Groundwater salinity in Greve, Denmark: determining the source from historical data

Elevated salinity in groundwater (over 250?mg/l chloride) in a fractured chalk aquifer in the municipality of Greve, Denmark, has been attributed to seawater intrusion from the Baltic Sea, resulting in the closure of a number of wells nearest to the coastline. However, a recent study in eastern Denmark shows that the salinity could also be from ancient connate pore waters. Historical chemistry data from bulk-water samples collected from wells have been used to determine the source. The sample data were studied with respect to their historical changes and temporal trends in chloride, carbonate, sulfate, sodium, potassium, magnesium, and calcium. Wells in the southern third of the municipality are relatively low in sodium and carbonate and high in chloride and calcium/magnesium, indicating waters undergoing saline intrusion. Wells in the northern two-thirds of the municipality are high in carbonate and sodium, but low in chloride and calcium/magnesium, indicating a freshening of the aquifer. This is confirmed by the temporal trends in chloride, where chloride levels in the northern wells remain constant, whereas in the south, chloride increases as abstraction continues. Therefore close monitoring for seawater intrusion should be conducted in the southern third of the municipality.     

Bedrock freeze-thaw weathering regime in an alpine environment,colorado front range

Reduced major axis analysis is used to describe monthly temperature averages for daily maxima, minima, means and ranges at a sequence of bedrock microenvironments in the alpine zone of the Colorado Front Range. Seven thermistors buried at 1 cm in bedrock provide comparative data on easterly, southerly and westerly aspects, and also upon the impact of snow accumulation (?0.5m to ≥4.0m deep) against an east-facing rock wall. Intersite temperatures commonly differ by less than 5°C and, rarely, by more than 10°C. The freezing intensity of freeze-thaw cycles occurring within the confines of a seasonal snow patch rarely dropped to ?5°C, while at snowfree, vertical faces freezing dropped to ?5°C quite commonly. Comparison with laboratory established criteria for effective freeze-thaw weathering (abundant moisture and freezing to at least ?5°C) suggests that moisture rich microsites lack adequate freezing intensity, while adequately frozen sites lack moisture. Available data suggest that the overlap between freeze-thaw and hydration weathering requires careful re-evaluation.     

Chemical denudation rates in Kärkevagge, Swedish Lapland

This study examines the spatial and temporal variability of chemical denudation rates in Kärkevagge, northern Sweden. The chemical flux rates within the valley are strongly influenced by the local geology. Chemical denudation rates determined for the study period are more than double those previously reported in the literature for this valley. Rates of greater than 46t km⁻² a⁻¹ were measured at the valley mouth over the course of the melt season. This difference is likely due to differences in measurement technique compared to that used by past researchers. This rate is also much higher than for other arctic and alpine watersheds. Chemical denudation in Kärkevagge is comparable to larger temperate rivers. The rapid chemical denudation in Kärkevagge is likely due to sulfide weathering creating acid solutions.     

Enigmatic Efflorescence in Kärkevagge, Swedish Lapland: The Key to Chemical Weathering?

The second marvel to catch the eye of the visitor to Kärkevagge, after the impressive boulder deposit on the floor of the valley, is the series of prominent white stripes running down the valley's dark cliffs. Streams and springs descending the eastern flank of Kärkevagge are marked by the presence of whitish coatings on the black rock surfaces and on cobbles lining ephemeral waterways. These were referred to as 'lime crusts' by early investigators, but they are not reactive to HCl. We believe that they are a precipitate resulting from acid attack on the local rocks. Pyrite is common in many of the rocks in the valley and its oxidation produces sulfuric acid. As the dissolved mineral elements are carried in the drainage water, efflorescence forms on the surfaces where the water flows due to evaporation or to changes in temperature. The exact mineralogy of the white crusts is unknown, but the crusts are dominated by Al, S, and O, and in some cases by Ca, depending on the substrate and local conditions. Gypsum, illite, and chlorite have been identified by X–ray diffraction of some scrapings of white–coated rocks. However, we believe that some unidentified oxy–hydroxy aluminum sulfates make up the bulk of the precipitates.     

