青藏高原西部赛利普中新世火山岩源区:地球化学及Sr-Nd同位素制约

青藏高原拉萨地块西部赛利普地区新生代火山岩依据主量元素可划分为超钾质、钾质和钙碱性系列,主要的岩石类型为粗面安山岩、粗面岩,一个超钾质岩石的40Ar-39Ar年龄为17.58Ma,指示出火山活动为中新世.超钾质、钾质和钙碱性火山岩都显示出富集LREE及LILE(Th、U)、亏损HFSE(Nb、Ta、Ti)的特征.超钾质火山岩具有较高的K2O(6.31%～8.55%)、MgO(6.75%～8.96%)、Cr(270.7×10-6～460.4×10-6)、Ni(142.3×10-6～233.9×10-6)含量,较高的(87Sr/86Sr)i(0.71883～0.72732)和较低的εNd(-14.78～-15.37),指示可能起源于一个前期亏损并经后期俯冲作用改造的富钾的方辉橄榄岩富集地幔源区.钾质火山岩具有比超钾质火山岩低的K2O、MgO、Cr、Ni含量以及高的Ba、Sr含量,初始87Sr/86Sr为0.71553～0.71628,初始143Nd/144Nd为0.51197～0.51198,在空间上与超钾质火山岩共生,可能是前者母岩浆的演化产物.钙碱性火山岩具有较高的Sr(881.7×10-6～1309.2×10-6)、Sr/Y比值(50～108)和较低的Y(12.05×10-6～18.02×10-6),明显亏损重稀土Yb(0.93×10-6～1.30×10-6),类似于典型的埃达克质岩成分特征但相对高钾,并具有相对低的(87Sr/86Sr);(0.70928～0.71374)以及高的εNd(-7.90～-10.91),指示起源于富钾增厚下地壳物质的部分熔融.区域上拉萨地块超钾质岩、钾质岩与N-S向地堑系在空间上共存、时间上相吻合,由此本文认为拉萨地块中新世钾质.超钾质岩和南北向地堑系的形成可能与中新世早期北向俯冲的印度大陆岩石圈断离有关.     

青藏及邻区新生代火山活动及构造演化

青藏高原是现今地球动力学和地质演化研究的一个热点。该区火山活动受中 -新生代以来高原深部地球物理 -化学反应的控制 ,是多种因素相互作用所表现的形式和结果。本区既有富钾质的 (主导 ) ,也有富钠质的火山岩 (次要 ) ;既有喷发熔岩流 (主导 ) ,也有一些浅源上侵的次火山岩体 ;火山活动发育在古近纪、新近纪与第四纪 ,而最强烈的发生在中新世期间。本区钠质和钾质两类火山岩在形成环境和时代上有很大的差异 :前者一般发育在古新世—始新世 (6 0～ 4 0MaBP) ,而后者主要形成在渐新世—中新世 (30～ 10MaBP) ;存在着钠质—钾质—酸性次火山岩的演化过程 ;大体上可划分为西羌塘、北羌塘、可可西里、中昆仑、西昆仑等 5个火山岩省。本文对比了青藏高原及邻区甘肃礼县和云南三岩区 (金沙江北段、腾冲和滇东南地区 )新生代火山岩的岩石组合、同位素年代学以及地球化学特征 ,大量的证据表明 ,这些火山岩形成在原始地幔、或“壳 -幔过渡带”或陆壳基底等源区。在实际考察和综合研究的基础上 ,探讨了岩石圈的区域构造特征及其与高原隆升的关系等     

陕西岚皋－镇坪一带早古生代火山杂岩成岩构造环境及碱（钾）质煌斑岩含矿性探讨

对北大巴山地区岚皋－镇坪一带的区域地质构造演化及其与早古生代碱基性火山杂岩的成岩关系进行了综合分析，指出本区曾经历了裂陷－愈合一再裂陷－愈合的地质发展和演化。早古生代时期本区是一个在已固结愈合的中－晚元古代的裂陷的扬子地台北缘构造软弱带的基础上重新活化的大陆边缘陆内断陷构造带。它不仅控制了区内该时期碱基性火山杂岩的产出位置、岩浆脉动活动特征，而且还影响到岩浆物质来源的深度。在此基础上，笔者探讨了与杂岩密切相关的碱（钾）质煌斑岩的金刚石含矿性。     

Petrographic Characteristics and Alteration Geochemistry of Granite-hosted Tungsten Mineralization at Degana, NW India

