Growth of large sulfide structures on the endeavour segment of the Juan de Fuca ridge

Mapping and sampling with DSRV “Alvin” has established that sulfide blocks 0.5 m across, dredged from the axial valley of the Endeavour Segment at 47°57′N, are samples of unusually large sulfide structures. The steep-sided structures, up to 30 m in length, 20 m in height, and 10–15 m across, are localized by venting along normal faults at the base of the western axial valley wall, and are distributed for about 200 m along strike paralleling the 020 trend of the ridge crest. High-temperature fluids (350 to more than 400°C) pass through the massive sulfide structures and enter seawater through small, concentric “nozzle-like” features projecting from the top or the sides of the larger vent structures. Diffuse, low-temperature flow is pervasive in the vicinity of the active sulfide structures, exiting from basalt and sulfide surfaces alike. Evidence of recent volcanic activity is sparse.The two largest samples taken with the dredge would not have been recoverable using the submersible. These samples represent massive, complex portions of the sulfide structures which were not closely associated with rapid high-temperature fluid flow at the time of sampling; they contain textural evidence of sealed hydrothermal fluid exit channels. Mineralogy is dominated by Fe sulfides nnd amorphous silica. Pyrite, marcasite, wurtzite, chalcopyrite, and iss are the most common sulfide phases. Pyrrhotite, galena, and sphalerite are present in trace amounts. Barite, amorphous silica, and chalcedony are the only non-sulfide phases; anhydrite is not observed in any of the dredge samples, although it is common in the chimney-like samples recovered by “Alvin”.Specific mineralogical-textural zones within the dredge samples are anaoogous to individual layers in East Pacific Rise at 21°N and southern Juan de Fuca Ridge samples, with two exceptions: a coarse-grained, highly porous Fe sulfide-rich interior containing sulfidized tubeworm casts, and a 2–5 cm thick zone near the outer margin of the samples dominated by late stage amorphous silica. The porous interior may have formed by dendritic crystal growth from a slowly circulating fluid within a large enclosed chamber. The amorphous silica deposited from a seawater/hydrothermal fluid mixture percolating slowly through the walls of the enclosed chamber; conductive cooling of the fluid as it traversed the walls allowed amorphous silica to precipitate. These silica-rich zones are the densest, most durable portions of the structures and may be responsible for the lasting stability of the large sulfide features.Observations in these samples are consistent with two distinct phases of development. Phase 1 is analogous to chimney growth and construction at 21°N and ends when flow channels become sealed to rapid flow of through-going fluid. The flow is evidently redirected within the structure. Phase 2 includes dissolution of anhydrite and precipitation of amorphous silica during conductive cooling of sluggishly circulating hydrothermal fluid or seawater/hydrothermal fluid mixtures. Evolution of vent structures through phase 2 allows lateral and vertical growth of unusually large structures.     

A dual sensor device to estimate fluid flow velocity at diffuse hydrothermal vents

Numerous attempts have been made over the last thirty years to estimate fluid flow rates at hydrothermal vents, either at the exit of black smoker chimneys or within diffuse flow areas. In this study, we combine two methods to accurately estimate fluid flow velocities at diffuse flow areas. While the first method uses a hot film anemometer that performs high-frequency measurements, the second allows a relatively rapid assessment of fluid flow velocity through video imagery and provides in situ data to calibrate the sensor. Measurements of flow velocities on hydrothermal diffuse flow areas were obtained on the Mid-Atlantic Ridge (MAR). They range from 1.1 to 4.9 mm/s at the substratum level, in low-temperature (4.5–16.4 °C) diffuse flow areas from the Tour Eiffel sulfide edifice. A strong correlation was observed between fluid flow velocities and temperature, supporting the possible use of temperature as a proxy to estimate the flow rates in diffuse flow areas where such a simple linear flow/temperature relation is shown to dominate.     

