, while at the headwater of ürumqi River it seems mainly as mineral ion, which assembles the behavior of aerosol-derived species that are “irreversibly” deposited and do not undergo significant post-depositional exchange with the atmosphere. Secondly, the chemical features of the snow and ice on the Antarctica are mainly determined by wet deposition, to the contrary, dry deposition is more significant at the headwater of lUrumqi River than that on the East Antarctic Plateau.     

面向多分辨率DEM的河网相似性测度与分析

河网是地形结构的核心要素,能够有效地反映DEM对地表形态的刻画能力.实现不同分辨率条件下DEM河网相似性测度对DEM地形综合、DEM质量评估及DEM不确定性分析等研究具有重要意义.基于此,本文以黄土高原典型样区为研究区,基于5 m高精度DEM建立的多分辨率DEM数据集,构建了地形特征自适应的DEM河网自动提取方法,建立...     

黄河流域气候水分盈亏时空格局分析

以中国气象局整编的1961~2001 年的气象资料为数据基础,采用联合国粮食及农业组织(FAO)1998 年推荐使用的Penmanmonteith模型,并以GIS技术为手段进行黄河流域气候水分盈亏的时空分布格局分析。结果表明：黄河流域干旱缺水是一种普遍现象,气候水分盈亏量在空间上总的变化规律表现为自南向北、自东向西气候水分亏缺量呈逐渐增大趋势,大部分地区全年气候水分亏缺量介于200~600 mm之间;就季节分布而言,水分亏缺的主要时期在春季和初夏,亏缺量一般在180~300 mm之间;就典型站点气候水分盈亏量逐月变化而言,存在着区域差异。研究结果和结论对区域充分发挥水分利用效率、发展高效节水农业具有重要意义。     

Deformation Mechanism and Stability of a Rocky Slope

A high slope is located on the side of the spillway at a hydropower station in Southwest China, which has some weak inter-layers inclining outwards. Parts of the slope show heavy weathering and unloading. There appeared deformation and tensile crack either on the surface or on the afteredge of the slope during excavation, and under a platform （elev. 488 m）, two levels of slopes collapsed on the downriver side. Based on the investigation in situ and the analysis of the geological structure, the conceptual model of deformation and failure mechanism was erected for this slope. Furthermore, the deformation characteristics were studied with FLAC^3D numerical simulation. Comprehensive analysis shows that the whole deformation of the slope is unloading rebound in certain depth scope and the whole body does not slide along any weak interlayer. In addition, two parts with prominent local deformation in the shallow layer of the slope show the models of ＂creep sfiding-tensile cracking＂ and ＂slidlng-tensile cracking＂, respectively. Based on the above analysis, the corresponding project of support and reinforcement is proposed to make the slope more stable.     

Pretreatment of high strength waste emulsions by combined vibratory shear enhanced process with Fenton oxidation

Pretreatment of waste emulsions with high organic content by a combined process of vibratory shear enhanced process and Fenton’s oxidation prior to biological treatment was investigated. Vibrating membrane had shown good performance in chemical oxygen demand and oil removals and the mitigation of concentration polarization. However, the permeate after filtration processing still contained high content of organics. Thus, additional Fenton oxidation was applied to reduce the organic loading, and improve the biodegradability of the wastewater. The optimal molar ratio of ferrous iron to hydrogen peroxide was 0.05 obtained from the jar-test experiments. Removal of organics was enhanced by increasing hydrogen peroxide dosage, while efficiency of hydrogen peroxide reached maximum of 1.11(w/w) at the hydrogen peroxide dosage of 6.8 g/L. Furthermore, the biological experiments indicated that the high concentration of organics could inhibit microbial activity, which decreased the chemical oxygen demand degradation rates. The adaptive period of the microbe was greatly shortened using Fenton’s reagent at the low dosages. The improvement of the biodegradability could be explained by partial mineralization and chemical transformation of parent organic compounds after Fenton oxidation.     

