雾化进样石墨炉原子吸收光谱法的研究 Ⅰ.直接雾化进样装置及其性能

介绍一种自行设计和加工的直接雾化石墨炉进样装置的结构、工作原理和操作方法。该装置由微机控制与石墨炉加热程序同步工作,可以实现自动控制和自动测量。对雾化进样石墨炉分析的仪器参数和实验条件进行了研究和选择。结果表明,该装置与石墨炉结合具有自动化程度高、重现性好、样品利用率高和分析速度快等特点。     

Modelling the April 15 spectrum of Supernova 1993 J

We present the modeling of the ultraviolet and optical spectra obtained simultaneously on 1993 April 15 with the HST and at Lick Observatory. A Monte Carlo code is employed in the modeling and a comparison is made between models reported by different groups. With an atmosphere similar to the Sun in chemical composition, the observed spectral lines are well reproduced by a power law density structure of index around 20 except the strong H and HeI λ5876 lines which have peculiar absorption profiles. The photospheric velocity is found to be 9500 km/s and the blackbody temperature of the spectrum is 7990 K. For H and HeI λ5876, we suggest a two-component density structure which has a smoother layer located immediately outside the steeply decreasing inner envelope. The power law indices are most probably 20 and 3, respectively, with the transition point at about 13 000 km/s. In addition, this outer smooth layer serves to flatten the far UV spectrum as observed.     

A THREE-DIMENSIONAL ELASTIC NESTED-GRID MESO-(β-γ)SCALE ATMOSPHERIC MODEL——PARTI:MODEL DESCRIPTION

A three-dimensional elastic nonhydrostatic mesoscale(β-γ)model with nested-grid is presented.It uses a set of fullequations in terrain-following coordinates as its basic dynamic frame,which is solved with a time-splitting algorithmfor acoustic and gravity waves.The model physical parameterization includes a K-theory subgrid eddy mixing for cloudand free atmosphere,a bulk planetary boundary layer parameterization,and three types of sofisticated cloudmicrophysics schemes with double-parameters for hail-bearing clouds,warm clouds and snowing clouds respectively.The model is designed to be used flexibly for simulations of a variety of meso-and small-scale atmospheric processes,and can be improved as a regional and local operational NWP system in future.     

黄金的成色

黄金的成色并不是一成不变的，它成色的高低是与成矿温度、成矿阶段、深度、时代、变质程度、水溶液及风化作用等有一定关系，我们从这些关系中可以寻找到我们找矿的捷径和依据。     

Spine–sheath polarization structures in four active galactic nuclei jets

We present the results of multifrequency (15 + 8 + 5 GHz) polarization Very Long Baseline Array (VLBA) observations of the three BL Lacertae objects 0745+241, 1418+546 and 1652+398 together with 5-GHz VLBI Space Observatory Programme (VSOP) observations of 1418+546 and 1.6- and 5-GHz VSOP observations of the blazar 1055+018. The jets of all these sources have polarization structure transverse to the jet axis, with the polarization E vectors aligned with the jet along the jet spine and 'sheaths' of orthogonal E vectors at one or both edges of the jet. The presence of polarization aligned with the jet near the 'spine' may indicate that the jets are associated with helical B fields that propogate outward with the jet flow; the presence of orthogonal polarization near the edges of the jet may likewise be a consequence of a helical jet B field, or may be owing to an interaction with the ambient medium on parsec scales. We have tentatively detected interknot polarization in 1055+018 with E aligned with the local jet direction, consistent with the possibility that the jet of this source is associated with a helical B field.     

A kinetic model of gas flow in a porous cometary mantle

A numerical study of gas flow through a porous cometary mantle is presented. A kinetic model based on the well-known Test Particle Monte Carlo Method for the solution of rarefied gas dynamics problems is proposed. The physical model consists of two spatial plane regions: the condensed ice phase and a porous dust mantle. The structure of the porous dust layer is described as a bundle of cylindrical inclined channels not crossing each other. A vertical temperature gradient may exist across the dust mantle. The aim is to investigate how the characteristics of molecular flow depend on the capillary length, inclination angle, and temperature gradient. Examples illustrating a significant deviation of some results from equilibrium values are shown. In particular, the gas velocity distribution at both ends of the pore is strongly non-Maxwellian if there is an important temperature contrast across the pore. The emergent gas flow rate is found to vary with the pore length/radius ratio in excellent agreement with Clausing's empirical formula. The degree of collimation of the flow is quantitatively studied as a function of the length/radius ratio, and consequences for the jet force of outgassing through a dust mantle or, indeed, a rough surface are estimated.     

The production of light elements in unconventional cosmologies with VMOs

The abundances of light elements (deuterium, helium and lithium) are calculated in unconventional cosmologies in which these elements are produced by interaction of fast -particles ejected by massive pregalactic stars with a purely hydrogenous cosmological substrate. The number density and energetics of such stars needed for suitable production of light elements are estimated. It is shown that the models always lead to overproduction of lithium. The intensity of ultraviolet, X-ray, and -ray emission caused by explosions of pregalactic massive stars is calculated. The distortions of cosmic background radiation by Compton losses of electrons heated by explosive stars are also calculated.     

Hydrodynamical models of type II supernovae

A series of hydrodynamical models of type-II supernova outbursts (SNII) has been calculated. Approximate relations connecting the total outburst energy ε, the mass of envelope ejectedM, the presupernova radiusR, and the amount of ionizing quanta radiated by the supernovaeN _H with such values as the duration of the light curve plateau Δt, and absolute magnitude in the wavelength bandV and photospheric velocityU _PH observed near the middle of the plateau have been established. Advantage has been taken of the relations to obtain a preliminary evaluation for the characteristics of the average SN II: ε=7×10⁵⁰ erg,M=6M _⊙,R=500R _⊙,N _H=2×10⁵⁸. The SNIIs with plateau-like light curves seem to be accounted for by thermonuclear explosions of degenerate cores of red giant stars and result in a total disruption of the star without any stellar remnant. To the contrary, SNIIs with linear light curves have substantially different properties (in particular, they throw considerably less massive envelopes off). These SNII must signify the birth of collapsed objects—neutron stars (pulsars) or black holes.     

Possible chemical structures and biological precursors of different vitrinites in coal measure in Northwest China

Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state ¹³C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in ¹³C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in ¹³C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and ¹³C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite.     

Silica phase transformations in the petroliferous sequences

The joint evolution of organic matter and silica in petroliferous sequences is considered in the terms of the laws of transformation of dispersion systems. The dispersion systems are transformed under conditions of low-temperature solid-phase processes accompanied by the silica phase transition and dehydration that favors the evolution of organic matter.