西藏班公湖-怒江缝合带西段特提斯洋晚二叠世(Ca.252Ma)洋内俯冲的地球化学和年代学证据

多龙蛇绿混杂岩是班公湖-怒江蛇绿岩带的重要组成部分,位于西藏阿里地区改则县北西约120 km的多龙矿集区内,大地构造位置处于班公湖-怒江缝合带中西段,南羌塘板块南缘。多龙蛇绿混杂岩主要分布在多龙矿区中部及东北部。矿区中部蛇绿岩主要由辉长岩、辉绿(玢)岩、枕状玄武岩、气孔杏仁状玄武岩、玄武质岩屑凝灰岩及硅质岩等组成,东西向延伸约35 km,南北宽3~7 km,出露面积约180 km2;该蛇绿岩残片的组成单元(包括基性岩单元以及硅质岩单元等)多被构造肢解,整体表现为不规则透镜体,以构造岩片的形式断续分布于侏罗系次深海陆棚-盆地斜坡复陆碎屑岩-类复理石建造内的断层带中,构成典型的网结状构造。矿区东北部蛇绿岩主要由含铁斜方辉石橄榄蛇纹岩、玻基玄武岩、碳酸盐化角闪辉长岩、微纹层状硅质岩等组成,该蛇绿混杂岩带沿北西-南东向断裂展布,延伸约12 km,宽1~3 km,出露面积约30 km2;该蛇绿岩残片组成单元(包括超基性岩单元、基性岩单元以及硅质岩单元等)均呈构造岩片的形式产出在三叠系灰岩地层内的断层带中。     

西藏改则县多龙矿集区发现岩墙岭蛇绿岩残片

西藏班公湖-怒江缝合带北缘多龙矿集区是青藏高原新近发现的具有超大型远景的、典型的富金斑岩型铜矿集区,其成岩成矿地质背景是解决班公湖-怒江洋构造演化的关键问题之一。近年来的区域地质调查研究发现,多龙矿集区南侧出露岩墙岭蛇绿岩残片,应该是班公湖-怒江蛇绿岩带的重要组成部分。岩墙岭蛇绿岩主要由席状岩墙群、枕状玄武岩和硅质岩组成,整体呈棱形或透镜体状断续分布于侏罗系复理石沉积内,构成典型的网结状构造。糜棱岩普遍发育在岩墙岭蛇绿岩和围岩的接触部位。综合前人研究成果,初步认为多龙矿集区早白垩世成岩成矿作用应该形成于增生楔之上伸展拉张的构造环境。岩墙岭蛇绿岩的发现和确定进一步约束了多龙矿集区成岩成矿地质背景,同时为班公湖-怒江缝合带的延伸及其构造演化的研究提供了新的线索。     

藏北多龙矿集区地壳基底性质、演化及其对成矿的制约——来自波龙火山-侵入岩中继承锆石U-Pb年龄的信息

地壳基底性质及其演化对区域金属成矿类型和成矿潜力具有重要影响。藏北多龙矿集区是目前中国规模最大的斑岩-浅成低温热液型铜多金属矿集区之一,其地壳基底性质与演化缺少研究,制约了对区内铜多金属成矿构造背景和成矿物质来源的全面认识。多龙矿集区内波龙火山-侵入岩中继承锆石LA-ICP-MS U-Pb测年结果显示,14颗继承锆石具有新太古代—古元古代年龄(2581~1670Ma),这些锆石多为自形-半自形颗粒,具有原地来源的特征,表明多龙矿集区深部存在新太古代—古元古代结晶基底。该基底应该是南羌塘中心地区古老基底向南延伸的一部分。该基底在中元古代—早古生代遭受多次构造-岩浆热事件改造,尤以泛非期—早古生代最强烈。进入晚中生代后,由于年轻地幔物质的加入,多龙地壳发生明显的垂向生长,形成富含金属和成矿组分的新生下地壳,该新生下地壳在早白垩世发生活化,为多龙成矿体系提供大量的金属及其他幔源有用组分。多龙矿集区是一个"两期岩浆叠加成矿"的典型例子。     

Early Cretaceous K-rich rhyolites from the Duolong Cu–Au deposit,southern Qiangtang,China: evidence for crustal growth