A submersible study in the western Blanco fracture Zone,N.E. Pacific: Structure and evolution during the last 1.6 Ma

During July and August 1991, the French-American Blanconaute dive program used the French submersibleNautile to investigate the West Blanco Depression (WBD), a deep, elongate trough located at the intersection of the Blanco Transform Fault Zone with the southern Juan de Fuca Ridge (JdFR). Twenty dives were carried out along the north wall of the WBD, which exposes the upper oceanic crust over a 65 km distance, from the JdFR axis (to the west) to the oblique trace of an ancient propagator (to the east, crustal age around 2 Ma). Thirteen of these dives were precisely located within a 13 × 7 km zone of the north wall, covered by a high-resolution sonar mapping operation during the Blancotrough cruise in 1987. This series of geological traverses, plus 4 dives across the south wall of the WBD (one dive) and the adjacent Parks Plateau (3 dives), collected 242 rock samples. We report here the main results of the dive program and preliminary laboratory studies:

1. Transform-related tectonic activity has recently abandoned the southern margin of Parks Plateau, and is presently located inside the WBD area, mainly along its northern wall. The tectonic features observed are compatible with a right-lateral strike-slip system, with a NE-SW extensional component.
2. Three main lithological units are exposed along the north wall of the WBD. From top to bottom, they are: (1) a Volcanic Unit, forming a steep upper cliff, made of massive and pillow flows and basaltic dikes, with an estimated average thickness of 800 m; (2) a less steep Transition Zone, about 150 to 400 m thick, largely masked by rubble but exposing both diabase outcrops and pillow flows; and (3) a massive Diabase Unit, exposed over 700–800 m, with a dike complex structure visible from place to place, and cut by a net of hydrothermal veins. Deep crustal rocks such as gabbros were not observed.
3. Spectacular mass-wasting features are visible all along the north wall of the WBD. About 60% of the face of the wall is masked by talus cones, rubble, rock avalanche deposits and slide blocks. Three main landslides, of approximately one km³ in volume each, were tentatively identified. One of them was mapped in detail and consists of an approximately 300 m thick (0.85 km³), coherent slide block detached from a zone where intense hydrothermal alteration and faulting have obviously weakened the bedrock, that is in places entirely altered to blue clays.
4. The basaltic lavas of the WBD north wall show a remarkable evolution with time, from east to west. Around the tip of the ancient propagator, they are restricted to primitive, olivine-rich picritic basalts. Proceeding westward, they exhibit a wide range of differentiation, including highly fractionated, FeTi-rich ferrobasalts at about 35–45 km from the JdFR axis. When approaching the JdFR axis, the FeTi enrichment decreases gradually, and the ferrobasalts evolve towards slightly differentiated MORB-type basalts, typical of the southern JdFR. This magmatic evolution marks the transition from the end of a propagating rift regime to a steady-state accretion regime.
5. The WBD north wall also permits the study of weathering and hydrothermal alteration processes and their evolution in space and time. Vertically, the alteration products evolve from oceanic weathering and zeolite facies (Volcanic Unit) to the greenschist facies (Transition Zone and Diabase Unit). Horizontally, the evolution with time is mainly a general hydration of the crust that is, however, very irregularly distributed.
6. Several vertical magnetic traverses along the north wall of the WBD, using a bottom magnetometer attached to the basket of the submersible, have shown a sharp 5000 to 7000 nT positive anomaly at about 3500 m depth. This anomaly corresponds exactly to the first appearance of extrusive pillow-lava outcrops, and confirms the dramatic decrease in magnetic anomaly amplitude below that depth, detected during the Blancotrough cruise in 1987. The vertical magnetic profiles thus appear to have imaged the base of the magnetic source layer.

     

A submersible study of the western intersection of the Mid-Atlantic ridge and Kane fracture zone (WMARK)

