Evaluation of Interactions Between Oilfield Chemicals and Reservoir Rocks

Natural Resources Research - Sand failure and production occurs when the formation stress exceeds the strength of the formation, which is derived majorly from the natural material that cements the...     

Diurnal variation in rates of calcification and carbonate sediment dissolution in Florida Bay

Water quality and criculation in Florida Bay (a shallow, subtropical estuary in south Florida) are highly dependent upon the development and evolution of carbonate mud banks distributed throughout the Bay. Predicting the effect of natural and anthropogenic perturbations on carbonate sedimentation requires an understanding of annual, seasonal, and daily variations in the biogenic and inorganic processes affecting carbonate sediment precipitation and dissolution. In this study, net calcification rates were measured over diurnal cycles on 27 d during summer and winter from 1999 to 2003 on mud banks and four representative substrate types located within basins between mud banks. Substrate types that were measured in basins include seagrass beds of sparse and intermediate densityThalassia sp., mud bottom, and hard bottom communities. Changes in total alkalinity were used as a proxy for calcification and dissolution. On 22 d (81%), diurnal variation in rates of net calcification was observed. The highest rates of net carbonate sediment production (or lowest rates of net dissolution) generally occurred during daylight hours and ranged from 2.900 to −0.410 g CaCO₃ m⁻²d⁻¹. The lowest rates of carbonate sediment production (or net sediment dissolution) occurred at night and ranged from 0.210 to −1.900 g CaCO₃ m⁻² night⁻¹. During typical diurnal cycles, dissolution during the night consumed an average of 29% of sediment produced during the day on banks and 68% of sediment produced during the day in basins. Net sediment dissolution also occurred during daylight, but only when there was total cloud cover, high turbidity, or hypersalinity. Diurnal variation in calcification and dissolution in surface waters and surface sediments of Florida Bay is linked to cycling of carbon dioxide through photosynthesis and respiration. Estimation of long-term sediment accumulation rates from diurnal rates of carbonate sediment production measured in this study indicates an overall average accumulation rate for Florida Bay of 8.7 cm 1000 yr⁻¹ and suggests that sediment dissolution plays a more important role than sediment transport in loss of sediment from Florida Bay.     

Comparing the Correlative Holdridge Model to Mechanistic Biogeographical Models for Assessing Vegetation Distribution Response to Climatic Change

A well-established and widely used correlative climate-vegetation model (Holdridge Life Zone model) was compared to three mechanistic simulation models (BIOME2, Dynamic Global Phytogeography Model (DOLY), and Mapped Atmosphere-Plant-Soil System (MAPSS)) for the conterminous United States under contemporary climate and a set of future climates prescribed by three Global Circulation Model experiments. Output from the mechanistic models were from the Vegetation/Ecosystem Modeling and Analysis Project (VEMAP) intercomparison. Holdridge modeling approaches, using a Simple implementation (vegetation distribution based on biotemperature and precipitation alone) or a Full implementation (vegetation distribution based on biotemperature, precipitation, altitudinal region, latitudinal belt, and transitional vegetation zones), represented current potential natural U.S. vegetation poor to fair, respectively. The more sophisticated mechanistic models were superior at reproducing potential vegetation under current climate compared to Holdridge, although there was significant variability among these models. The Holdridge implementations generally showed similar or greater climate sensitivity with respect to spatial redistribution of vegetation compared to the mechanistic models run both with and without doubled CO₂ levels; however, the sensitivity of the Holdridge model depended on the implementation. Reduced sensitivity of the mechanistic models arises from direct (physiological) CO₂ effects and other compensating feedbacks not captured by the Holdridge model. The greater degree of physical realism in the mechanistic models makes them the model class of choice for climate impact assessment. However, under circumstances of limited data availability, computation resources, and access to mechanistic models and model expertise, simple correlational models such as Holdridge may be the only method that can be applied. The paper makes some recommendations on the use of the Holdridge model for impact assessment if it is the only available model.     

The tidal range energy potential of the West Coast of the United Kingdom

With concerns mounting over the UK’s energy future and the effects of climate change, it will soon become paramount that all viable sources of renewable energy are fully exploited. This study has examined the scope for reliable and fully predictable tidal electricity generation from the conjunctive operation of 5 major estuary barrages on the West Coast of the UK in an attempt to establish the potential scale of the extractable resources. Two levels of investigation have been undertaken: simple 0-D (‘two-tank’) modelling of barrage energy generation under different operational modes, using the hydraulic characteristics of turbine performance; and 2-D modelling of tidal hydrodynamics over a wide sea area in a computational grid incorporating the barrages with turbines and sluices. It has been demonstrated that more than 33TWh per year of electricity should be attainable, from 22GW of installed capacity, this representing close to 10% of present UK demand.     

Modelling line profiles in infalling cores

Results are presented from a model of molecular line formation in collapsing star-forming cores. The study includes, for the first time, a self-consistent chemical and dynamical model which is then directly coupled to an appropriate radiative transfer model. The assumptions of chemical uniformity or simple monotonic variations within such cores are shown to be unacceptable. The results show that the abundance variations and the line profiles are highly sensitive to the assumed values of the free parameters in the chemical model. Extreme caution is therefore advised in the quantitative analysis of emission-line profiles from infall sources. The implied degeneracy can be overcome by multiple line-of-sight observations of many species and transitions.     

Acoustic inversion of bottom reflectivity and bottom sound-speedprofile

This paper applies a full-field technique to invert bottom sound profile and bottom reflectivity from simulated acoustic data in a shallow water environment. Bottom sound-speed profile and bottom reflectivity have been traditionally estimated using seismic reflection/refraction techniques when acoustic ray paths and travel time can be identified and measured from the data. However, in shallow water, the many multipaths due to bottom reflection/refraction make such identification and measurement rather difficult. A full-field inversion technique is presented here that uses a broad-band source and a vertical array for bottom sound-speed and reflectivity inversion. The technique is a modified matched field inversion technique referred to as matched beam processing. Matched beam processing uses conventional beamforming processing to transform the field data into the beam domain and correlate that with the replica field also in the beam domain. This allows the analysis to track the acoustic field as a function of incident/reflected angle and minimize contamination or mismatch due to sidelobe leakage     

Simulating H2O Maser Emission in the Mass Outflows from Evolved Stars

The combination of a time-dependent spherically symmetric hydrodynamic model of stellar atmosphere pulsation and a radiation transport code, which incorporates maser saturation theory, enabled us to synthesise maps and spectra of H₂O maser emission from the circumstellar envelopes of long period variable stars. The synthetic maps and spectra compare favourably with observed 22, 321 and 325 GHz H₂O maser emission. As is observed in H₂O maser regions the peak emission occurs between 3–8 stellar radii from the star. The calculated H₂O maser regions are in conditions of n_H2 = 10⁶ − 10⁸ cm⁻³, assuming a fractional abundance of 10⁻⁴; kinetic temperatures of 550–3000 K; dust ensemble temperatures of 500–1200 K and an accelerating velocity field. The IR radiation field is explicitly included in the radiation transport model, incorporating the latest absorption efficiency data for silicates from Draine. We reproduce the features seen in high angular resolution MERLIN spectral line datacubes. This shows that a mass outflow model which extends the photosphere using pulsations and incorporates radiation pressure on silicate based dust particles can produce the observed data on small (10-mas) angular scales. This revised version was published online in September 2006 with corrections to the Cover Date.