Tashelgite, CaMgFe2 + Al9O16(OH), a new mineral species from calc-skarnoid in Gorny Shoria

A new mineral species has been discovered at the calc-skarnoid occurrence near the mouth of the Tashelga River, Kuznetsky Alatau, Gorny Shoria, Russia, and named after the locality of its discovery. Associated minerals are calcite, hibonite, grossular, vesuvianite, hercynite, magnetite, corundum, perovskite, scapolite, diopside, and apatite. The new mineral occurs as prismatic or finely fibrous crystals up to 1.5–2.0 mm in length, their parallel intergrowths, and felty aggregates as large as 10 mm across. Tashelgite is bluish green, translucent to transparent, with vitreous luster; D _calc = 3.67 g/cm³. The IR spectrum does not contain bands of OH groups. Tashelgite is biaxial (−), with α = 1.736(2), β = 1.746(2), γ = 1.750(2); 2V _meas = −20(2)°. Dispersion is strong, r < ν. Pleochroism is distinct: X (blue-green) > Y (yellowish green) > Z (almost colorless). Chemical composition (electron microprobe, average of five-point analyses, Fe₂O₃ is estimated from the ratio of intensities I(Fe_Kb5 )/I(Fe_Kb1 )I(Fe_{K\beta _5 } )/I(Fe_{K\beta _1 } ) in the X-ray spectrum, H₂O was determined as a weight loss on heating in vacuum up to 1000°C), wt %: 7.98 CaO, 6.75 MgO, 0.45 MnO, 11.32 FeO, 1.40 Fe₂O₃, 70.70 Al₂O₃, 1.8(2) H₂O, 100.40 in total. The empirical formula calculated on the basis of 17 oxygen atoms is H_1.27Ca_0.90Mg_1.06Mn_0.04 Fe_1.00²⁺Fe_0.11³⁺Al_8.80O_17.00. The idealized formula is CaMgFe²⁺Al₉O₁₆(OH). According to single-crystal X-ray structural data, tashelgite is monoclinic, pseudoorthorhombic, space group Pc; unit cell parameters are: a = 5.6973(1), b = 17.1823(4), c = 23.5718(5)?; β = 90.046(3)°; V = 2307.5(1)?³, Z = 8. The crystal structure of tashelgite is unique and characterized by ordering of all cations; Al occupies sites with octahedral and tetrahedral coordination. The cation ordering has also been confirmed by IR spectroscopy. The strongest lines of the X-ray powder diffraction pattern (d, ?]-I[hkl] are: 11.79–48 [002], 2.845–43 [061], 2.616–100 [108], 2.584–81 [146], 2.437–44 [163], 2.406–61 [057], 2.202–72 [244]. The type specimen of tashlegite has been deposited at the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia.     

Multiple re‐advances of a Lake Vättern outlet glacier during Fennoscandian Ice Sheet retreat,south‐central Sweden

Lake Vättern represents a critical region geographically and dynamically in the deglaciation of the Fennoscandian Ice Sheet. The outlet glacier that occupied the basin and its behaviour during ice‐sheet retreat were key to the development and drainage of the Baltic Ice Lake, dammed just west of the basin, yet its geometry, extent, thickness, margin dynamics, timing and sensitivity to regional retreat forcing are rather poorly known. The submerged sediment archives of Lake Vättern represent a missing component of the regional Swedish deglaciation history. Newly collected geophysical data, including high‐resolution multibeam bathymetry of the lake floor and seismic reflection profiles of southern Lake Vättern, are used here together with a unique 74‐m sediment record recently acquired by drill coring, and with onshore LiDAR‐based geomorphological analysis, to investigate the deglacial environments and dynamics in the basin and its terrestrial environs. Five stratigraphical units comprise a thick subglacial package attributed to the last glacial period (and probably earlier), and an overlying >120‐m deglacial sequence. Three distinct retreat–re‐advance episodes occurred in southern Lake Vättern between the initial deglaciation and the Younger Dryas. In the most recent of these, ice overrode proglacial lake sediments and re‐advanced from north of Visingsö to the southern reaches of the lake, where ice up to 400 m thick encroached on land in a lobate fashion, moulding crag‐and‐tail lineations and depositing till above earlier glacifluvial sediments. This event precedes the Younger Dryas, which our data reveal was probably restricted to north‐central sectors of the basin. These dynamics, and their position within the regional retreat chronology, indicate a highly active ice margin during deglaciation, with retreat rates on average 175 m a^?1. The pronounced topography of the Vättern basin and its deep proglacial‐dammed lake are likely to have encouraged the dynamic behaviour of this major Fennoscandian outlet glacier.     

Utilizing a seismoacoustic complex for the study of the upper sedimentary stratum and seafloor relief in East Arctic

The paper describes a high-resolution seismoacoustic complex for studying the upper sedimentary stratum and seafloor relief. The described complex was used during the 57th cruise of the R/V Akademik M.A. Lavrent’ev in the East Siberian and Laptev seas in the autumn of 2011. The combination of an SES-2000 narrow-beam parametric subbottom profiler and a Gidra 250/500 sidescan sonar has enabled obtaining a series of unique data on the structure of the sedimentary layers and the seafloor relief.     

Sector Structure, Rotation, and Cyclic Evolution of Large-Scale Solar Magnetic Fields

Auto-correlation analysis was performed using digitized synoptic charts of photospheric magnetic fields for the past three solar activity cycles (1965–1994). The obtained correlograms were used to study the rotation and the zonal-sector structure of large-scale solar magnetic fields all over the observable region of heliolatitudes in various phases of solar activity. It is shown that the large-scale system of solar magnetic fields is rather complex and comprises at least three different systems. One is a global rigidly rotating system. It determines the cyclic variation of magnetic fields and is probably responsible for the behavior of magnetic fields in the polar zones. Another is a rigidly rotating 4-sector structure in the central (equatorial and mid-latitude) zone. The third is a differentially rotating system that determines the behavior of the LSSMF structure elements with a size of 30–60° and less. This one is the most noticeable in the central zone and absent in the polar zones. Various cyclic and rotation parameters of the three field structures are discussed.     

Manifestations of Degassing in the Upper Part of the Pechora Sea Sediment Section and Its Relation to Tectonics

Doklady Earth Sciences - The spatial distribution of subsurface seismoacoustic anomalies of the “bright spot” type in the Pechora Sea, which are indicators of free gas accumulation, is...     

Variations of Solar Irradiance, 10.7 cm Radio Flux, He I 10830 Å Equivalent Width, and Global Magnetic Field Intensity and Their Relation to Large-Scale Solar Magnetic Field Structure

Variations of total solar irradiance, 10.7 cm radio emission, the Hei 10830 Ú equivalent width and the solar magnetic field flux measured for the entire Sun are compared with variations of the energy index of the global solar magnetic field and the index of the effective solar multipole for years 1979–1992. It is shown that photospheric radiation and that generated in the upper chromosphere and corona display different relationships with the global magnetic field of the Sun, and that interaction between the magnetic field and the solar irradiance is much more complicated than the traditional blocking effect.