Trace-element contents and cathodoluminescence of “trapiche” rubies from Mong Hsu, Myanmar (Burma): geological significance

Summary ?Mong Hsu rubies of the “trapiche” type are sporadically seen in the gem market. However, they have never been described in the field. The study of the nature of solid inclusions, the variation of trace-element contents, as well as the cathodoluminescence behaviour of six “trapiche” rubies permit the conclusion that these rubies crystallised in the same geological environment (marble-type deposit) as the normal rubies from Mong Hsu: (1) Cr and V are the main chromophorous elements in both ruby types; they act, together with Ti, as activators or quenchers for cathodoluminescence; (2) calcite, dolomite, rutile, mica, diaspore, apatite, chlorite, and feldspar are solid inclusions found in both ruby types; (3) the presence of bastn?site in trapiche ruby and fluorite in non-trapiche ruby indicates the circulation of F-bearing fluids during ruby deposition; (4) the distribution of trace-element contents in the crystal is similar for both ruby types. In the Cr₂O₃ vs. Fe₂O₃ and Cr₂O₃ vs. Fe₂O₃/TiO₂ diagrams, the population fields of Mong Hsu “trapiche” and non-“trapiche” rubies overlap. They are distinct from those of rubies and sapphires hosted in basalts from South-east Asia. Received October 30, 2001; revised version accepted March 25, 2002     

A 2000-YEAR CONTEXT FOR MODERN CLIMATE CHANGE

ABSTRACT. Although considerable attention has been paid to the record of temperature change over the last few centuries, the range and rate of change of atmospheric circulation and hydrology remain elusive. Here, eight latitudinally well-distributed (pole-equator-pole), highly resolved (annual to decadal) climate proxy records are presented that demonstrate major changes in these variables over the last 2000 years. A comparison between atmospheric ¹⁴C and these changes in climate demonstrates a first-order relationship between a variable Sun and climate. The relationship is seen on a global scale.     

A note on turbulent perturbations of salinity in a partially mixed estuary

Measurements of salinity perturbations in a partially mixed estuary have been used to evaluate the usefulness of an inductive salinometer and to determine some of the characteristics of the salinity perturbations. The salinometer performed satisfactorily under most conditions. Although internal wave like effects were present, the turbulence fluctuations were dominant. The salinity fluctuations and the turbulent fluxes $\text{sw}$ and $\text{su}$ were found to behave in a manner similar to the density fluctuations in a thermally stratified atmospheric boundary layer and a laboratory open channel flow. A quadrant analysis suggested that the contribution of each quadrant to the turbulent flux changed with Ri. The turbulence parameters ν and c_γ were found to decrease and increase respectively as Ri increases.     

Characterization of soil's structural crust by spectral reflectance in the SWIR region (1.2–2.5 μm)

Structural crust is a thin layer formed on the soil surface after a rainstorm. The crust is the result of a physical segregation and rearrangement of soil particles in a way that affects some of the soil properties, such as infiltration, runoff and soil erosion. In practice, there is no rapid, in situ method for monitoring, assessing and mapping crust intensity and quality. In this study, a controlled spectral investigation of the structural crust across the NIR–SWIR spectral region was conducted on three selected Israeli soils, to study the potential of reflectance radiation to detect structural crust in soils. Two major factors served as the driving forces for this study: (1) there is no valid method for in situ assessment of the crust's characteristics in the agriculture field, and (2) the crust might bias thematic remote sensing of soils, because the thin layer of crust blocks photon–matter interaction, which represents the relevant soil body. Through the use of a laboratory rainfall simulator and a sensitive spectrometer, it was revealed that for three selected soils, significant spectral differences occurred between the crust and its bulk soil. The spectral information was found to be related to changes in particle size distribution and texture at the surface of the soil. This conclusion was based on indications of absorption of OH in clay lattice, OH in adsorbed water and CO₃ in carbonates. It was concluded that the structural crust is a phenomenon that should not be ignored by remote-sensing users. In fact, in the field of agriculture, the spectral properties of crust can be used as tools for estimating the crust's intensity.     

Inverted echo sounder measurement of dynamic height through an ENSOcycle in the central equatorial Pacific

A four-year record from an inverted echo sounder deployed near Palmyra Island at 6°N in the central Pacific Ocean is compared with a simultaneous record of subsurface pressure from this island lagoon. A factor m, converting round-trip acoustic travel time to surface dynamic height relative to a deep pressure level, was estimated from the ratio of the spectra of the two records in the energetic synoptic oscillation band. Year-to-year variation in m was not statistically significant. For the overall record, m was found to be -70±8 dynamic m/s, where the error bounds represent a 90% confidence interval. This is consistent with first-baroclinic-mode excitation     

A time series analysis of sound propagation in a strongly multipathshallow water environment with an adiabatic normal mode approach

