Repercussions of solar high energy protons on ozone layer during super storms

We are very aware of the importance of the ozone layer, without which life on the Earth would not have evolved in the way it has. Solar storms carry energetic protons into the Earth's upper atmosphere,where they boost production of nitrogen oxides which are known as ozone killers and which ultimately increase ultraviolet(UV) radiations. In the present study, we estimate the effects of solar energetic protons during super storms(Dst index -300 nT) over the total ozone column for the last 32 yr. We select a total of seven super storm events that occurred during solar cycles 22–24(for the last 32 yr) having Dst index -300 nT. To that end, we apply superposed epoch analysis(SEA) to verify the impact of storm events on the quantitative variation of total ozone column and on UV radiations during super storm events.After completing the empirical analysis, we conclude that the ozone column gets depleted significantly(22±6.8%) as proton density increases during super storm events and this decrement in the ozone level is further responsible for a substantial increase(26±11.2%) in peak UV radiation intensities.     

Nature and Estimated Human Toxicity of Polar Metabolite Mixtures in Groundwater Quantified as TPHd/DRO at Biodegrading Fuel Release Sites

Polar metabolites resulting from petroleum biodegradation are measured in groundwater samples as TPHd unless a silica gel cleanup (SGC) is used on the sample extract to isolate hydrocarbons. Even though the metabolites can be the vast majority of the dissolved organics present in groundwater, SGC has been inconsistently applied because of regulatory concern about the nature and toxicity of the metabolites. A two‐step approach was used to identify polar compounds that were measured as TPHd in groundwater extracts at five sites with biodegrading fuel sources. First, gas chromatography with mass spectrometry (GC‐MS) was used to identify and quantify 57 individual target polar metabolites. Only one of these compounds—dodecanoic acid, which has low potential human toxicity—was detected. Second, nontargeted analysis was used to identify as many polar metabolites as possible using both GC‐MS and GC×GC‐MS. The nontargeted analysis revealed that the mixture of polar metabolites identified in groundwater source areas at these five sites is composed of approximately equal average percentages of organic acids, alcohols and ketones, with few phenols and aldehydes. The mixture identified in downgradient areas at these five sites is dominated by acids, with fewer alcohols, far fewer ketones, and very few aldehydes and phenols. A ranking system consistent with systems used by USEPA and the United Nations was developed for evaluating the potential chronic oral toxicity to humans of the different classes of identified polar metabolites. The vast majority of the identified polar metabolites have a “Low” toxicity profile, and the mixture of identified polar metabolites present in groundwater extracts at these five sites is unlikely to present a significant risk to human health.     

A new generalized soil thermal conductivity model for sand–kaolin clay mixtures using thermo-time domain reflectometry probe test

As the demand of exploitation and utilization of geothermal energy increases, more geothermal-related earth structures occur recently. The design of the structures depends upon an accurate prediction of soil thermal conductivity. The existing soil thermal conductivity models were mostly developed by empirical fits to datasets of soil thermal conductivity measurements. Due to the gaps in measured thermal conductivities between any two tested natural soils, the models may not provide accurate prediction for other soils, and the predicted thermal conductivity might not be continuous over the entire range of soil type. In this research, a generalized soil thermal conductivity model was proposed based on a series of laboratory experiments on sand, kaolin clay and sand–kaolin clay mixtures using a newly designed thermo-time domain reflectometry probe. The model was then validated with respect to k _dry–n (thermal conductivity of dry soils and porosity) and k _r–S _r (normalized thermal conductivity and degree of saturation) relationships by comparing with previous experimental studies. The predicted thermal conductivities were found to be in a good agreement with the experimental data collected from both this study and the other literatures with at least 85% confidence interval. It is concluded that the proposed model accounts for the effects of both environmental factors (i.e., moisture content and dry density) and compositional factors (i.e., quartz content and soil type) on soil thermal conductivity, and it has a great potential in predicting soil thermal conductivity more accurately for geothermal applications.     

Density and temperature diagnostics of solar emission lines from Navii and Alix

Line intensity ratios of EUV emission lines from Navii and Alix have been considered for electron density and temperature determinations within the chromosphere-corona transition region and the corona. The electron pressure within the emission region has been assumed to be a constant parameter. Theoretical line intensities for these ions have been computed using a model solar atmosphere and compared with the values as observed by ATM ultraviolet spectrometer. The observed intensities correspond to the average quiet-Sun conditions near solar minimum.     

Density and temperature diagnostics of solar emission lines from NeVI and MgVI

Line intensity ratios of NeVI lines with respect to a resonance line of MgVI have been considered for electron density and temperature determinations within the chromosphere-corona transition region. The electron pressure within the transition region has been assumed to be constant. In addition, these ratios would enable us to estimate the relative element abundances of neon to magnesium. An attempt has been made to explain the extreme ultraviolet intensities of NeVI and MgVI lines as observed by ATM ultraviolet spectrometer. The observed intensities correspond to the average quiet-Sun conditions near solar minimum. Theoretical intensities for NeVI and MgVI lines have been computed using a model solar atmosphere. Theoretical intensities obtained by using the values 3.98 × 10^–5 and 3.16 × 10^–5 for element abundance of Ne and Mg, respectively, seem to agree well with the expected intensities. The agreement between some of the expected and computed intensities suggests the need for future observations at higher spectral resolutions to resolve difficulties arising out of blending due to two or more lines.