The chemical composition of fogs and intercepted clouds in the United States

Over the past decade, the chemical compositions of fogs and intercepted clouds have been investigated at more than a dozen locations across the United States. Sampling sites have been located in the northeast, southeast, Rocky Mountain, and west coast regions of the US. They include both pristine and heavily polluted locations. Frontal/orographic clouds (warm and supercooled), intercepted coastal stratiform clouds, and radiation fogs have all been examined. Sample pH values range from below 3 to above 7. Major ions also exhibit a wide concentration range, with clouds at some locations exhibiting high sea salt concentrations, while composition at other locations is dominated by ammonium and sulfate or nitrate.     

Toward a Synthesis: Lessons from Thirteen Cropland Watershed-Scale Studies

To integrate lessons from the U.S. Department of Agriculture (USDA), National Institute of Food and Agriculture–Conservation Effects Assessment Project (NIFA CEAP) program, key informant (KI) interviews were conducted in all 13 project areas. The purpose of these interviews was to supplement technical information about watersheds, their contaminants, modeling, economics, and key findings. We interviewed a wide range of people to develop a systematic look at individual project results, synthesize meanings, and derive principles useful in guiding future watershed management. Findings revealed common themes, which tended to align with KI categories, regardless of location. For instance, farmers and ranchers often understood water quality problems as well as federal and state personnel and university employees do. Conservation adoption by farmers was related to perceived need, cost, and convenience of the practice, as well as practice specifics and individual situations. Possible implications of these findings are advanced.     

Low-bit-rate coding of underwater video using wavelet-basedcompression algorithms

Recent advances in autonomous underwater vehicle (AUV) and underwater communication technology have promoted a surge of research activity within the area of signal and information processing. A new application is proposed herein for capturing and processing underwater video onboard an untethered AUV, then transmitting it to a remote platform using acoustic telemetry. Since video communication requires a considerably larger bandwidth than that provided by an underwater acoustic channel, the data must be massively compressed prior to transmission from the AUV. Past research has shown that the low contrast and low-detailed nature of underwater imagery allows for low-bit-rate coding of the data by wavelet-based image-coding algorithms. In this work, these findings have been extended to the design of a wavelet-based hybrid video encoder which employs entropy-constrained vector quantization (ECVQ) with overlapped block-based motion compensation. The ECVQ codebooks were designed from a statistical source model which describes the distribution of high subband wavelet coefficients in both intraframe and prediction error images. Results indicate that good visual quality can be achieved for very low bit-rate coding of underwater video with our algorithm     

The Effect of Air Bubbles and Headspace on the Aqueous Concentrations of Volatile Organic Compounds in Sampling Vials

The presence of headspace and air bubbles in volatile organic analysis sampling vials lowers the actual aqueous concentration of these compounds due to the partitioning of solutes into the gaseous phase. This could make the sample invalid for analysis.
In this work, the effects of air bubbles and headspace on the aqueous concentration of 60 volatile organic compounds listed in U.S.Environmental Protection Agency (U.S. EPA) Method 8260 were evaluated experimentally and theoretically. The results showed that for air to water ratios of 1 to 20 and less, there was no significant effect on the aqueous concentrations of target organic solutes in the sampling vials. When the air to water ratio was increased to 1 to 10, the recovery rates of four organic compounds were lower than the control. Laboratory experiments on sampling vials showed that the presence of air bubbles or headspace with the volumetric air to water ratios of 1 to 20 and less do not produce any significant effect on the original concentrations for most targeted volatile organic compounds.
The experimental results also indicated that in 40 mL sampling vials with headspace range of 2 to 8 mL, the recovery rates of most volatile organic compounds with high values of Henry's law constant (> 0.01 Atm m³/mol. at 25°C) were larger than the calculated rates.     

Hydrogeochemical exploration and sources of anomalous waters

Fifty-four surface and twenty drill-hole waters were sampled in the vicinity of the old Eustis mine in the Eastern Townships of Quebec. Some of these waters were tested periodically over a three-month period. The purpose of the investigation was to develop a method for locating sources of anomalous waters using chemical analyses together with geomorphic and geologic evidence. Techniques have been developed which use chemical and hydrologic theory to estimate travel distance and location of the approximate source area of a water. The travel distance can be approximated as a function of hydraulic head, sodium concentration in the water, and an approximate constant which must be derived for the area.Water samples having anomalous concentrations of copper or zinc can be ascribed, in the specific region of this investigation, partly to contamination from mine workings (35%), partly to known mineralization (25%), and partly to unknown causes (40%).