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混合捕收剂去除高岭土中含铁矿物试验研究
引用本文:夏光华,李晓鸣,苏小丽.混合捕收剂去除高岭土中含铁矿物试验研究[J].地质找矿论丛,2012,27(1):121-124.
作者姓名:夏光华  李晓鸣  苏小丽
作者单位:1. 景德镇陶瓷学院材料科学与工程学院,江西景德镇,333001
2. 北海兖矿高岭土有限公司,广西北海,536001
基金项目:江西省科技支撑重点项目(编号:2008AE00147)资助
摘    要:文章根据高岭土中含铁矿物的浮选试验研究,采用胺类与皂化油酸表面活性剂组合作为高岭土中含铁矿物的捕收剂。高岭土中铁的赋存状态表明,采用分段阳离子/阴离子捕收剂组合试剂,当pH=8~10时,十八胺乳化液以静电力吸附形式捕收含铁硅酸盐;当pH=5~7时,皂化油酸和少量十二烷基磺酸钠通过表面活化反应捕收氧化铁矿,使北海高岭土精矿自然白度达到85%~86%,煅烧白度(1 200℃)达到88%~89%。

关 键 词:高岭土  含铁矿物  浮选  混合捕收剂
收稿时间:2010/11/21 0:00:00

The experiment research on iron removal from kaolin by using mixed collecting agent
XIA Guang-hua , LI Xiao-ming , SU Xiao-li.The experiment research on iron removal from kaolin by using mixed collecting agent[J].Contributions to Geology and Mineral Resources Research,2012,27(1):121-124.
Authors:XIA Guang-hua  LI Xiao-ming  SU Xiao-li
Institution:1.School of Materials Science and Engineering,Jingdezhen Ceramic Institute, Jingdezhen 333001,Jiangxi,China;2.Yankuang Kaolin Co.,Ltd of Bei Hai, Beihai 536001,Guangxi,China)
Abstract:Flotation experiment of Fe-beaeing minerals in kaolin is carried out.Amine and and active agent of saponified oleic acid are combined to be used as collector.Occurrence analysis of iron shows that adoption of phased-cationic / anionic collector results in electrostatic adsorption of iron silicate by octadecylamine emulsion at pH=8-10 and capture of iron oxide by surface activation of saponified oleic acid-a small amount of sodium dodecyl sulfate at pH=5-7.Ultimately natural whiteness of the kaolin concentrates increases to 85%-86%,whiteness after calcination(1 200℃)to 88%-89%.
Keywords:kaolin  Fe-beaeing minerals  flotation process  mixed collector
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