The Late Cretaceous Impact of the Trindade Mantle Plume: Evidence from Large-volume, Mafic, Potassic Magmatism in SE Brazil

When the subcontinental lithospheric mantle undergoes heatingand/or extension, some of the earliest mafic melts to be generatedare those rich in volatUes and potassium. In some cases, e.g.when a plume impinges on thick cratonic lithosphere or whenthe amount of extension is very small, K-rich mafic igneousrocks may be the only surface expression of mantle melting.The Alto Paranaiba Igneous Province, in SE Brazil, is one ofthe world's most voluminous mafic potassic provinces (>15000km³),which until recently was relatively unknown. The magmas wereemplaced into a narrow Proterozoic mobile belt close to thesurface margin of the Sao Francisco craton, and it is one ofseveral Cretaceous alkaline igneous provinces that are locatedaround the margin of the Parana sedimentary basin in Braziland Paraguay.Detailed geochemical analyses of samples from throughoutthe Alto Paranaiba Igneous Province show that it is composedof a relatively diverse suite of ultrapotassic-potassic, ultramaficmqfic,silica-undersaturated lavas and hypabyssal intrusions, i.e.kimberlites, madupitic olivine lamproites and kamafugitic rocks.These all have very high concentrations of incompatible traceelements and are all strongly enriched in light rare earth relativeto heavy rare earth elements (e.g. La/Yb=50-230). Wide variationsin major element ratios, which are unrelated to the effectsof crystal fractionation in these magmas (e.g. CaO/Al₂O₃), suggestthat the mafic potassic rocks were derived from a heterogeneousmantle source. They show relatively restricted ranges of initial⁸⁷Sr/⁸⁶Sr (070436-070588) and Nd₂₅ values of -4 to -8, intermediatebetween Group I and II South African kimberlites. T_DM Nd isotopemodel ages of 900 Ma suggest that the magmas were derived bythe remobilization of subcontinental lithospheric mantle thathad been enriched by small-volume K-rich melt fractions sincethe Late Proterozoic.New K/Ar ages for mica separates show thatthe kimberlites, madupitic olivine lamproites and kamafugiticrocks were emplaced together with large carbonatite-bearingplutonic complexes at 85 Ma. Reconstructions of plate motionsshow that, at this time, the location of the Alto ParanaibaIgneous Province coincided with the postulated position of thepresent-day Trindade(or Martin Vaz) plume. We propose that thewidespread Late Cretaceous alkaline magmatism in SE Brazil mayhave been caused by impingement of this plume on the base ofthe subcontinental lithosphere. Heat penetrating the lithosphere,both by conduction and advection by asthenospheric-source decompressionmelts, may have caused melting of the readily fusible partsof the lithospheric mantle and the genesis of mafic potassicand (after fractionation) carbonatite magmas. The Proterozoicmobile belt (the Brasilia Belt) appears to have acted as a Hhinspofrelative to the adjacent Sao Francisco craton, allowing greaterupwelling and melting of the asthenosphere. Subsequently, asthe craton passed over the plume, volcanism was switched off'until the Early Tertiary when the plume reemerged from beneaththe westward drifting South America continent and was the magmasource for oceanic-islands and seamounts of the Trindade-Vitriachain. Corresponding author     

Reconstruction of past climates from stable isotope records of palaeo-precipitation preserved in continental archives

Abstract

The potential of stable isotope ratios (²H/¹H and ¹⁸O/¹⁶0) of water as a modern tool for palaeoclimatic reconstructions on continents is reviewed. Examples of stable isotope records of palaeo-precipitation preserved in various continental archives (polar ice sheets, mid- and low latitude glaciers, lacustrine deposits, groundwater) are presented, and the methodology of their interpretation in terms of climatic changes is briefly discussed. To interpret quantitatively the isotope records preserved in continental archives, the response of the isotopic composition of precipitation to long-term fluctuations of key climatic parameters (temperature, precipitation amount, relative humidity) over the given area should be known. Further, the transfer functions relating the climate-induced changes of the isotopic composition of precipitation to the isotope record preserved in the given archive should be established. Since the isotopic composition of precipitation has been monitored only for the past three decades, alternatives ways of assessing the long-term climatic sensitivity of the isotopic signature of precipitation are being investigated. The isotope composition of precipitation should be viewed not only as a powerful proxy climatic indicator but also as an additional hydrometeorological parameter which should be explored as a diagnostic tool for the modelling of climate-induced changes in the water cycle, both on a regional and a global scale.     

