C,Si在CO—CO2—SiO气体与Fe—Si—C合金间迁移平衡与Pco2—Psio…

通过评价和优化有关热力学数据，利用冶金物理化学原理建立了钢铁冶金中最为重的Ｆｅ－Ｓｉ－Ｃ三元体系与ＣＯ－ＣＯ２－ＳｉＯ混合气体间硅，碳迁移的热力学数学模型，计算了相关热力学数据并计算机绘制了该体系的Ｐｃｏ２－Ｐｓｉｏ和ｌｇＰｓｉｏ相平衡图。该模型的可靠性１８７３Ｋ高温条件下的一系列的平衡实验中得到了检验。     

混合气体驱替煤层气技术的可行性研究

气体驱替煤层气技术是近年来发展起来的具有温室气体减排和提高煤层气采收率双赢效果的新兴技术,相关研究受到世界主要发达国家的广泛重视。对于温室气体减排的压力,发达国家的研究主要着眼于该技术在高渗透、不可采煤层中的应用,注入气体主要为CO2,目的是尽可能多地封存CO2,同时提高煤层气采收率。目前,国内在这方面的研究刚刚起步。国内煤层具有渗透率普遍较低、不开采煤层与要开采煤层难以界定的特点,注CO2气体驱替煤层气在这种煤层中的可行性值得商榷。针对国内煤层特点和煤矿瓦斯抽采率低的现状,建议采用富N2混合气体驱替煤层气技术,以提高煤层气产采收率。通过理论分析、数值模拟和现场试验研究分析了实施混合气体驱替煤层气技术的可行性。研究结果表明,混合气体驱替煤层气技术适用于国内低渗透、可开采煤层,可以提高煤层气采收率和单产量。     

Intercomparison of NO<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>, SO<Subscript>2</Subscript>, O<Subscript>3</Subscript>, and aromatic hydrocarbons measured by a commercial DOAS system and traditional point monitoring techniques

A field-based intercomparison study of a(DOAS) instrument (OPSIS AB, Sweden) andcommercial Differential Optical Absorption Spectroscopydifferent point-sample monitoring techniques (PM, basedon an air monitoring station, an air monitoring vehicle, and various chemical methods) was conducted inBeijing from October 1999 to January 2000. The mixing ratios of six trace gases including NO, NO2, SO2,03, benzene, and toluene were monitored continuously during the four months. A good agreement betweenthe DOAS and PM data was found for NO2 and SO2. However, the concentrations of benzene, toluene,and NO obtained by DOAS were significantly lower than those measured by the point monitors. Theozone levels monitored by the DOAS were generally higher than those measured by point monitors. Theseresults may be attributed to a strong vertical gradient of the NO-O3-NO2 system and of the aromatics atthe measurement site. Since the exact data evaluation algorithm is not revealed by the manufacturer ofthe DOAS system, the error in the DOAS analysis can also not be excluded.     

Geochemical constraints on mixed source and hydrocarbon filling process in the Yingjisu Sag,Tarim Basin,Xinjiang

The Yingjisu Sag was petroliferous for normal oil, condensate oil, reservoir bitumen and natural gases. Geochemical studies showed that natural gases in the Yingjisu Sag were a gas mixture consisting mainly of Cambrian pyrolysis gas, Jurassic condensate oil in well Yingnan 2 and normal oil in well Tadong 2, reflecting the characteristics of marine-phase gases and oils, while crude oils in well Longkou 1 demonstrated the characteristics of both marine and terrestrial oils, which were derived from lower algae and higher plants. Jurassic oils from wells Longkou 1 and Huayingcan 1 and Cambrian crude oils from well Tadong 2 were derived mainly from Cambrian-Lower Ordovician source rocks. Jurassic and Silurian reservoir bitumens from well Yingnan 2 were biodegradated, suggesting they are of marine and terrestrial origins. The bitumens have similar geochemical characteristics, which are correlated well with Ordovician crude oils from well Tadong 2 and Jurassic condensate oil from well Yingnan 2. Based on the characteristics of tectonic evolution in this area and the analysis of hydrocarbon accumulation, the constraints on the mixed source and hydrocarbon filling process in the Yingjisu Sag were brought forward.     

混合气体在水溶液中的溶解度计算模型

该文将段振豪及合作者建立的单气体溶解度模型推广到混合气体系,建立了能够计算CO2-CH4-N2-C2H6-H2S混合气 体在电解质水溶液中溶解度的热力学模型。本模型将DMW92方程扩展到上述多组分混合气体系并使用其计算气体组分的 逸度系数,采用Pitzer活度系数模型描述液相并沿用段振豪及合作者以前确定的纯CO2、CH4、C2H6和H2S的溶解度模型参 数,而纯N2的溶解度模型参数由本研究确定。由于本模型不包含依赖混合气体溶解度实验数据确定的参数,因此对混合气 体溶解度的计算是预测性的。通过与实验数据的对比,证实了本模型能够在宽广的温度、压力范围内准确预测 CO2-CH4-N2-C2H6-H2S混合气体在水溶液中的溶解度（对于CO2和CH4的摩尔百分数超过90%的混合气体,本模型适用于 273~523 K和0~2000×105 Pa的温压范围）。本模型的计算表明,相对于纯CO2气相,少量CH4、N2或H2S的加入会降低CO2的溶解度。对于CO2-H2O-NaCl型流体包裹体,少量CH4的加入会增大流体包裹体的均一压力。相关的计算程序可从通讯作者 处获得。     

二元混合气体等温吸附实验结果与扩展Langmuir方程预测值的比较

通过实验获得了CH4和N2及其二元混合气体的等温吸附方程，并利用扩展Langmuir方程对二元混合气体的吸附行为进行了预测。结果表明，利用纯CH4气体的等温吸附方程和扩展Langmuir方程对二元混合气体吸附行为的预测结果，均与二元混合气体的等温吸附实验数据存在较大误差。所以，当煤层气中合有一定数量的非甲烷气体时，只有通过混合气体的等温吸附实验，才能获得准确的吸附特性参数。