地球化学异常再现性与可对比性

不同密度采样是否可以获得稳定的和可追索的地球化学模式是检验采样是否具有代表性，分析技术是否成熟的重要依据。笔者选择新疆哈密大南湖地区约6400km^2面积，进行了从超低密度(1个样／100km^2)，甚低密度(1个样／25km^2)直到低密度(1个样／4km^2)地球化学采样，对比了3种密度地球化学采样所获得的地球化学数据和异常分布模式。得出如下结论：超低密度、甚低密度、低密度地球化学调查获得的元素含量平均值和背景值非常接近；超低密度、甚低密度、低密度调查所圈定的地球化学省在形态上和变化趋势上非常相似，浓集中心的位置重合，表明不同调查阶段可获得稳定的和可追索的地球化学模式；采样密度越大数据离散程度越高，即最小值更小，最大值更大，表明元素分布的局部不均匀性，正是这种局部的不均匀性才能通过加密采样刻画出地球化学模式的细节变化，为逐步追踪矿化体奠定了基础；超低密度和甚低密度采样可以有效圈定矿集区所形成的大规模地球化学异常，低密度地球化学调查不仅可以圈定矿集区异常，同时可以圈定分散矿化的小规模局部异常。     

Large-sample hydrology: recent progress,guidelines for new datasets and grand challenges

ABSTRACT

Large-sample hydrology (LSH) relies on data from large sets (tens to thousands) of catchments to go beyond individual case studies and derive robust conclusions on hydrological processes and models. Numerous LSH datasets have recently been released, covering a wide range of regions and relying on increasingly diverse data sources to characterize catchment behaviour. These datasets offer novel opportunities, yet they are also limited by their lack of comparability, uncertainty estimates and characterization of human impacts. This article (i) underscores the key role of LSH datasets in hydrological studies, (ii) provides a review of currently available LSH datasets, (iii) highlights current limitations of LSH datasets and (iv) proposes guidelines and coordinated actions to overcome these limitations. These guidelines and actions aim to standardize and automatize the creation of LSH datasets worldwide, and to enhance the reproducibility and comparability of hydrological studies.     

纳米级微粒地球化学测量中异常重现性研究

纳米级微粒测量是寻找隐伏矿的新方法,选取实地模拟实验和在已知隐伏矿区,利用液态捕集剂和等离子体质谱分析测试样品,进行重复测量试验,研究结果表明,不同成矿元素,在地表形成异常的运移富集速率不同,其运移速率主要取决于纳米级微粒本身的地球化学性质,地下上升气流、断裂等裂隙有利于微粒的上升运移富集;纳米级微粒地球化学重复测量时,异常可具有良好的重现性,但异常重现较常规气体缓慢,通常需要2~3个月。     

祁连山天然气水合物地球化学勘查方法稳定性和异常重现性分析

根据祁连山木里地区已知天然气水合物上方不同期次近地表土壤地球化学勘查重复性试验,对土壤酸解烃、顶空气、荧光光谱、碳酸盐等指标方法的稳定性及异常重现性问题进行研究和探讨。结果表明,各项化探指标不同期次含量最大值等特征值虽然存在一定程度的差异,但是其数据波动特征和数据结构是相对一致的。顶空气甲烷、酸解烃、荧光光谱和碳酸盐方法指标前后两次测量结果均具有较高的相关性,配对T-检验显示顶空气轻烃、酸解烃和碳酸盐指标数据变化差异不显著,从统计学上看其指标数据具有较好的稳定性。顶空气甲烷、酸解烃、荧光光谱等指标地球化学异常在研究区已知天然气水合物矿区上方具有相似的空间分布特征,说明其化探指标异常空间上具有良好的稳定性和重现性;但是顶空气重烃异常模式、碳酸盐异常强度的变化,反映其具有重现性,但异常稳定性相对较差。这为地球化学勘查在陆域冻土区天然气水合物勘查中发挥作用提供了较好的基础。     

利用重复性和再现性的估计值评估测量不确定度

利用标准分析方法重复性、再现性的估计值,对EDTA容量法测定铜铅锌矿石中铅含量的结果进行不确定度评定,检验了参与协作试验的7个实验室偏倚分量的显著性及方法的重复性,当协作试验实验室偏倚及方法精密度处于控制范围时,测量不确定度主要与方法的再现性有关。为按相关标准进行协同试验建立的标准测试方法,提供了一种经济有效的测量不确定度评定方法。     

