伊豆-小笠原前弧地区Hahajima海山蛇纹石化橄榄岩岩石学和地球化学研究

Serpentinites, which contain up to 13 wt% of water, are important reservoirs for chemical recycling in subduction zones. In the past two decades, forearc mantle serpentinites were identified in different locations around the world. Here, we present petrology and whole rock chemistry of ultramafic and mafic rocks dredged from the Hahajima Seamount, which is located 24–40 km west to the junction of the Izu-Bonin Trench and the Mariana Trench. Nearly all the collected samples are extensively hydrated, and olivine grains in ultramafic rocks are replaced by serpentine minerals, with only one sample preserving remaining trace of orthopyroxene. Our new results show that the Hahajima serpentinized peridotite samples are all MgO-rich(～42 wt%), but have low contents in Al_2O_3, CaO, rare earth and high field strength elements, which is consistent with the overall depleted character of their mantle protoliths. Model calculations indicate that these Hahajima peridotite samples were derived from 10%–25% partial melting of the presumed fertile mantle source, which is generally lower than those of peridotites from Torishima Forearc Seamount, Conical Seamount and South Chamorro Seamount(mostly25%). All the serpentinites from these four forearc seamounts show strong enrichment in fluid-mobile and lithophile elements(Li, Sr, Pb and U). In details, Hahajima Seamount serpentinites do not have obvious enrichment in Cs and Rb, and display remarkably high abundances of U. These observations indicate that the serpentinization of Hahajima peridotites occurred by addition of seawater or low temperature seawater-derived hydrothermal fluid, without or with little contribution from slab-derived fluids. The geochemical signature of serpentinites from Hahajima Seamount could be interpreted as the result of the combination of extensive partial melting and subsequent percolation of seawater through the mantle wedge.     

青岛八仙墩海相碎屑岩的岩石地球化学特征及其油气研究意义

青岛八仙墩剖面出露了一套海相陆源碎屑沉积层序。这套碎屑岩受崂山花岗岩侵入已经发生变质,岩性以硬砂岩为主,夹有页岩、含锰细砂岩、长石砂岩,富含白云质。这套地层保留了各种原生的沉积构造,发育有浊积岩的底模构造,同沉积变形,水平层理、微粒序层理。岩石地球化学分析结果表明:碎屑岩的SiO_2含量在59.6%～71.6%之间,含量的多少与岩性无相关性;而黑色页岩的Al_2O_3含量变化于12.31%～16.39%之间,多在15%以上,高于灰白色砂岩的含量(普遍小于14.5%)。镜下特征和Al203含量都表明砂岩的成熟度低。除一个样品外,碎屑岩的∑REE含量高,在146.75×10~(-6)～245.78×10~(-6)之间,La在30.35×10~(-6)～61.39×10~(-6)之间,对球粒陨石标准化的(La/Yb)_N在8.68×10~(-6)～21.89×10~(-6)之间。对PASS标准化碎屑岩的(La/Ce)_N值为1.07～1.18,显示了陆源碎屑物质的主要贡献。该地层弱的Ce/Ce*负异常和富含白云质岩层指示了海相沉积环境。主量元素判别图解和微量元素判别图解表明这套碎屑岩具有活动大陆边缘背景和大陆岛弧的共同特征,但高的∑REE含量、La和Ce丰度支持了活动大陆边缘的沉积环境,但有待于采用更准确的重矿物分析来确定其物源区的大地构造性质。这套碎屑岩的出露指示了南黄海盆地深部应有奥陶统盆地相浊积沉积体系的存在,可能具有良好的浊积砂岩油气储层。