Incipient weathering rind development on introduced machine‐polished granite discs in an Arctic alpine environment,northern Scandinavia

Weathering rinds, zones of alteration on the exterior surfaces of rock outcrops and coarse unconsolidated surficial debris are widely used by geomorphologists and Quaternary geologists as indicators of the relative age of landforms and landscapes. Additionally they provide unique insights into the earliest stages of rock and mineral weathering, yet the origin of these alteration zones is relatively poorly understood. This lack of understanding applies especially to the initial stages of rind formation. The study reported in this paper has two principal objectives. The first is to use lightly polished granite discs inserted in soil profiles under several different plant communities in an Arctic alpine environment for a period of four or five years to investigate the nature of incipient weathering rind development. The second is to investigate the factors responsible for spatial variability in the nature and rates of rind formation. Incipient weathering rind development on the outer edges of the granite discs is observable and measurable over a period of time as short as four years in the mild Arctic alpine environment of Swedish Lapland. The earliest stages of rind development involve the development of a porous structure consisting of a combination of pits and fractures which have been solutionally enlarged and modified. Solution appears to be preferentially concentrated on the surfaces of feldspars and, to a lesser extent, quartz. In addition, iron oxides are present along grain boundaries and in grain interiors and are interpreted to have been derived from the oxidation of ferromagnesian minerals. Spatial variability in weathering rind development appears to be particularly driven by differences in moisture but is not related to soil pH. Copyright © 2005 John Wiley & Sons, Ltd.     

CHEMICAL WEATHERING PROCESSES ON THE VANTAGE PEAK NUNATAK,JUNEAU ICEFIELD,SOUTHERN ALASKA

On the Vantage Peak nunatak in the Juneau Icefield of southeastern Alaska, grus and soils display evidence of extensive chemical alteration in a self-evidently periglacial environment. Accompanying the alteration of bedrock to grus and soil is a decrease in grain size. Grus is dominated by very coarse sand while the soils are predominantly fine sand. Grain-size reduction is attributed primarily to mineral grain dissolution. Total chemical analyses show that alkali earths (calcium and magnesium) and alkalis (sodium and potassium) are lost as weathering progresses, while silicon and iron increase relative to resistant elements. Secondary clay minerals present in the grus and soils appear to have been derived from clay-size primary minerals. Vermiculite is the principal secondary clay mineral and appears to have formed by the alteration of biotite. Scanning electron microscopy shows that quartz and feldspars are primarily weathered by dissolution with no evidence of feldspar transformation to secondary clays. Superimposed on these weathering transformations is evidence of eolian processes. Chemical weathering processes, notably dissolution and clay mineral transformation, do occur in the periglacial environment of the Vantage Peak nunatak and are clearly an important component of the periglacial geomorphic process suite.     

Spatial variation of early season surface water chemistry in Kärkevagge, Swedish Lapland

This study examines the spatial variability of early season water chemistry in the arctic-alpine valley of Kärkevagge, Sweden. The data demonstrate the spatially heterogeneous nature of water chemistry and the general patterns of chemical weathering in the valley. Water chemistry in this valley is dominated by two anions, bicarbonate and sulfate. Bicarbonate is derived from the dissolution of atmospheric CO₂ and the weathering of carbonate units in the local metamorphic rocks, while the sulfate is derived from the oxidation of pyrite in the Seve-Koli tectonic nappe. Spatial patterns of chemical constituents reflect the broad effects of local geology on surface water chemistry. In particular, they demonstrate the effects that mineral species present in minor amounts have on basin-wide water chemistry. However, solute flux rates derived from water chemistry and discharge demonstrate less variability.     

Medical imaging: examples of clinical applications

Clinical routine is currently producing a multitude of diagnostic digital images but only a few are used in therapy planning and treatment. Medical imaging is involved in both diagnosis and therapy. Using a computer, existing 2D images can be transformed into interactive 3D volumes and results from different modalities can be merged. Furthermore, it is possible to calculate functional areas that were not visible in the primary images. This paper presents examples of clinical applications that are integrated into clinical routine and are based on medical imaging fundamentals. In liver surgery, the importance of virtual planning is increasing because surgery is still the only possible curative procedure. Visualisation and analysis of heart defects are also gaining in significance due to improved surgery techniques. Finally, an outlook is provided on future developments in medical imaging using navigation to support the surgeon's work. The paper intends to give an impression of the wide range of medical imaging that goes beyond the mere calculation of medical images.     

Near–surface ground temperature regime variability in selected microenvironments, Kärkevagge, Swedish Lapland

The importance of topographic microvariability in influencing shallow (10–50 cm depths) soil temperature regimes in arctic–alpine Kärkevagge, northern Sweden, from August 1999 to July 2000 is demonstrated using six sites. The ground microclimate on the tops of very large boulders forming an extensive boulder field in the central valley bottom is more comparable to that at an alpine ridge–crest site 300 m higher than it is to the microclimate at the base of one of the boulders. The boulder crests also differ substantially from the more generalized valley–bottom conditions outside the boulder field. Assuming that chemical processes may be active at temperatures at or above 0°C, sites in the valley experience favorable conditions from 159 to 324 days of the year. Aside from the annual cycle, freeze–thaw cycles are infrequent within Kärkevagge.