新显色剂5—（4—溴苯偶氮）—8—羟基喹啉与钴（Ⅱ）显色反应的？…

研究了新显色剂 5 -(4-溴苯偶氮 ) -8-羟基喹啉 (BAHQ)与钴 (Ⅱ )形成配合物的条件。试验表明 ,该显色剂的离解常数pKa1 ,pKa2 分别为 1.80 ,7.90。BAHQ与钴 (Ⅱ )形成配合物的最大吸收峰在 483nm处。钴 (Ⅱ )浓度在 0～ 16 μg/ 2 5mL范围内符合比耳定律 ,表观摩尔吸光系数ε483 =5 .10× 10 4L·mol- 1 ·cm- 1 ,对比度△λ =88nm。考查了二十多种离子的干扰情况 ,用于测定维生素B1 2 药品中的钴 ,结果满意     

Rare—Earth Element Geochemistry of Elogites from the Ultra—High Pressure Metamorphic Belt in Central China

Based on their REE contents and REE patterns,eclogites from the ultra-high pressure metamorphic belt in central China may be roughly divided into xis types including LREE-rich.LREE-rich positive Eu anomaly,LREE-rich negative Eu anomaly,REE pattern-smooth,MREE-rich and HREE-rich.The LREE_rich,LREE-rich positive Eu anomaly and LREE-rich negative Eu anomaly types of eclogites are dominant .REE types of eclogites in different areas can be compared and the REE feactures of the same REE type of eclogites in different areas are similar.The results of reconstruction of the primary rocks show that the primary rocks of eclogites possibly are dominated by continental tholeiites which are the product of partial melting of relatively fertile mantle and the rocks of tholeiite crystallization-differentiation.There is perfect evolution relationship among the primary rocks of the LREE-rich, LREE-rich positive Eu anomaly and LREE-rich negative Eu anomaly types of eclogites and among those of the REE pattern smooth and MREE-rich types of eclogites,the former three types were deried from continental settings and the latter two from nearly oceanic settings.Meanwhile,it is concluded that the mantle sources of primary rocks of the eclogites are inhomogeneous and the primary rocks of eclogites in this area appear to have undergone varying degree of crustal contamination.     

Lead isotope geochemical characteristics of Pb-Zn-Cu deposits on the southwestern margin of Tarim, and their significance

The polymetallic(Pb,Zn,Cu,etc) ore belt on the southwestern margin of Tarim is one of the major regions with the greatest prospecting potential in Xinjiang.Reported in this paper are the lead isotope data for 66 sulfide samples(including 50 galena samples,15 chalcopyrite samples and 1 pyrite sample) collected from such representative deposits as Tamu,Tiekelike,Kalangu,Abalieke,etc.in this ore belt.The Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb in the galena samples range from 17.931 to 18.176,15.609 to 15.818 and 38.197 to 38.944,with the average values of 18.017,15.684 and 38.462,respectively.Those in the chalcopyrite samples range from 17.926 to 18.144,15.598 to 15.628 and 38.171 to 38.583,with the average values of 18.020,15.606 and 38.262,respectively.The pyrite sample has the Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb to be 17.980,15.604 and 38.145,respectively.In combination with the previous Pb isotope data for sulfides,it is found that there is only a slight variation in the Pb isotopic composition of galena,chalcopyrite,sphalerite and pyrite in the ore belt.However,there is some difference in Pb isotopic characteristics between galena and chalcopyrite,especially the Pb isotopic composition of galena shows an obvious linear correlation with some other relevant parameters(e.g.β and γ).The comprehensive analysis suggested that lead in galena(maybe including sphalerite and pyrite) was derived principally from wall rocks and underlying basement,and that in chalcopyrite only originated from the basement.The single-stage model ages of these sulfides couldn’t indicate the time limit of metallogenesis(Pb,Zn,Cu,etc.),and the positive linear correlations for the Pb isotopic composition of galena are of no single-stage and two-stage Pb-Pb isochron significance.Furthermore,there are significant differences in Pb isotopic composition characteristics between the genetic type of deposits in this polymetallic ore belt and the Mississippi Valley type(MVT).In addition,the authors also pointed out that there is a phenomenon of differentiation(not paragenesis) for lead and copper elements during the process of metallogenesis in this ore belt.