微量元素分析在判别沉积环境中的应用——以柴达木盆地西部锶矿区富锶地层为例

沉积岩中的微量元素对沉积环境水介质的变化较为敏感,是研究沉积物沉积时古气候、古环境的有效手段。选取了对沉积环境介质较为敏感的锶(Sr)、钡(Ba)、铜(Cu)、铀(U)、钒(V)、镍(Ni)、钍(Th)等元素作为判别指标,对柴达木盆地西部上新统油砂山组、狮子沟组和更新统七个泉组三套富锶岩层的古气候和古沉积环境特征进行了研究。结果表明,柴达木盆地西部从油砂山组到七个泉组沉积时总体上为干旱的气候环境;湖盆水体的盐度较高,表现为咸水环境,且从油砂山组到七个泉组随着地层变新,盐度有逐渐增大的趋势;油砂山组、狮子沟组和七个泉组沉积时湖盆水体均表现为中等分层、湖水循环较为顺畅的氧化环境。     

西北太平洋深海海山的一种蛇尾新记录

Ophioleila elegans是一种非常少见的蛇尾。2014年大洋35航次中利用“蛟龙”号载人潜器在西北太平洋麦哲伦海山链的采薇平定海山水深1660m处采集到2株该种标本。该种首次发现于夏威夷海山相似的生境当中，本次采集到的样品是继首次发现之后的再次公开报道。本文中对该种的形态学特征，如腕部骨骼等，进行了更加详细的研究，同时基于COI序列进行系统发育分析。形态和系统发育分析的结果都表明，Ophioleila属与辐蛇尾科更加接近。     

解郁安神法联合体外反搏对PCI术后气滞血瘀型胸痹患者的临床疗效观察

目的：观察解郁安神法联合体外反搏（EECP）对经皮冠状动脉介入治疗（PCI）术后气滞血瘀型胸痹患者的临床疗效。方法：将80例冠心病PCI术后气滞血瘀型胸痹患者随机分为治疗组和对照组,每组各40例。对照组采用PCI术后规范化治疗,同时联合EECP治疗;治疗组在对照组基础上加服解郁安神方治疗,随访观察7周,比较2组临床证候疗效、Zung焦虑自评量表（SAS）评分、抑郁自评量表（SDS）评分、西雅图心绞痛调查量表（SAQ）评分。结果：总有效率治疗组为82.5%（33/40）,高于对照组的60.0%（24/40）,2组比较,差异有统计学意义（P<0.05）;2组SAS、SDS、SAQ评分治疗前后组内比较及治疗后组间比较,差异均有统计学意义（P<0.05）。结论：解郁安神法联合EECP治疗可明显改善PCI术后气滞血瘀型胸痹患者的临床症状,缓解焦虑抑郁程度,提高患者生活质量,值得临床推广应用。     

Inversion of multimode surface wave data: evidence for sub-lithospheric anisotropy

Summary. Multiparameter inversions of multimode dispersion data are performed for two large regions: the Pacific Ocean and North America. Anisotropy is taken into account by considering transversely isotropic structures with a vertical axis of symmetry. Two fundamental questions are studied in detail: (1) how to make the inverted models consistent when using different sets of parameters, (2) what is the significance of transversely isotropic inversion for the actual Earth's structure? It is proved that full consistency of the inverted models can be achieved by properly taking into account some a priori informations on the model and it is shown that the use of transversely isotropic models with vertical axis of symmetry does not cause severe limitations when interpreting the data. The models we have obtained are discussed in the light of these investigations. Considering an olivine-rich upper mantle, we make a tentative interpretation of these models in terms of preferred orientation of the a -axis of the crystals in one fixed horizontal direction.     

