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排序方式: 共有151条查询结果,搜索用时 15 毫秒
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报道一种新的有效催化剂-碘-钒盐和在一定条件下合成四溴邻苯二甲酸酐的方法。探讨催化剂的组成配比、用量、温度及废酸循环使用等因素对合成方法的影响。该催化剂的催化效果和常用的碘、碘-铁催化剂相同,适用于四溴邻苯二甲酸酐的合成。 相似文献
3.
Kun HE Yuming DONG Lin YIN Aiming ZHANG Zhen LI 《中国地球化学学报》2006,25(B08):101-101
Catalytic ozonation has attracted much attention in treatment of wastewater for its mild conditions. Phenol and its ramifications are common components in a wide variety of wastewaters including those from coal conversion processes, coking plants, petroleum refineries and several chemical industries. In this paper, natural brucite and magnesia have been successfully used in catalytic ozonation of phenol. And the mechanisms of catalysis were also investigated. From Figs. 1 and 2, it can be found that both brucite and magnesia have remarkable catalysis on degradation of phenol and removal of Chemical Oxygen Demand (COD). The pH of solutions on the process of ozonation alone, catalytic ozonation with brucites and with magnesia were 6.35-2.76, 10.18-8.52 and 10.58-10.83, respectively. It can be concluded that alkali environment plays a critical role for catalytic ozonation of phenol. We also found that the alkaline minerals reacted on the surface with oxalic acid and other low molecular-weight acids which are intermediate products in ozonation, but those intermediate products could be mineralized into carbon dioxide completely with enough ozonation time. 相似文献
4.
A. Heusel-Waltrop K. Diehl S. K. Mitra H. R. Pruppacher 《Journal of Atmospheric Chemistry》2003,44(2):211-223
Laboratory experiments have been carried out to investigate the uptake of sulfur dioxide by water drops containing heavy metal ions where the metal ions serve as catalysts to oxidise the taken up S(IV) into S(VI). During the gas uptake the drops were freely suspended at their terminal velocity in the airstream of the Mainz vertical wind tunnel. Two series of experiments were carried out, one with large millimeter size water drops containing manganese or iron ions, and the other with small water drops containing manganese ions and having radii in hundreds of micron size range. The experimental results were compared against model computations using the Kronig–Brink model and the fully mixed model, modified for the case that heavy metal ions present in the liquid phase act as catalysts for the oxidising process. The results of the model calculations show that there are only small differences between the predicted gas uptake according to the two models. In addition it was found that the experimental obtained results from the uptake of SO2 by water drops containing heavy metal ions for both, large and small water drops did agree with the model results. 相似文献
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系统研究了Ge-ARS-H2C2O4-V体系报道极谱催化波的影响因素,测定了Ge-ARS-H2C2O4三元配合物的配合比为1:2:1。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为0.14mg.mL^-1,相对标准偏差小于9.89%,标准回收率为93.70%-109.0%,0-50mg.mL^-1的锗具有良好的线性关系。 相似文献
7.
催化分光光度法测定痕量钛 总被引:2,自引:0,他引:2
催化分光光度法测定痕量钛周之荣1吴伟华东地质学院应化系江西临川344000催化褪色光度法测定钛的报道较少[1],本文研究了痕量Ti(Ⅳ)催化过氧化氢氧化酸性铬蓝K褪色反应的影响因素,建立了测定痕量Ti(Ⅳ)的催化光度法,并用于测定植物及人发中钛。方法... 相似文献
8.
催化光度法测定痕量锇 总被引:3,自引:0,他引:3
在05mol/L的H2SO4介质中,As(Ⅲ)存在下,Os(Ⅷ)催化KClO3氧化邻苯二酚紫褪色反应。反应受温度、反应时间影响,冷却及加入抗坏血酸可终止反应。据此,建立了一个测定痕量Os(Ⅷ)的新方法。方法的灵敏度为257×10-10g/LOs(Ⅷ),测定范围为0~0091μg/L,用地质管理样中锇的测定验证,结果与原结果相符 相似文献
9.
催化褪色光度法测定痕量锰的研究及应用 总被引:2,自引:0,他引:2
本研究了在PH=4.0醋酸-醋酸钠缓冲溶液中,锰催化KIO4氧化5-Br-PADAP的褪色反应及其动力学条件,建立了一个痕量锰的高灵敏度新方法,方法灵敏度为1.32×10^-10g/ml,测定范围Mn^2+浓度为0 ̄1.5μg/ml,用于测定人发,自来水,茶叶中痕量锰,结果满意。 相似文献
10.
Ralph Lehmann 《Journal of Atmospheric Chemistry》2004,47(1):45-78
When the output of a complex chemical model is analysed, a typical topic isthe determination of pathways, i.e., reaction sequences, that produce ordestroy a chemical species of interest.A representative example is the investigation of catalytic ozone destruction cycles in the stratosphere.An algorithm for the automatic determination of pathways in any given reactionsystem is presented. Under the assumption that reaction rates are known, it finds all significant pathways, i.e., all pathways with a rate above a prescribed threshold.The algorithm forms pathways step by step, starting from single reactions.The chemical species in the system are consecutively considered as `branching points'.For every branching-point species, each pathway producing it is connected witheach pathway consuming it.Rates proportional to `branching probabilities' are calculated.Pathways with a rate that is smaller than a prescribed threshold arediscarded.If a newly formed pathway contains sub-pathways, e.g., null cycles, it is split into these simpler pathways.In order to demonstrate the performance of the algorithm, it has been applied to the determination of catalytic ozone destruction cycles and methaneoxidation pathways in the stratosphere. 相似文献