In 1994, a joint Japanese-American dive program utilizing the worlds deepest diving active research submersible (SHINKAI 6500) was carried out at the western ridge-transform intersection (RTI) of the Mid-Atlantic Ridge and Kane transform in the central North Atlantic Ocean. A total of 15 dives were completed along with surface-ship geophysical mapping of bathymetry, magnetic and gravity fields. Dives at the RTI traced the neovolcanic zone up to, and for a short distance (2.5 km) along, the Kane transform. At the RTI, the active trace of the transform is marked by a narrow valley (<50 m wide) that separates the recent lavas of the neovolcanic zone from the south wall of the transform. The south wall of the transform at the western RTI consists of a diabase section near its base between 5000 and 4600 m depth overlain by basaltic lavas, with no evidence of gabbro or deeper crustal rocks. The south wall is undergoing normal faulting with considerable strike-slip component. The lavas of the neovolcanic zone at the RTI are highly magnetized (17 A m^–1) compared to the lavas of the south wall (4 A m^–1), consistent with their age difference. The trace of the active transform changes eastwards into a prominent median ridge, which is composed of heavily sedimented and highly serpentinized peridotites. Submersible observations made from SHINKAI find that the western RTI of the Kane transform has a very different seafloor morphology and lithology compared to the eastern RTI. Large rounded massifs exposing lower crustal rocks are found on the inside corner of the eastern RTI whereas volcanic ridge and valley terrain with hooked ridges are found on the outside corner of the eastern RTI. The western RTI is much less asymmetric with both inside and outside corner crust showing a preponderance of volcanic terrain. The dominance of low-angle detachment faulting at the eastern RTI has resulted in a seafloor morphology and architecture that is diagnostic of the process whereas crust formed at the WMARK RTI must clearly be operating under a different set of conditions that suppresses the initiation of such faulting.     

Chemistry of hot springs along the Eastern Lau Spreading Center

The Eastern Lau Spreading Center (ELSC) is the southernmost part of the back-arc spreading axis in the Lau Basin, west of the Tonga trench and the active Tofua volcanic arc. Over its 397-km length it exhibits large and systematic changes in spreading rate, magmatic/tectonic processes, and proximity to the volcanic arc. In 2005, we collected 81 samples of vent water from six hydrothermal fields along the ELSC. The chemistry of these waters varies both within and between vent fields, in response to changes in substrate composition, temperature and pressure, pH, water/rock ratio, and input from magmatic gases and subducted sediment. Hot-spring temperatures range from 229° to 363 °C at the five northernmost fields, with a general decrease to the south that is reversed at the Mariner field. The southernmost field, Vai Lili, emitted water at up to 334 °C in 1989 but had a maximum venting temperature of only 121 °C in 2005, due to waning activity and admixture of bottom seawater into the subseafloor plumbing system. Chloride varies both within fields and from one field to another, from a low of 528 mmol/kg to a high of 656 mmol/kg, and may be enriched by phase separation and/or leaching of Cl from the rock. Concentrations of the soluble elements K, Rb, Cs, and B likewise increase southward as the volcanic substrate becomes more silica-rich, especially on the Valu Fa Ridge. Iodine and δ⁷Li increase southward, and δ¹¹B decreases as B increases, apparently in response to increased input from subducted sediment as the arc is approached. Species that decrease southward as temperature falls are Si, H₂S, Li, Na/Cl, Fe, Mn, and ⁸⁷Sr/⁸⁶Sr, whereas pH, alkalinity, Ca, and Sr increase. Oxygen isotopes indicate a higher water/rock ratio in the three systems on Valu Fa Ridge, consistent with higher porosity in more felsic volcanic rocks. Vent waters at the Mariner vent field on the Valu Fa Ridge are significantly hotter, more acid and metal-rich, less saline, and richer in dissolved gases and other volatiles, including H₂S, CO₂, and F, than the other vent fields, consistent with input of magmatic gases. The large variations in geologic and geophysical parameters produced by back-arc spreading along the ELSC, which exceed those along mid-ocean ridge spreading axes, produce similar large variations in the composition of vent waters, and thus provide new insights into the processes that control the chemistry of submarine hot springs.     

Deep-sea mining of seafloor massive sulfides

The potential emergence of an ocean mining industry to exploit seafloor massive sulfides could present opportunities for oceanographic science to facilitate seafloor mineral development in ways that lessen environmental harms.     

Observation of sections of oceanic crust and mantle cropping out on the southern wall of Kane FZ (N. Atlantic)

The objective of the 20 Nautile dives of the recent Kanaut cruise was to study the southern wall of the Kane Fracture Zone from its eastern intersection with the Mid-Atlantic Ridge (MAR) to 5 Myr in age. The geological mapping shows four successive massifs, wrench faulted and slightly tilted. The transform-facing walls of these massifs exhibit outcrops of fresh and serpentinized peridotites, gabbros and basalts. The entire crustal exposure is cataclased and metamorphosed to greenschist facies.