Ultrapotassic Magmas along the Flanks of the Oligo-Miocene Rio Grande Rift, USA: Monitors of the Zone of Lithospheric Mantle Extension and Thinning Beneath a Continental Rift

Recent theoretical studies of rift tectonics have concludedthat their observed geophysical features, require that (1) extensionaffects a much wider zone of the underlying lithospheric mantlethan the crust; (2) early extension involves a comparativelywide zone that narrows with time. The Neogene evolution of thesegment of the Rio Grande rift between the Great Plains andColorado Plateau shows this theoretical pattern clearly. Thewidth of the crustal extension zone narrowed from {small tilde}170km in the Oligo-Miocene to {small tilde}50 km in the Pliocene.In contrast, both gravity and teleseismic studies indicate thatthe current width of the zone of thinned lithospheric mantle(ß = 2–3) beneath the rift is {small tilde}750km. To assess the contributions of lithosphere- and asthenosphere-derivedmelts to the magmatismassociated with the early phase of developmentof the Rio Grande rift, we have undertaken a 670-km geochemicaltraverse of Oligo-Miocene volcanism between latitudes 36 and38N. Our section is centered on the present-day axis of therift in the Espanola Basin. It extends from the Navajo volcanicfield, Arizona, to Two Buttes, SE Colorado, and intersects hypabyssalintrusions on the rift shoulders at Dulce, west of the rift,and Spanish Peaks to the east. We have sampled a diverse rangeof magma types that vary in composition from ultrapotassic toHy- and Ne-normative basalts. A geochemical profile along thistraverse shows a spatially symmetrical variation in elementand oxide ratios, such as Na₂O/K₂O and Ba/Nb, and also in Srand Nd isotope ratios. On the rift flanks and shoulders Oligo-Miocenevolcanism was dominated by K-rich mafic magmatism, whereas atthe rift axis tholeiitic and alkalic basalts with whole-rockcompositions similar to those of ocean-island basalts (OIB)were erupted. This symmetrical geochemical variation broadlyparallels the corresponding teleseismic lithosphere thicknessprofile and is a mirror image of the gravity profile. We interpret the OIB-type magmas at the rift axis as predominantlyasthenosphere-derived melts. These suggest that mantle upwelling,and melting by decompression, were occurring during the earlydevelopment of the Rio Grande rift The symmetrical variationof incompatible elements and isotope ratios in rocks about therift axis suggests that the sources of the K-rich mafic magmason the stable flanks and shoulders of the rift are not directlyrelated to the subduction of the Farallon plate: an asymmetricprocess. Instead, we propose that the K-rich mafic magmas onthe flanks and shoulders of the Rio Grande rift are derivedfrom the melting of a metasomatized layer in the lithosphericmantle during extension. *Present address: British Antarctic Survey, High Cross, Madingley Road, Cambridge CB3 0ET, UK     

Pressure--Temperature--Time Paths of Regional Metamorphism I. Heat Transfer during the Evolution of Regions of Thickened Continental Crust

The development of regional metamorphism in areas of thickenedcontinental crust is investigated in terms of the major controlson regional-scale thermal regimes. These are: the total radiogenicheat supply within the thickened crust, the supply of heat fromthe mantle, the thermal conductivity of the medium and the lengthand time scales of erosion of the continental crust. The orogenicepisode is regarded as consisting of a relatively rapid phaseof crustal thickening, during which little temperature changeoccurs in individual rocks, followed by a lengthier phase oferosion, at the end of which the crust is at its original thickness.The principal features of pressure—temperature—time(PTt) paths followed by rocks in this environment are a periodof thermal relaxation, during which the temperature rises towardsthe higher geotherm that would be supported by the thickenedcrust, followed by a period of cooling as the rock approachesthe cold land surface. The temperature increase that occursis governed by the degree of thickening of the crust, its conductivityand the time that elapses before the rock is exhumed sufficientlyto be affected by the proximity of the cold upper boundary.For much of the parameter range considered, the heating phaseencompasses a considerable portion of the exhumation (decompression)part of the PTt path. In addition to the detailed calculationof PTt paths we present an idealized model of the thickeningand exhumation process, which may be used to make simple calculationsof the amount of heating to be expected during a given thickeningand exhumation episode and of the depth at which a rock willstart to cool on its ascent path. An important feature of thesePTt paths is that most of them lie within 50 °C of the maximumtemperature attained for one third or more of the total durationof their burial and uplift, and for a geologically plausiblerange of erosion rates the rocks do not begin to cool untilthey have completed 20 to 40 per cent of the total uplift theyexperience. Considerable melting of the continental crust isa likely consequence of thickening of crust with an averagecontinental geotherm. A companion paper discusses these resultsin the context of attempts to use metamorphic petrology datato give information on tectonic processes.     