超站仪技术在复杂地形测量中的应用研究

由于很多施工区域的地形较为复杂,对测量工作提出了新的要求,除改进常规测量方法外,同时需要更高效的仪器提供技术保障.本文以震后四川省九寨沟县鲜浒沟地质灾害工程1:500地形测绘项目为例,介绍了超站仪在地形测量中的应用原理,结合施工区,讨论了其实施方法、注意事项、对测量成果的重复性、复现性等问题进行了分析,提出了复杂地形测...     

Establishing a framework for Open Geographic Information science

When conducting research within a framework of Geographic Information Science (GISc), the scientific validity of this work can be argued as highly dependent upon the extent to which the methods employed are reproducible, and that, in the strictest sense, can only be fully achieved by implementing transparent workflows that utilize both open source software and openly available data. After considering the scientific implications of non-reproducible methods, we provide a review of both open source Geographic Information Systems (GIS) and openly available data, before describing an integrated model for Open GISc. We conclude with a critical review of this embryonic paradigm, with directions for future development in supporting spatial data infrastructure.     

Reproducibility of river water quality measurements: inter-agency comparisons for quality assurance

We assessed the reproducibility of river state-of-environment (SoE) water quality measurements in the Wellington Region, New Zealand (NZ). Field staff from GWRC and NIWA conducted 29 side-by-side water sampling and in-situ measurements at six river sites of diverse water quality for 12 variables measured routinely in river SoE monitoring across NZ. Field measurements of water temperature, dissolved oxygen, electrical conductivity and visual clarity agreed closely with strong numerical similarity (within 10%). Numerical similarity ranged widely for laboratory measurements, from strong for nitrate-nitrite-nitrogen to weak for turbidity, dissolved reactive phosphorus, and ammoniacal-nitrogen. Numerical agreement was very weak for laboratory pH (which is problematic) and E. coli–which is ‘tolerable’ for many applications given good correlation (R?=?0.94) over a 2000-fold concentration range. The findings of our inter-agency comparison have contributed to quality assurance recommendations in the NZ National Environmental Monitoring Standard (NEMS) for water quality.     

因瓦水准标尺尺长改正检定方法的对比研究

目前国内外新旧水准标尺检定装置并存,有传统的特定分划检定和采用自动化装置的全尺分划检定两种方法。为比较两种方法的差异,用配对样本t检验法对两种方法测量结果的一致性进行检验,对复现性条件下测量结果的可接受性进行评价,并对全尺分划检定进行重复性试验。结果表明,全尺分划检定与分米分划检定的结果无显著性差异|同一种检定方法的重复性误差与两种检定方法的互差为同一数量级。     

HIGH-ACCURACY ANALYSIS OF SOIL HYDROGEN ANOMALY IN FAULT ZONE

Hydrogen is recognized as one of the most useful gases to detect fault activities. Based on long-term high-accuracy soil hydrogen observation data in fault zones, the paper evaluates the reliability of data according to the distribution of measurements. Through the evaluation of earthquake-reflecting ability of hydrogen concentration, we consider that there is a certain corresponding relationship between hydrogen concentration and seismic activity and we present the judging index for this anomaly. Hydrogen concentration characteristics with the earthquakes within the range of 350km around the station were analyzed, especially the two earthquakes, which occurred on October 24, 2010 and March 8, 2011 in Taikang, Henan Province, with magnitude M_S4.6 and M_S4.1 respectively. The observation station is located at Xiaxian in Shanxi Province, 300km away from the epicenter. In a week before the two earthquakes, high-accuracy soil hydrogen concentration measurements showed similar anomaly variation, which was increasing abruptly, then decreasing, and after the earthquakes it returned to background level. Overall, the changing scope was more than 20 times of the background value. We concluded that the anomaly was affected by tectonic setting of the earthquakes. The similar hydrogen distribution pattern recorded at the same station is attributed to the same tectonic position and focal mechanism solution. The hydrogen could be an effective tool for short-term and imminent earthquake prediction, which provides reference for short-term and imminent earthquake prediction in areas with high earthquake risk.