Long-chain alkenones and U37′ variability along a south–north transect in the Western Pacific Ocean

In this paper, we present 50 surface water samples collected during the IMAGES III cruise (June–July 1997) along a transect from New Zealand to the China Sea (42°S–178°E, 21°N–120°E) covering a temperature range from 13.3 to 30.4 °C. A very worthwhile aspect of this study is a coupling of both biomarker (alkenone) and coccolithophorid counting. We show that the U₃₇^k′–temperature relationship is very similar to the Prahl et al. [Geochim. Cosmochim. Acta 52 (1988) 2203] culture calibration and to the global core top calibration of Müller et al. [Geochim. Cosmochim. Acta 62 (1998) 1757]. However, in the warmest surface waters of the Western Pacific ocean (>26.4 °C) where Gephyrocapsa oceanica is likely the most widespread species, the associated U₃₇^k′ has a constant value of 1.0. The consequence is that above this temperature threshold, U₃₇^k′ cannot be used as an accurate paleothermometer.     

Sea‐surface temperature and salinity changes in the northwest Pacific since the Last Glacial Maximum

The oxygen isotope records of both benthic and planktonic Foraminifera in five piston cores, collected from the region between the Oyashio and Kuroshio Currents near Japan, clearly show the marked latitudinal shifts of these two currents during the past 25 kyr. Under the present hydrographic condition, a clear relationship between the sea‐surface temperature (SST) and oxygen isotope differences from benthic to planktonic Foraminifera is observed in this region. Using this relationship, we find decreased SSTs of 12–13°C (maximum 15°C) in the southernmost core site at the Last Glacial Maximum (LGM), indicating the Oyashio Current shifted southward. The SSTs at the southern two core sites abruptly increased more than 10°C at 10–11 ka, suggesting the Kuroshio Current shifted northward over these sites at 10–11 ka. In contrast, the northern two core sites have remained under the influence of the cold Oyashio Current for the past 25 kyr. With the reasonable estimate of bottom‐water temperature decrease of 2.5°C at the LGM, the SSTs estimated by this new method give exactly the same SST values calculated from Mg/Ca ratio of planktonic Foraminifera, allowing palaeosea‐surface salinities to be reconstructed. The result suggests that the ice volume effect was 1.0 ± 0.1‰ at the LGM. Copyright © 2004 John Wiley & Sons, Ltd.     

Advances in our understanding of the gem corundum deposits of the West Pacific continental margins intraplate basaltic fields

Recent discoveries over the last decade of new gemfields, exploitation of new and existing deposits, and application of relatively new techniques have greatly increased our knowledge of the basalt-derived gem sapphire–ruby–zircon deposits. In this paper we focus on the Late Mesozoic to Cenozoic intraplate basaltic fields of the West Pacific continental margins. We review advances made in understanding the genesis of these deposits, based on the application of newer techniques. We also critically review existing data on the gem corundum deposits, in order to further refine a model for their origin.In some of the intraplate basaltic fields, corundum-bearing xenoliths have been found showing a range of PT formation conditions from 790 °C at 0.85 GPa to as much as 1100 to 1200 °C at 1.0 to 2.5 GPa. Although most magmatic sapphires contain syngenetic inclusions of columbite-group phases, zircon, spinel and rutile, some contain additional nepheline and K-feldspar, suggesting crystallization from more undersaturated alkaline magma while the Weldborough field of NE Tasmania also contains molybdenite and beryl, suggesting at least some interaction with more fractionated ‘granitic-type’ magmas. There is a large range in PT conditions calculated for the metamorphic rubies (from 780 to 940 °C, through 800 to 1150 °C up to 1000 to 1300 °C). Fluid/melt inclusion studies on magmatic corundums generally suggest that they formed in a CO₂-rich environment from a ‘syenitic’ melt under a range of T conditions from 720 to 880 °C up to 1000 to 1200 °C. Oxygen isotope studies reveal that typical magmatic corundums have values of + 4.4 to 6.9‰, whereas metamorphic corundums from the same basaltic host have lower values of + 1.3 to 4.2‰.Geochronological studies have shown that some fields produced a simple eruptive and zircon/corundum crystallization event while others had multiple eruptive events but only one or two zircon crystallization events. For a few fields, some corundums/zircons crystallized in storage regions and then remained relatively inert for periods of 200 to 400 Ma without significant change before transport to the surface in the Cenozoic. Tectonic studies of the Australian region suggest that many of the corundums crystallized from magmas related to episodic basaltic volcanism in a tectonic regime of extension, associated with the opening of the Tasman and Coral Seas. For the Asian region, the magmatic–polygenetic corundums within the basaltic fields largely crystallized in a tectonic regime of distributed E–W extension, whereas the metamorphic-metasomatic corundums crystallised in a transpressional regime associated with the collision of the Indian Plate with the Eurasian Plate (e.g., [Garnier, V., Giuliani, G., Maluski, H., Ohnenstetter, D., Deloule, E., 2003. Ar–Ar and U–Pb ages of marble-hosted ruby deposits from Central and South-east Asia. Geophysical Research Abstracts 5, 03751; Garnier, V., Giuliani, G., Ohnenstetter, D., and Schwarz, D., 2004. Les gisements de corindon: classification et genese. Les placers a corindon gemme. Le Regne Mineral 55, 7-47; Garnier, V., Ohnenstetter, D., Giuliani, G., Maluski, H., Deloule, E., Phan Trong, T., Pham Van, L., Hoang Quang, V., 2005a. Age and significance of ruby-bearing marble from the Red River Shear Zone, Northern Vietnam. Canadian Mineralogist 43, 1315–1329]).     