Abstract. Vein type tungsten mineralization at Degana is genetically and spatially associated with the Degana Granite. The deposit is characterized by pervasive wall rock alteration around the mineralized quartz veins. Laterally three different alteration zones, greisen, silicification and potassic zones, are marked based on the field features, mineral assemblages and geo-chemical characteristics. In the present paper, systematic mineralogical and chemical variation in these alteration zones is reported. Thick mono-mineralic (zinnwaldite) selvages around the veins characterize the deposit. Plagioclase and alkali feldspar are low in the greisen zones while K-feldspar shows more increase than plagioclase in the potassic zone. Quartz is uniformly high in all the alteration zones, but it shows an anomalous value in the silicification zone. Al₂O₃ concentration shows initial depletion in greisen zone with gradual increase away from the contact. MgO and FeO are higher in greisen zone than silicification and potassic zones. The potassic zone is characterized by the depletion of Na₂O and higher value of K₂O.
The common presence of topaz and fluorite as both primary and secondary minerals and fluorine-bearing micas suggest fluorine partitioning in substantial amount between granitic melt and coexisting aqueous fluid phase and higher HF activity during the evolution of hydrothermal fluid. The mutual relationship of the fluorine minerals (topaz and fluorite) in the different alteration zones suggests an increase in the Ca²⁺ activity and decrease of H+ activity during the fluid evolution from greisenization towards alkali-metasomatised granite and the fluid is assumed to change from low to high activity ratio of Ca²⁺/H+.     

长江中下游庐枞火山岩盆地南侧钾质侵入岩带的成因

庐枞火山岩盆地南侧的钾质侵入岩带由正长岩-石英正长岩-正长花岗岩组成,以石英正长岩为主。它们的形成时间介于123"130 Ma之间,峰值约为126 Ma,其中正长岩和石英正长岩的形成时间稍早,而正长花岗岩的形成时间略晚。整个钾质侵入岩带的侵位时间晚于庐枞盆地内的橄榄玄粗质火山作用约4"7 Ma,也是长江中下游地区除最东段的宁镇地区外中生代最晚的岩浆活动产物之一。地球化学上,该钾质侵入岩带以高钾、富碱、富集Rb、Th、U、K等强不相容元素和轻稀土元素、亏损高场强元素Nb、Ta和Ti为特征。它们的母岩浆主要是由富集型上地幔部分熔融形成的,从正长岩经石英正长岩到正长花岗岩的演化主要受矿物的分离结晶作用控制,地壳物质同化所起的影响不大。但与同样来自富集型上地幔部分熔融的庐枞盆地内火山杂岩的母岩浆相比,前者的母岩浆来源深度可能更大些或其中包含了更多来自软流圈地幔的组分。两者的演化路径也完全不同,钾质侵入岩带的母岩浆除经历过高压下的分离结晶作用外,晚期在低压下还经历过长石为主,可能还有黑云母的分离结晶,甚至上地壳物质一定程度的混染作用;而盆地内火山杂岩的母岩浆低压下矿物的分离结晶作用及上地壳物质的混染都不明显。庐枞盆地南缘的富钾侵入岩与盆地内的火山杂岩一样,地球化学上都具有明显的大陆弧的特征,暗示它们的岩浆源区可能形成于俯冲带环境,意味着扬子地块北缘先前(推测为古元古代晚期)曾发生过俯冲作用,上地幔的交代富集可能就与这次的俯冲作用有关。     

Geodynamic setting,structure, and composition of continuous trachybasalt-trachyandesite-rhyolite series in the north of Altai-Sayan area: the role of crust-mantle interaction in continental magma formation

The geologic positions and geochemical and isotope parameters of the Ordovician-early Silurian and Early-Middle Devonian continuous volcanic series of the Minusa basin and its mountainous framing are compared. Both series are composed mostly of moderately alkaline rocks with variations in SiO₂ contents from 45 to 77 wt.%. The Ordovician-early Silurian series differs from the Early-Middle Devonian one in lower contents of TiO₂ (< 1.7 wt.%) and Fe₂O_3tot and higher contents of Al₂O₃ in all rock varieties and in the more fractionated REE patterns of trachybasalts. The compositions of both series reflect two simultaneous mechanisms of magma evolution. The main process was fractional crystallization leading to the formation of rocks from trachybasalts to trachyrhyodacites. The accessory mechanism was the contamination of fractionated melts by crustal material, anatectic melting of crust, and mixing of deep-seated magmas with crustal melts. These processes had specifics at each stage and were controlled by the composition of the sources of parental melts. Their geochemical and isotopic parameters (high alkalinity, high contents of lithophile elements, negative anomalies of Nb, Ta, and Ti, and enrichment in radiogenic Sr) point to the interaction of mantle plumes with the lithospheric mantle that was metasomatically transformed during the preceding Vendian-early Cambrian subduction processes.     