We report new zircon U–Pb age, Hf isotopic, and major and trace element data for rhyolites from the Duolong Ore Concentration Area of the Southern Qiangtang Terrane. Building on previous studies, we constrain the tectonic setting and propose a model to explain the geodynamics and crustal growth during regional magmatism in the Early Cretaceous. The analysed rhyolites yield laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb ages of 115 and 118 Ma. The rocks are K-rich (K₂O = 6.66–9.93 wt.%; K₂O/Na₂O = 8.2–19.7 wt.%), alkaline and peraluminous (A/CNK = 1.02–1.46), and are characterized by high SiO₂ contents (72.8–78.8 wt.%) similar to highly fractionated I-type granites. Fractionation of Fe–Ti oxides, plagioclase, hornblende, Ti-bearing phases, apatite, monazite, allanite and zircon contributed to the variations in major and trace element chemistry. High K₂O contents are likely due to partial melting of the continental crust. The samples have positive zircon εHf(t) values ranging from +7.1 to +11.2. These features, together with young zircon Hf crustal model ages of 489–721 Ma, indicate that the K-rich rhyolites were derived from juvenile lower crust with an input of a mantle-derived component. We suggest that the Early Cretaceous K-rich rhyolites formed in a continental arc setting during northward subduction of Bangong Co–Nujiang oceanic lithosphere. Basaltic magma underplating was responsible for vertical crustal growth, triggered by slab roll-back in the Duolong Ore Concentration Area in the Early Cretaceous.     

西藏多龙矿区生态环境遥感调查研究

本文依托项目《西藏多龙矿床技术经济与环境综合评价》,利用高分二号、资源三号及landsat8等多源遥感数据对西藏多龙矿区生态地质环境进行调查研究。通过遥感技术与实地调查结合,查明了矿区生态地质环境现状,取得了涵盖人类活动、矿山地质活动、河流湖泊现状、植被覆盖与荒漠化情况等内容的专题成果。研究结果表明,砂金矿开采及尾矿堆积物给当地生态环境造成不可逆破坏,同时探槽、钻孔及地表金属污染等也给生态环境带来一定程度的影响。通过对目前中国矿储量第一的多龙铜多金属矿床进行开发前全面、综合的生态地质环境调查研究,能够为藏北矿山开发对生态地质环境的影响评估提供科学依据,为西藏多龙矿区建设绿色矿山和绿色开发提供建议及决策依据。     

西藏多龙矿集区拿若铜（金）矿床成矿元素空间分布规律及地球化学勘查模型

拿若铜(金)矿床是多龙矿集区内继多不杂斑岩铜(金)矿、波龙斑岩铜(金)矿之后又一取得重大找矿突破的大型斑岩型矿床。作者以矿区探矿工程分析数据为基础,研究各成矿元素空间分布规律。成矿元素在垂向上的分带特征不明显,在平面上分带特征较显著,表现为自矿区中心ZK0001,向南西方向具有Cu+Au-Cu(Au、Ag)→Cu(Ag、Au)-Cu(Ag)的分带特征。同时,矿区土壤地球化学测量显示,从0线开始至31线(北东→南西)具有Mo、Cu→Mo(Cu、Au)→Cu、Au(Ag、Mo、Pb)→Pb→Pb、Zn分带特征,显示物质来源和热源位于0线附近,成矿流体是以0线、7线一带向四周运移,并具有从北东向南西方向运移的特点。通过矿床地质特征、元素分带特征研究,建立了矿区地球化学勘查模型。     

西藏改则县多龙矿集区斑岩型铜金矿床的地质特征与成矿-找矿模型

多龙矿集区位于班公湖_怒江成矿带西段、羌塘地块南缘的岩浆弧中。过去十多年来,西藏地勘局第五地质大队在多龙矿集区内已发现和评价了多不杂、波龙、地堡那木岗、拿若、荣那等5处大型、超大型铜金多金属矿床,目前已探明的铜资源量近1000万吨,金300余吨。区内以斑岩型铜金矿床为主,兼有斑岩_浅成低温热液型和斑岩_角砾岩型矿化组合。研究发现,矿区黄铁矿的δ34S值变化于-2.2‰~2.3‰之间,平均为0.2‰,峰值在-1‰~1‰之间,塔式效应明显,接近幔源硫,显示成矿物质来源于深部岩浆;成矿温度介于250~420℃之间,成矿深度1~5 km,成矿流体为残余岩浆流体,大气降水在成矿过程中的作用不明显。作者根据多年的勘查实践,总结出多龙矿集区斑岩型铜金矿最有效的找矿勘查方法技术组合是:地质+化探(水系沉积物)+物探(高精度磁测、激电中梯)+钻探。     

西藏多龙矿集区铜金流体演化过程探讨 ——来自硫同位素的证据

西藏多龙矿集区发育世界典型的斑岩铜矿系统,文章选取区内多个代表性矿床开展硫同位素研究,并结合前人数据,为探讨该成矿系统成矿物质来源、流体演化过程提供了新证据.研究表明,波龙、拿若、拿厅、拿顿和铁格隆南矿床δ34S平均值相似(接近于0),指示含矿岩浆提供了各矿床所需的硫元素.此外,区内典型矿床流体演化过程可分为2类:①流体演化主要受控于温度变化,表现为δ34S随温度降低而降低(如拿顿矿床);②流体演化受温度和氧化还原状态共同影响,表现为δ34S随温度降低而升高(如:波龙和拿若矿床),或是随温度降低,δ34S波动变化范围较大(如拿厅和铁格隆南矿床).结合岩相学证据,文章推测热液体系氧化还原状态的变化是由水岩反应所导致,最后,文章提出多龙矿集区内矿化阶段硫化物通常具有较低的δ34S,指示成矿流体为高氧化性流体,并且该特征在类似矿床的找矿勘查工作中也可发挥积极的指示作用.     

