Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.     

Temperature effects on non-bridging oxygen and aluminum coordination number in calcium aluminosilicate glasses and melts

Configurational changes with temperature are important for the thermodynamic and transport properties of most aluminosilicate melts, but in general are not well understood. Here, we present high-resolution ²⁷Al and ¹⁷O NMR data on several calcium aluminosilicate glasses prepared with varying quench rates and thus with fictive temperatures that span ranges up to about 200 K. In all compositions the content of five-coordinated aluminum increases with fictive temperature, in agreement with recent high temperature NMR data on melts. In a glass of CaAl₂Si₂O₈ (“anorthite”) composition, the content of non-bridging oxygens also increases with temperature; however this effect was not observed in a sample with a much higher CaO/Al₂O₃ ratio. We present a consistent notation for reactions among structural species in these systems that clarify why in some cases, high-coordinated network cations may appear on the same side of the reaction, while in others they occur on the opposite sides: the key difference is in accounting for all coordination changes for oxygens. Mixing of non-bridging oxygens and of high-coordinated aluminum make significant contributions to the overall configurational entropy and heat capacity of the melts, as does the mixing of various bridging oxygens and of tetrahedral network cations. Other, less well known, types of increase in disorder with temperature may be important as well.     

Convection induced by cooling at one side wall in two-dimensional non-rotating fluid —applicability to the deep Pacific circulation—

In recognition that similarity in the density balance leads to resemblance in circulation between the two-dimensional non-rotating and three-dimensional rotating systems which have similar density stratification, we investigate convection induced by cooling at one side wall and heating at the sea surface by using a two-dimensional non-rotating model as idealized representation for the deep Pacific circulation. In the model, various vertical profiles are taken for the side wall cooling, which are assumed to correspond to the density structure of the Anatarctic Circumpolar Current. In a small diffusivity range, two important features are found to be robust against change in the vertical profile of the side wall cooling. One is that the density stratification is horizontally almost uniform. The other is that the balance in the density equation between the vertical advection and the vertical diffusion holds in the interior. Consequently, the vertical density balance, together with the equation of continuity, determines the circulation pattern for the prescribed vertical profile of the side wall cooling. The multi-layered meridional flow, which is expected to exist in the deep Pacific, is shown to form for certain vertical profiles of the side wall cooling.     

Convergence,divergence and vertical velocity at a tidal front in Hiuchi-Nada,Japan

The detailed flow structure around a tical front in Hiuchi-Nada, Japan was observed with the use of ADCP (Acoustic Doppler Current Profiler). The surface convergence region is observed at the transition zone between vertically well mixed area and the stratified area. The surface divergence regions exist next to the surface convergence region. The strong downward current is estimated in the middle layer just below the surface convergence region. The maximum surface convergence and the maximum downward velocity in the middle layer are 1.0×10^–4 s^–1 and 0.12 cm s^–1, respectively.     

Northward transport of pacific summer water along the Northwind Ridge in the Western Arctic Ocean

The recent sea-ice reduction in the Arctic Ocean is not spatially uniform, but is disproportionally large around the Northwind Ridge and Chukchi Plateau compared to elsewhere in the Canada Basin. In the Northwind Ridge region, Pacific Summer Water (PSW) delivered from the Bering Sea occupies the subsurface layer. The spatial distribution of warm PSW shows a quite similar pattern to the recent ice retreat, suggesting the influence of PSW on the sea-ice reduction. To understand the regionality of the recent ice retreat, we examine the dynamics and timing of the delivery of the PSW into this region. Here, we adopt a two-layer linearized potential vorticity equation to investigate the behavior of Rossby waves in the presence of a topographic discontinuity in the high latitude ocean. The analytical results show a quite different structure from those of mid-latitude basins due to the small value of β. Incident barotropic waves excited by the sea-ice motion with large annual variation can be scattered into both barotropic and baroclinic modes at the discontinuity. Since the scattered baroclinic Rossby wave with annual frequency cannot propagate freely, a strong baroclinic current near the topographic discontinuity is established. The seasonal variation of current near the topographic discontinuity would cause a kind of selective switching system for shelf water transport into the basin. In our simple analytical model, the enhanced northward transport of summer water and reduced northward transport of winter water are well demonstrated. The present study indicates that these basic dynamics imply that a strengthening of the surface forcing during winter in the Canada Basin could cause sea-ice reduction in the Western Arctic through the changes of underlying Pacific Summer Water.     