Measured time series were generated by small omnidirectional explosive sources in a shallow water area. A bottom-mounted hydrophone recorded sound signals that propagated over a sloping bottom. The time series in the 250-500 Hz band were analyzed with a broad-band adiabatic normal mode approach. The measured waveforms contain numerous bottom interacting multipaths that are complicated by the subbottom structure that contains high-velocity layers near the water-sediment interface. Several of the details of the geoacoustic structure and the depth of the water column at the receiver are inferred from comparisons of the measured data to simulated time series. The sensitivity of broad-band matched-field ambiguity surfaces in the range-depth plane for a single receiver to selected waveguide parameters is examined. A consistent analysis is made where the simulated time series are compared to the measured time series along with the single-receiver matched-field localization solutions for ranges out to 5 km. In this range interval, it was found that the peak cross-correlation between the measured and simulated time series varied between 0.84 and 0.69. The difference between the GPS range and the range obtained from the matched-field solution varied from 0 to 63 m. The geoacoustic structure obtained in the analysis consists of an 8-m low-velocity sediment layer over an 8-m high-velocity layer followed by a higher velocity, infinite half-space     

Evolution of 2:1 layered silicates in low-grade metamorphosed Liassic shales of Central Switzerland

White mica from the Liassic black shales and slates in Central Switzerland was analysed by transmission electron microscopy (TEM) and electron microprobe to determine its textural and compositional evolution during very low-grade prograde metamorphism. Samples were studied from the diagenetic zone, anchizone and epizone (T ≈100°–450 °C). Phyllosilicate minerals analysed include illite/smectite (I/S), phengite, muscovite, brammallite, paragonite, margarite and glauconite. Textural evolution primarily is towards larger, more defect-free grains with compositions that approach those of their respective end-members. The smectite-to-illite transformation reduced the amounts of the exchange components SiK_?1Al_?1, MgSiAl_?2, and Fe³⁺Al_?1. These trends continue to a lesser degree in the anchizone and epizone. Correlations between the proportion of smectite in I/S and the composition of I/S indicate that smectite layers may contain a high layer charge. Illite in I/S bears a compositional resemblance to macrocrystalline phengite in some samples, but is different in others. Paragonite first appears in the upper diagenetic zone or lower anchizone as an interlayer-deficient brammallite, and it may be mixed with muscovite on the nanometre scale. Owing to the small calculated structure factor for paragonite-muscovite superstructures, conventional X-ray powder diffraction cannot distinguish between mixed-layer structures and a homogeneous compositionally intermediate solid solutions. However, indirect TEM evidence shows that irregularly shaped domains of Na- and K-rich mica exist below 10 nm. Subsequent coarsening of domains at higher grades produced discrete paragonite grains at the margins of muscovite crystals or in laths parallel to the basal plane of the host muscovite. Margarite appears in the epizone and follows a textural evolution similar to paragonite in that mixtures of margarite, paragonite, and muscovite may initially occur on the nanometre scale. However, no evidence of interlayer-poor margarite has been found.     

Slumping and shallow faulting related to the presence of salt on the Continental Slope and Rise off North Carolina

Seismic reflection profiles and long- and medium-range sidescan sonar were used to investigate a salt diapir complex and area of slope instability near the base of the Continental Slope off North Carolina. Within the area of investigation three diapirs are bounded on their upslope side by a scarp 60 m high and 50 km long. The slope above the scarp is characterized by a series of shallow rotational normal faults. The bottom below the scarp is furrowed by slide tracks, which were probably carved by large blocks that broke off the scarp face and slid downslope leaving rubble and scree lobes.Extensive slumping in this area appears to be a result of uplift and faulting associated with salt intrusion, which has fractured and oversteepened the slope leading to instability and failure. Sharply defined slide tracks suggest that slope failure above the breached diapir complex is a continuing process, in contrast to much of the surrounding slope area where few instability features were observed.     

Volcanic style in the Strand Fiord Formation (Upper Cretaceous), Axel Heiberg Island, Canadian Arctic Archipelago

The Strand Fiord Formation is a volcanic unit of early Late Cretaceous age which outcrops on west-central and northwestern Axel Heiberg Island in the Canadian Arctic Archipelago. The formation is part of the thick Sverdrup Basin succession and immediately precedes the final basin foundering event. The Strand Fiord volcanics are encased in marine strata and thin southward from a maximum thickness of 789+ m on northwestern Axel Heiberg to a zero edge near the southern shore of the island. Tholeiitic icelandite flows are the main constituent of the formation with volcaniclastic conglomerates, sandstones, mudrocks and rare coal seams also being present. The lava flows range in thickness from 6 to 60 m and subaerial flows predominate. Both pahoehoe and aa lava types are common and the volcanic pile accumulated mostly by the quiet effusion of lavas. The volcaniclastic lithologies become more common near the southern and eastern edges of the formation and represent lahars and beach to shallow marine reworked deposits. The Strand Fiord volcanics are interpreted to represent the cratonward extension of the Alpha Ridge, a volcanic ridge that was active during the formation of the Amerasian Basin.