Pressure--Temperature--Time Paths of Regional Metamorphism II. Their Inference and Interpretation using Mineral Assemblages in Metamorphic Rocks

A companion paper (England & Thompson, 1984a) investigatesthe pressure-temperature-time (PTt) paths followed by rocksundergoing burial metamorphism in continental thickening events.This paper discusses problems involved in inferring such pathsfrom the petrological data available in metamorphic rocks and—oncesuch paths are determined—how they may be interpretedin terms of the thermal budgets of metamorphism. Each of theprincipal facies series (glaucophane-jadeite, andalusite- sillimaniteand kyanite-sillimanite) may be encountered by rocks involvedin the thickening and erosion of continental crust in a regimeof average continental heat flow. The inference of a minimumthermal budget required for a given metamorphism depends stronglyon a knowledge of the PTt paths followed by rocks during themetamorphism. Discrimination between possible thermal regimesis greatly enhanced if portions of PTt paths, rather than singlePT points, are available, and additional constraint is possibleif these paths are supplemented by geochronological, structuraland heat flow data.     

Shelf construction in a foreland basin: storm beds, shelf sandbodies, and shelf-slope depositional sequences in the Upper Cretaceous Mesaverde Group, Book Cliffs, Utah

The Upper Cretaceous (Campanian) Kenilworth Member of the Blackhawk Formation (Mesaverde Group) is part of a series of strand plain sandstones that intertongue with and overstep the shelfal shales of the western interior basin of North America. Analysis of this section at a combination of small (sedimentological) and large (stratigraphical) scales reveals the dynamics of progradation of a shelf-slope sequence into a subsiding foreland basin. Four major lithofacies are present in the upper Mancos and Kenilworth beds of the Book Cliffs. A lag sandstone and channel-fill shale lithofacies constitutes the thin, basal, transgressive sequence, which rests on a marine erosion surface. It was deposited in an outer shelf environment. Shale, interbedded sandstone and shale, and amalgamated sandstone lithofacies were deposited over the transgressive lag sandstone lithofacies as a wave-dominated delta and its flanking strand plains prograded seaward. Analysis of grain size and primary structures in Kenilworth beds indicates that there are four basic strata types which combine to build the observed lithofacies. The fine- to very fine-grained graded strata of the interbedded facies are tempestites, deposited out of suspension by alongshelf storm flows (geostrophic flows). There is no need to call on cross-shelf turbidity currents (density underflows) to explain their presence. Very fine- to fine-grained hummocky strata are likewise suspension deposits created by waning storm flows, but were deposited under conditions of more intense wave agitation on the middle shoreface. Cross-strata sets in this region are bed-load deposits that accumulated on the upper shore-face, in the surf zone. Lag strata are multi-event, bed-load deposits that are the product of prolonged storm winnowing. They occur on transgressive surfaces. While the graded beds are tempestites in the strict sense, all four classes of strata are storm deposits. The distribution of strata types and their palaeocurrent orientations suggests a model of the Kenilworth transport system driven by downwelling coastal storm flows, and probably by a northeasterly alongshore pressure gradient. The stratification patterns shift systematically from upper shoreface to lower shoreface and inner shelf lithofacies partly because of a reduction in fluid power expenditure with increasing water depth, but also because of progressive sorting, which resulted in a decrease in grain size in the sediment load delivered to successive downstream environments. The Kenilworth Member and an isolated outlier, the Hatch Mesa lentil, constitute a delta-prodelta shelf depositional system. Their rhythmically bedded, lenticular, sandstone and shale successions are a prodelta shelf facies, and may be prodelta plume deposits. Major Upper Cretaceous sandstone tongues in the Book Cliffs are underlain by erosional surfaces like that beneath the Blackhawk Formation, which extend for many tens of kilometres into the Mancos shale. These surfaces are the boundaries of Upper Cretaceous depositional sequences. The sequences are large-scale genetic stratigraphic units. They result from the arranging of facies into depositional systems; the depositional systems are in turn stacked in repeating arrays, which constitute the depositional sequences. The anatomy of these foreland basin sequences differs     

Determination of Beryllium and Zirconium In 45 Geochemical Reference Samples By Inductively Coupled Plasma Emission Spectrometry

The beryllium and zirconium contents of 45 geochemical reference samples have been determined by inductively coupled plasma after fusion of the samples with lithium metaborate and dissolution of the melt in dilute nitric acid. The method described here is rapid and sample preparation straightforward. Good agreement is shown with previously published results for these two elements. A correction has to be made for an interference due to vanadium in determining the beryllium content, and there is a slight interference due to yttrium in the determination of zirconium. The detection limit for beryllium is about 0.2 μg g^-1 and for zirconium about 15 μg g^-1 in the sample.     