Estimating potential landslide sites of an upland sub-watershed in Western Ghat’s of Kerala (India) through frequency ratio and GIS

The purpose of this study is to assess the susceptibility of landslides in parts of Western Ghats, Kerala, India, using a geographical information system (GIS). Landslide inventory of the area was made by detailed field surveys and the analysis of the topographical maps. The landslide triggering factors are considered to be slope angle, slope aspect, slope curvature, slope length, distance from drainage, distance from lineaments, lithology, land use and geomorphology. ArcGIS version 8.3 was used to manipulate and analyse all the collected data. Probabilistic-likelihood ratio was used to create a landslide susceptibility map for the study area. The result was validated using the Area under Curve (AUC) method and temporal data of landslide occurrences. The validation results showed satisfactory agreement between the susceptibility map and the existing data on landslide locations. As the result, the success rate of the model was (84.46%) and the prediction rate of the model was (82.38%) shows high prediction accuracy. In the reclassified final landslide susceptibility zone map, 5.68% of the total area is classified as critical in nature. The landslide susceptibility map thus produced can be used to reduce hazards associated with landslides and to land cover planning.     

Timing of UHP metamorphism in the Hong’an area,western Dabie Mountains,China: evidence from zircon U–Pb age,trace element and Hf isotope composition

The Hong’an area (western Dabie Mountains) is the westernmost terrane in the Qinling-Dabie-Sulu orogen that preserves UHP eclogites. The ages of the UHP metamorphism have not been well constrained, and thus hinder our understanding of the tectonic evolution of this area. LA-ICPMS U–Pb age, trace element and Hf isotope compositions of zircons of a granitic gneiss and an eclogite from the Xinxian UHP unit in the Hong’an area were analyzed to constrain the age of the UHP metamorphism. Most zircons are unzoned or show sector zoning. They have low trace element concentrations, without significant negative Eu anomalies. These metamorphic zircons can be further subdivided into two groups according to their U–Pb ages, and trace element and Lu–Hf isotope compositions. One group with an average age of 239 ± 2 Ma show relatively high and variable HREE contents (527 ≥ Lu_N ≥ 14) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.00008–0.000931), indicating their growth prior to a great deal of garnet growth in the late stage of continental subduction. The other group yields an average age of 227 ± 2 Ma, and shows consistent low HREE contents and ¹⁷⁶Lu/¹⁷⁷Hf ratios, suggesting their growth with concurrent garnet crystallization and/or recrystallization. These two groups of age are taken as recording the time of prograde HP to UHP and retrograde UHP–HP stages, respectively. A few cores have high Th/U ratios, high trace element contents, and a clear negative Eu anomaly. These features support a magmatic origin of these zircon cores. The upper intercept ages of 771 ± 86 and 752 ± 70 Ma for the granitic gneiss and eclogite, respectively, indicate that their protoliths probably formed as a bimodal suite in rifting zones in the northern margin of the Yangtze Block. Young Hf model ages (T _DM1) of magmatic cores indicate juvenile (mantle-derived) materials were involved in their protolith formation. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.