西藏多龙矿集区地堡那木岗铜(金)矿床流体包裹体特征及矿床成因

地堡那木岗铜(金)矿床位于西藏多龙矿集区,探明储量达大型规模;矿床的成矿过程分为岩浆作用阶段、钾长石-硫化物阶段、石英-多金属硫化物阶段、碳酸盐-黄铁矿阶段和氧化作用阶段,其中石英-多金属硫化物阶段和碳酸盐-黄铁矿阶段为主要成矿阶段;为查明成矿流体特征,确定矿床成因类型,对取自深部矿石中的碳酸盐脉(均为碳酸盐-黄铁矿成矿阶段含黄铁矿黄铜矿石英脉)开展流体包裹体的岩相学观察和显微测温分析。分析结果表明,上述矿物中主要发育富液相、富气相和含子矿物三相包裹体。其中,富液相包裹体的均一温度与盐度分别为:t=80~600℃、w(NaCl,eq)=4.48%~18.79%;富气相包裹体的均一温度和盐度分别为:t=240~560℃、w(NaCl,eq)=5.09%~9.73%;含子矿物三相包裹体的均一温度与盐度分别为:t=240~560℃、w(NaCl,eq)=36%~72%。综合分析认为,地堡那木岗铜(金)矿床成矿流体发生了强烈的沸腾作用,流体沸腾作用是该矿床的重要成矿机制。通过与国内外典型斑岩型矿床与高硫化型浅成低温热液矿床的流体包裹体特征进行对比,其与斑岩型矿床的中高温、高盐度流体特征相似。因此,推测地堡那木岗矿床的成因类型为斑岩型铜(金)矿床。     

Mineralogy and Mineral Chemistry of the Cretaceous Duolong Gold‐Rich Porphyry Copper Deposit in the Bangongco Arc,Northern Tibet

The Early Cretaceous Duolong gold‐rich porphyry copper deposit is a newly discovered deposit with proven 5.38 Mt Cu resources of 0.72% Cu and 41 t gold of 0.23 g t^?1 in northern Tibet. Granodiorite porphyry and quartz diorite porphyrite are the main ore‐bearing porphyries. A wide range of hydrothermal alteration associated with these porphyries is divided into potassic, argillic and propylitic zones from the ore‐bearing porphyry center outward and upward. In the hydrothermal alteration zones, secondary albite (91.5–99.7% Ab) occurs along the rim of plagioclase phenocryst and fissures. Secondary K‐feldspar (75.1–96.9% Or) replaces plagioclase phenocryst and matrix or occurs in veinlets. Biotite occurs mainly as matrix and veinlet in addition to phenocryst in the potassic zone. The biotite are Mg‐rich and formed under a highly oxidized condition at temperatures ranging from 400°C to 430°C. All the biotites are absent in F, and have high Cl content (0.19–0.26%), with log (X_Cl/X_OH) values of ?2.74 to ?2.88 and IV (Cl) values of ?3.48 to ?3.35, suggesting a significant role of chloride complexes (CuCl₂^‐ and AuCl₂^‐) in transporting and precipitating copper and gold. Chlorites are present in all alteration zones and correspond mainly to pycnochlorite. They have similar Fe/(Fe+Mg), Mn/(Mn+Mg) ratios, and a formation temperature range of 280–360°C. However, the formation temperature of chlorite in the quartz‐gypsum‐carbonate‐chlorite vein is between 190°C and 220°C, indicating that it may have resulted from a later stage of hydrothermal activity. Fe³⁺/Fe²⁺ ratios of chlorites have negative correlation with Al^IV, suggesting oxygen fugacity of fluids increases with decreasing temperature. Apatite mineral inclusions in the biotite phenocrysts show high SO₃ content (0.44–0.82%) and high Cl content (1–1.37%), indicating the host magma had a high oxidation state and was enriched in S and Cl. The highest Cl content of apatite in the propylitic zone may have resulted from pressure decrease, and the lowest Cl content of apatite in the argillic zone may have been caused by a low Cl content in the fluids. The low concentration of SO₃ content in the hydrothermal apatite compared to the magmatic one may have resulted from the decrease of oxygen fugacity and S content in the hydrothermal fluid, which are caused by the abundant precipitation of magnetite.