Responses of phytoplankton and heterotrophic bacteria in the northwest subarctic Pacific to in situ iron fertilization as estimated by HPLC pigment analysis and flow cytometry

To verify the hypothesis that the growth of phytoplankton in the Western Subarctic Gyre (WSG), which is located in the northwest subarctic Pacific, is suppressed by low iron (Fe) availability, an in situ Fe fertilization experiment was carried out in the summer of 2001. Changes over time in the abundance and community structure of phytoplankton were examined inside and outside an Fe patch using phytoplankton pigment markers analyzed by high-performance liquid chromatography (HPLC) and flow cytometry (FCM). In addition, the abundance of heterotrophic bacteria was also investigated by FCM. The chlorophyll a concentration was initially ca. 0.9 μg l⁻¹ in the surface mixed layer where diatoms and chlorophyll b-containing green algae (prasinophytes and chlorophytes) were predominant in the chlorophyll biomass. After the iron enrichment, the chlorophyll a concentration increased up to 9.1 μg l⁻¹ in the upper 10 m inside the Fe patch on Day 13. At the same time, the concentration of fucoxanthin (a diatom marker) increased 45-fold in the Fe patch, and diatoms accounted for a maximum 69% of the chlorophyll biomass. This result was consistent with a microscopic observation showing that the diatom Chaetoceros debilis had bloomed inside the Fe patch. However, chlorophyllide a concentrations also increased in the Fe patch with time, and reached a maximum of 2.2 μg l⁻¹ at 5 m depth on Day 13, suggesting that a marked abundance of senescent algal cells existed at the end of the experiment. The concentration of peridinin (a dinoflagellate marker) also reached a maximum 24-fold, and dinoflagellates had contributed significantly (>15%) to the chlorophyll biomass inside the Fe patch by the end of the experiment. Concentrations of 19′-hexanoyloxyfucoxanthin (a prymnesiophyte marker), 19′-butanoyloxyfucoxanthin (a pelagophyte marker), and alloxanthin (a cryptophyte marker) were only incremented a few-fold increment inside the Fe patch. On the contrary, chlorophyll b concentration reduced to almost half of the initial level in the upper 10 m water column inside the Fe patch at the end of the experiment. A decrease with time in the abundance of eukaryotic ultraphytoplankton (<ca. 5 μm in size), in which chlorophyll b-containing green algae were possibly included was also observed by FCM. Overall, our results indicate that Fe supply can dramatically alter the abundance and community structure of phytoplankton in the WSG. On the other hand, cell density of heterotrophic bacteria inside the Fe patch was maximum at only ca. 1.5-fold higher than that outside the Fe patch. This indicates that heterotrophic bacteria abundance was little respondent to the Fe enrichment.     

Simulation of Formation and Spreading of Salinity Minimum Associated with NPIW Using a High-Resolution Model

A series of numerical experiments were conducted with a high-resolution (eddy-permitting) North Pacific model to simulate the formation and spreading of the salinity minimum associated with the North Pacific Intermediate Water (NPIW). It was found that two factors are required to simulate a realistic configuration of the salinity minimum: a realistic wind stress field and small-scale disturbances. The NCEP reanalyzed wind stress data lead to better results than the Hellerman and Rosenstein wind stress data, due to the closer location of the simulated Oyashio and Kuroshio at the western boundary. Small-scale disturbances formed by relaxing computational diffusivity included in the advection scheme promote the large-scale isopycnal mixing between the Oyashio and Kuroshio waters, simulating a realistic configuration of the salinity minimum. A detailed analysis of the Oyashio water transport was carried out on the final three-year data of the experiment with reduced computational diffusivity. Simulated transport of the Kuroshio Extension in the intermediate layer is generally smaller than the observed value, while those of the Oyashio and the flow at the subarctic front are comparable to the observed levels. In the Oyashio-Kuroshio interfrontal zone the zonally integrated southward transport of the Oyashio water (140–155°E) is borne by the eddy activity, though the time-mean flow reveals the existence of a coastal Oyashio intrusion. In the eastern part (155°E–180°) the zonally integrated transport of the Oyashio water indicates a southward peak at the southern edge of the Kuroshio Extension, which corresponds to the branching of the recirculating flow from the Kuroshio Extension. This revised version was published online in July 2006 with corrections to the Cover Date.     