Early Cretaceous trachybasalt-trachyte-trachyrhyolitic volcanism in the Nyalga basin (Central Mongolia): sources and evolution of continental rift magmas

As shown by geological, mineralogical, and isotope geochemical data, trachybasaltic-trachytic-trachyrhyolitic (TTT) rocks from the Nyalga basin in Central Mongolia result from several eruptions of fractionated magmas within a short time span at about 120 Ma. Their parental basaltic melts formed by partial melting of mantle peridotite which was metasomatized and hydrated during previous subduction events. Basaltic trachyandesites have high TiO₂ and K₂O, relatively high P₂O₅, and low MgO contents, medium ⁸⁷Sr/⁸⁶Sr(₀) ratios (0.70526-0.70567), and almost zero or slightly negative ε_Nd(T) values. The isotope geochemical signatures of TTT rocks are typical of Late Mesozoic basaltic rocks from rift zones of Mongolia and Transbaikalia. The sources of basaltic magma at volcanic centers of Northern and Central Asia apparently moved from a shallower and more hydrous region to deeper and less hydrated lithospheric mantle (from spinel to garnet-bearing peridotite) between the Late Paleozoic and the latest Mesozoic. The geochemistry and mineralogy of TTT rocks fit the best models implying fractional crystallization of basaltic trachyandesitic, trachytic, and trachyrhyodacitic magmas. Mass balance calculations indicate that trachytic and trachydacitic magmas formed after crystallization of labradorite-andesine, Ti-augite, Sr-apatite, Ti-magnetite, and ilmenite from basaltic trachyandesitic melts. The melts evolved from trachytic to trachyrhyodacitic and trachyrhyolitic compositions as a result of prevalent crystallization of K-Na feldspar, with zircon, chevkinite-Ce, and LREE-enriched apatite involved in fractionation. Trachytic, trachyrhyodacitic, and trachyrhyolitic residual melts were produced by the evolution of compositionally different parental melts (basaltic trachyandesitic, trachytic, and trachyrhyodacitic, respectively), which moved to shallower continental crust and accumulated in isolated chambers. Judging by their isotopic signatures, the melts assimilated some crustal material, according to the assimilation and fractional crystallization (AFC) model.     

Petrogenesis of Cenozoic Potassic Volcanic Rocks in the Nangqen Basin

The Nangqen basin is one of the Tertiary pull-apart basins situated in the east of the Qiangtang block.Similar to the adjacent Dengqen basin and Baxoi basin, there occurred a series of potassic volcanic and sub-volcanic rocks, ranging from basic, intermediate to intermediate-acid in lithology.Based on the study of petrology, mineralogy and geochemistry, including REEs, trace elements, isotopic elements and chronology, the authors concluded that the Cenozoic potassic volcanic rocks in the Nangqen basin were formed in the post-collisional intraplate tectonic settings. The relations between the basic, intermediate and intermediate-acid rocks are neither differentiation nor evolution, but instead the geochemical variability is mainly attributable to the different partial melting degrees of the mantle sources formed at depths of 50-80 km.The sources of the potassic rocks are enriched metasomatic mantle that has experienced multiple mixing of components mainly derived from the crust. The recycling model can b     

五大连池钾质火山岩中的壳源捕虏体特征及地质意义

黑龙江省五大连池钾质火山岩石中普遍含有壳源捕虏体和捕虏晶,并多赋存于火山集块、浮岩砾、火山渣等各级火山碎屑物及盾状台地的表皮相到内部相火山熔岩中。花岗岩质捕虏体一般大小为5～50cm,捕虏晶一般为0.2～5mm,成分以二长花岗岩为主,少见花岗闪长岩及黑云母英云闪长岩和少量砂岩捕虏体。石英、斜长石、少数钾长石捕虏晶见于各期火山碎屑(物)和熔岩中,其中以石英捕虏晶最为常见。壳源捕虏体中的代表性矿物及浅色玻璃电子探针分析结果表明,火山岩SiO2偏高是岩浆上涌喷发过程中捕获了大量壳源物质的结果。五大连池火山群富钾火山岩岩石化学、地球化学长期保持均一,说明其岩浆直接来自EMⅠ型钾质地幔,岩浆在上升过程中遭受了地壳物质的明显混染。     

湘东北临湘地区钾质煌斑岩~(40)Ar-~(39)Ar定年及其地球化学特征

对出露于湘东北临湘地区的煌斑岩脉群进行了同位素年龄测定及岩石地球化学分析。研究表明,煌斑岩的全岩40Ar-39Ar年龄为(119.5±2.2)Ma,形成于早白垩世。岩石地球化学方面,岩石属碱性系列、钾质—超钾质煌斑岩;富集大离子亲石元素(LILE)和高场强元素(HFSE);稀土元素分配模式为相似的右倾轻稀土富集型;具有较小的TDMⅡ值(1.5Ga)和较低的εNd(t)(-7.3)。上述特征暗示煌斑岩物质来源于异常(交代富集)地幔,形成于后造山陆内拉张减薄的构造环境。