Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.     

甘肃酒泉荒漠戈壁灌木群落优势物种生态位特征

了解物种利用资源和占据生态空间的能力，对维持完善和科学保育荒漠戈壁植物群落的多样性具有重要意义。在综合反映各生态因子作用的群落类型和海拔梯度组合而成的两条资源轴上，测度分析了甘肃酒泉荒漠戈壁灌木群落主要优势种的生态位特征。结果表明：(1)在群落类型和海拔梯度两条资源轴上，红砂（Reaumuria songarica）、泡泡刺（Nitraria sphaerocarpa）和合头草（Sympegma regelii）的重要值和生态位宽度均较大，说明这些物种适应能力强,能够较好地利用环境资源，分布范围大，作为荒漠戈壁灌木群落中的广域种具有重要的生态地位和作用。(2)荒漠戈壁优势物种间的生态位重叠值多数较小，在群落类型和海拔梯度资源轴上生态位重叠值小于0.5的分别占总种对的62.63%和77.89%。生态位宽度大的物种之间一般生态位重叠值较高，物种利用资源能力强且存在竞争关系；然而，生态位宽度较小的物种与其他物种之间的生态位重叠程度较低，不同物种在环境资源的需求上产生互补，可以和谐共存；生态位宽度小的物种之间生态位重叠值仍较高，物种分布呈斑块现象；因此，生态位重叠与生态位宽度之间无显著相关性。(3)荒漠戈壁优势物种间总体表现为不显著的正关联，表明该植被群落结构及其物种之间处于稳定共存的状态。     

由地面重力数据确定扰动位径向二阶梯度

提出利用地面重力异常数据计算地面扰动位径向二阶梯度，将该梯度的积分表达式转换为卷形式的谱表达式，便于应用ＦＦＴ／ＦＨＴ技术进行快速计算。     

湘中煤层含气性及其变化特征

湘中主要赋存有下石炭统测水组、上二叠统龙潭组、上三叠统安源组和下侏罗统造上组等煤系。湘中煤层气含量主要是受煤级、煤层埋深、构造运动、围岩、水文地质条件因素的影响。     

超基性岩中含铜、钴块状硫化物矿床——德尔尼铜矿成因新认识

长期以来对德尔尼铜矿的成因存在着不同认识。从矿石组成和结构、构造来看,应属典型的块状硫化物矿石,矿床亦应属于含铜黄铁矿型矿床。但从其地质产状来看又与一般的黄铁矿型矿床大不相同,与一般的岩浆熔离铜镍硫化物矿床也有较多差异。这就是本矿床类型独特之处。近年来通过工作又取得一些新资料,特别是超基性岩和矿石的同位素年龄数据。本文在综合新老资料基础上,提出新看法,认为该矿床形成于上地幔,再就位于地壳浅部。其成因类型暂定为:“深部熔离—构造侵位矿床”。鉴于本矿床与一般块状硫化物矿床相比有其独特性,建议命名为“德尔尼型”。     

瞬变电磁法在断层含水性评价中的应用

本文介绍了瞬变电磁法在煤矿水文地质勘探中的具体应用效果.采用瞬变电磁法对落差较大断层的含(导)水性进行测量,不仅可有效地控制断层的空间位置,而且可定性地判断断层的富水性,其测量结果与已知水文地质资料吻合较好.     

高效液相色谱-等离子体质谱技术在溴元素形态分析中的应用

溴是一种在自然水体中都含有的元素,通常以B r-的形式存在。目前最常用的水净化方式就是向水中通入臭氧以杀灭细菌;而臭氧分解的副产物即为B r-转换成的B rO3-,这是一种公认的致癌物质。本实验室曾使用阴离子交换高效液相色谱(HPLC)与等离子体质谱(ICP-MS)联用分析B rO3-和B r-,方法虽能有效地将这两种溴形态分离,但分析每个样品需8 m in。本文试图建立新的方法缩短分析时间,并验证该方法应用于实际水样分析时测定其他含溴化合物的能力。1实验部分1.1高效液相色谱分析条件表1列出了等度淋洗和梯度淋洗两种模式下HPLC的分析条件,完成形态的分离。等度淋洗和梯度淋洗在分析中显示出不同