The geochemistry of lead in rivers,estuaries and the continental shelf of the Southeastern United States

Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.     

Finite element formulation and algorithms for unsaturated soils. Part II: Verification and application

The finite‐element formulation and integration algorithms developed in Part I are used to analyse a number of practical problems involving unsaturated and saturated soils. The formulation and algorithms perform well for all the cases analysed, with the robustness of the latter being largely insensitive to user‐defined parameters such as the number of coarse time steps and error control tolerances. The efficiency of the algorithms, as measured by the CPU time consumed, does not depend on the number of coarse time steps, but may be influenced by the error control tolerances. Based on the analyses presented here, typical values for the error control tolerances are suggested. It is also shown that the constitutive modelling framework presented in Part I can, by adjusting one constitutive equation and one or two material parameters, be used to simulate soils that expand or collapse upon wetting. Treating the suction as a strain variable instead of a stress variable proves to be an efficient and robust way of solving suction‐dependent plastic yielding. Moreover, the concept of the constitutive stress is a particularly convenient way of handling the transition between saturation and unsaturation. Copyright © 2003 John Wiley & Sons, Ltd.     

Estuary/ocean exchange and tidal mixing in a Gulf of Maine Estuary: A Lagrangian modeling study

A Lagrangian particle method embedded within a 2-D finite element code, is used to study the transport and ocean–estuary exchange processes in the well-mixed Great Bay Estuarine System in New Hampshire, USA. The 2-D finite element model, driven by residual, semi-diurnal and diurnal tidal constituents, includes the effects of wetting and drying of estuarine mud flats through the use of a porous medium transport module. The particle method includes tidal advection, plus a random walk model in the horizontal that simulates sub-grid scale turbulent transport processes. Our approach involves instantaneous, massive [O(500,000)] particle releases that enable the quantification of ocean–estuary and inter-bay exchanges in a Markovian framework. The effects of the release time, spring–neap cycle, riverine discharge and diffusion strength on the intra-estuary and estuary–ocean exchange are also investigated.The results show a rather dynamic interaction between the ocean and the estuary with a fraction of the exiting particles being caught up in the Gulf of Maine Coastal Current and swept away. Three somewhat different estimates of estuarine residence time are calculated to provide complementary views of estuary flushing. Maps of residence time versus release location uncover a strong spatial dependency of residence time within the estuary that has very important ramifications for local water quality. Simulations with and without the turbulent random walk show that the combined effect of advective shear and turbulent diffusion is very effective at spreading particles throughout the estuary relatively quickly, even at low (1 m²/s) diffusivity. The results presented here show that a first-order Markov Chain approach has applicability and a high potential for improving our understanding of the mixing processes in estuaries.     

Whipple telescope observations of LS I +61 303: 2004–2006

In this paper we present the results of the past two years observations on the galactic microquasar LS I +61 303 with the Whipple 10 m gamma-ray telescope. The recent MAGIC detection of the source between 200 GeV and 4 TeV suggests that the source is periodic with very high energy (VHE) gamma-ray emission linked to its orbital cycle. The entire 50-hour data set obtained with Whipple from 2004 to 2006 was analyzed with no reliable detection resulting. The upper limits obtained in the 2005–2006 season covered several of the same epochs as the MAGIC Telescope detections, albeit with lower sensitivity. Upper limits are placed on emission during the orbital phases of 0→0.1 and 0.8→1, phases which are not included in the MAGIC data set.      

Seasonally Hypersaline Estuaries in Mediterranean-climate Regions

Data collected in three Californian estuaries indicate that hypersaline conditions exist during the dry summers typical of a Mediterranean climate. The generalised seasonal and longitudinal hydrographic structures are described and explained. It is argued that this seasonal hypersalinity is common and that it represents a major class of estuaries. The observed accumulation of salt indicates surprisingly long residence times in small basins which have free exchange with the ocean. This semi-isolation of the inner basin leads to a large build-up or severe depletion of nutrients, pollutants and plankton in these systems. Of concern are the trends to increase pollutant loading in the same systems that are experiencing an increase in residence times owing to freshwater extraction in the watershed.     

The onset of chaotic motion in the restricted problem of three bodies

A full characterization of a nonintegrable dynamical system requires an investigation into the chaotic properties of that system. One such system, the restricted problem of three bodies, has been studied for over two centuries, yet few studies have examined the chaotic nature of some ot its trajectories. This paper examines and classifies the onset of chaotic motion in the restricted three-body problem through the use of Poincaré surfaces of section, Liapunov characteristic numbers, power spectral density analysis and a newly developed technique called numerical irreversibility. The chaotic motion is found to be intermittent and becomes first evident when the Jacobian constant is slightly higher thanC ₂.