Intrusion–Related Vein Gold Deposits: Types, Tectono-Magmatic Settings and Difficulties of Distinction from Orogenic Gold Deposits

Abstract: A spectrum of intrusion-related vein gold deposits is recognized. Representative examples are described of the following geochemical associations: Au-Fe oxide–Cu, Au–Cu–Mo–Zn, Au–As–Pb–Zn–Cu, Au–Te–Pb–Zn–Cu and Au–As–Bi–Sb. The associated intrusions range from small outcropping stocks to complex batholiths. The different vein associations are believed to reflect the compositions of related intrusions, which themselves characterize distinct tectonic settings. The Au-Fe oxide–Cu and Au–Cu–Mo–Zn associations belong to two broad groups of deposits, Fe oxide–Cu–Au and porphyry Cu–Au, both of which are related to highly oxidized calc-alkaline intrusions emplaced in sub–duction–related arcs. The Au–As–Pb–Zn–Cu association seems to be linked to somewhat less oxidized intrusions emplaced in a similar setting. The Au–Te–Pb–Zn–Cu association, which possesses well-known epithermal counterparts, is also found with highly oxidized intrusions, but of alkaline composition and back-arc location. In contrast, the Au–As–Bi–Sb association, part of a newly recognized class of intrusion-hosted Au–Bi–W–As deposits, is related to relatively reduced intrusions, spanning the boundary between the magnetite– and ilmenite–series. Such intrusions, which may host major bulk-mineable gold deposits, were emplaced along the landward sides of arcs, possibly during lulls in subduction, as well as in continental collision settings. Therefore, a variety of geological environments is prospective for vein and, by extrapolation, other styles of gold mineralization, not all of them fully appreciated in the past. Several features of vein gold deposits, including imprecise relationships to individual intrusive phases, poorly developed mineral and metal zoning, apparent time gaps between intrusion and mineralization and presence of low–salinity, CO₂–rich fluid inclusions, are commonly taken to indicate a non-igneous origin and to be more typical of orogenic (mesothermal) gold deposits generated during accretionary tectonic events. However, several or all of these features apply equally to some intrusion– related vein gold deposits and, therefore, do not constitute distinguishing criteria. The currently popular assignment of most gold-rich veins to the orogenic category requires caution, because of the geological convergence that they show with some intrusion-related deposits. A proper distinction between intrusion-related and orogenic gold deposits is crucial for exploration planning.     

Calc-Silicate Diffusion Zones between Marble and Pelitic Schist

Four distinct calc-silicate zones are observed between interlayeredmarble and pelite in a roof-pendant (Gile Mountain Fm.) of agranitic intrusive at Lake Willoughby in northern Vermont. Thezones are characterized by garnet, coarse diopside-clinozoisite,fine clinozoisite-diopside and amphibole-plagioclase. The bulkcompositions of the zones, calculated from modal data and microprobeanalyses, deviate significantly from a gradational mixture ofmarble and pelite. The observed zonal sequence is close to thatpredicted by a simple model of cation diffusion metasomatism.Possible locations of the initial marble-pelite boundary aresuggested on the basis of bulk compositional data and petrographicevidence. Calculated mass balance relations for the formationof the zones by diffusion at constant volume are unrealisticfor reasonable locations of the initial boundary. Calculatedmass balance relations at constant Al₂O₃ suggest a volume decreaseof about one third during formation of the diffusion zones whollyfrom the pelite. In addition the data suggest that nearly equalvolumes of initial marble and pelite have disappeared, leadingto a total volume decrease of near 50 percent. The observationssuggest that diffusion of calcium was dominant and that diffusionof aluminium, iron and magnesium was relatively unimportant.Evaluation of relative diffusional mobilities is shown to bepossible but intractable with the quality of available thermochemicaldata and activity-concentration relations of crystalline solutions.