Effects of presence of a circumpolar region on buoyancy-driven circulation

Effects of the presence of a circumpolar region on buoyancy-driven circulation are investigated by using an idealized numerical ocean model. Comparison of circulation and meridional density (heat) transport is made between a closed ocean and an ocean with a cyclic gap near its southern boundary. The presence of the circumpolar region leads to disconnection of the meridional overturning across the circumpolar region. And the circumpolar eastward flow reaches the bottom of the ocean. It is essential for this that the pycnocline is deeper than the bottom of the gap. Since the amount of the mass transported northward must return southward at the levels deeper than the bottom of the cyclic gap, the weak stratification, hence weak vertical geostrophic shear, at the deeper levels leads to inactive communication across the circumpolar region. Meridional heat transport across the circumpolar region is made mainly by horizontal diffusion for the ocean with the cyclic gap, while the contribution of the advection is dominant for the closed ocean. Sensitivity of meridional heat transport to change in horizontal diffusivity is studied. The meridional heat transport for the ocean with the cyclic gap is more sensitive than for the closed ocean. The change in heat transport occurs not only in the circumpolar region but also in the rest of the ocean. It is suggested that subgrid scale phenomena, especially mesoscale eddies, in the circumpolar region controls the whole ocean to a great extent.     

State Estimation of the North Pacific Ocean by a Four-Dimensional Variational Data Assimilation Experiment

A four-dimensional variational data assimilation system has been applied to an experiment to describe the dynamic state of the North Pacific Ocean. A synthesis of available observational records and a sophisticated ocean general circulation model produces a dynamically consistent dataset, which, in contrast to the nudging approach, provides realistic features of the seasonally-varying ocean circulation with no artificial sources/sinks for temperature and salinity fields. This new dataset enables us to estimate heat and water mass transports in addition to the qualification of water mass formation and movement processes. A sensitivity experiment on our assimilation system reveals that the origin of the North Pacific Intermediate Water can be traced back to the Sea of Okhotsk and the Bering Sea in the subarctic region and to the subtropical Kuroshio region further south. These results demonstrate that our data assimilation system is a very powerful tool for the identification and characterization of ocean variabilities and for our understanding of the dynamic state of ocean circulation. This revised version was published online in July 2006 with corrections to the Cover Date.     

Community Structure and Dynamics of Phytoplankton in the Western Subarctic Pacific Ocean: A Synthesis

The phytoplankton community in the western subarctic Pacific (WSP) is composed mostly of pico- and nanophytoplankton. Chlorophyll a (Chl a) in the <2 μm size fraction accounted for more than half of the total Chl a in all seasons, with higher contributions of up to 75% of the total Chl a in summer and fall. The exception is the western boundary along the Kamchatka Peninsula and Kuril Islands and the Oyashio region where diatoms make up the majority of total Chl a during the spring bloom. Among the picophytoplankton, picoeukaryotes and Synechococcus are approximately equally abundant, but the former is more important in term of carbon biomass. Despite the lack of a clear seasonal variation in Chl a concentration, primary productivity showed a large seasonal variation, and was lowest in winter and highest in spring. Seasonal succession in the phytoplankton community is also evident with the abundance of diatoms peaking in May, followed by picoeukaryotes and Synechococcus in summer. The growth of phytoplankton (especially >10 μm cell size) in the western subarctic Pacific is often limited by iron bioavailability, and microzooplankton grazing keeps the standing stock of pico- and nano-phytoplankton low. Compared to the other HNLC regions (the eastern equatorial Pacific, the Southern Ocean, and the eastern subarctic Pacific), iron limitation in the Western Subarctic Gyre (WSG) may be less severe probably due to higher iron concentrations. The Oyashio region has similar physical condition, macronutrient supply and phytoplankton species compositions to the WSG, but much higher phytoplankton biomass and primary productivity. The difference between the Oyashio region and the WSG is also believed to be the results of difference in iron bioavailability in both regions. This revised version was published online in July 2006 with corrections to the Cover Date.