Evaluation of Subsurface Lithologic Units for Groundwater Exploration in the Barind Tract of Bangladesh

Barind Tract, located north western part of Bangladesh, is one of the most diversified physiographic units of the country. The surface water supply in this part is particularly limited, so the irrigation is almost entirely depends on groundwater. However, over exploitation indicates falling groundwater heads in this area. The objective of present study is to examine the nature of the aquifer system Barind Tract of Bangladesh in order to assess the sustainability of groundwater yield. Borehole lithology data were collected, processed and analyzed for this purpose. Representative panel diagram, 3-D stratigraphic and cross-sectional views were also prepared for necessary assessment of the variation of individual subsurface stratum in different locations. The study identified three subsurface geologic formations namely, a top clay layer, sand layer of different grain size and at the bottom an impermeable clay zone. Maps of formation thickness and index revealed that aquifer thickness is low in the north-western corner and in some places of middle of south-western corner. The thickness of sand formation in other places is recorded above 20 m. It is expect that the finding of the study will help groundwater resources development, planning and management in the area.     

Evaluation of Bioavailability and Partitioning of Aluminum in Sediment Samples of Different Ecosystems by Modified Sequential Extraction Methods

Sequential extraction procedures are widely used to characterize the different operational fractions with different potential toxicity of metals in environmental solid samples. The present work describes the application of different analytical approaches for sequential extraction of aluminum to evaluate its mobility, availability, and persistent chemical forms in sediment samples of different fresh water ecosystems (lake, canal, and river). The conventional BCR three‐stage sequential extraction procedure (C‐BCR) was modified at each stage, by applying ultrasonic device (U‐BCR), in order to shorten the required shaking time of 16 h for each three steps (excluding the hydrogen peroxide digestion in step 3, which was not performed with ultrasonic bath), could be completed in 40, 50, and 45 min, respectively. The aluminum in all extracts were determination by atomic absorption spectrometry using nitrous oxide – acetylene flame. The accuracy of results obtained from C‐BCR and proposed U‐BCR was verified with literature reported values of certified sediment sample (BCR 701). The overall recoveries of aluminum obtained by proposed U‐BCR were found in the range of 96.7–113% of those values obtained with C‐BCR for all fractions. Use of ultrasonic device, provided a large saving in extraction time relative to conventional shaking. It was observed that major part of Al in real sediment samples (80–83% of total Al) were bound to residual fraction. The acid soluble fraction of aluminum extracted by 0.11 mol/L CH₃COOH has good correlation with aluminum content in corresponding water samples of each ecosystem.     

Thermal Drying and Alkaline Treatment of Biosolids: Effects on Nitrogen Mineralization

Biosolids from the Cañeveralejo WWTP were dehydrated by filter press and then applied two processes to reduce pathogens (PRP): thermally dried biosolid (TDB) and alkalinized biosolid (AB). Untreated, dehydrated biosolid (DB) was used as a control. We evaluated the impact of thermal drying and alkaline treatments on nitrogen mineralization in these substrates. Moreover, agronomic rates for biosolid applications to sugarcane were estimated for each of the treatments leading to application rates of 35.8, 36.4, and 54.5 t/ha for DB, TDB, and AB, respectively, to meet the nitrogen requirement (200 kg N/ha) for sugarcane cultivation (Saccharum officinarum). The results showed that the biosolid rates used increased the mineral nitrogen content of soils by an average of 93.8 and 439.8 mg/kg for all biosolids and the PRP (thermal drying and alkaline treatment) in biosolids had significant effects on mineralization rate, showing better results for the TDBs.     

Removal of Chromium from Synthetic Effluent using Nymphaea rubra

In the present work, biosorption of Cr(VI) by Nymphaea rubra was investigated in batch studies. Batch experiments were conducted to study the effect of initial sorbent dosage, solution pH and initial Cr(VI) concentration. The results showed that the equilibrium uptake capacity was increased with decrease in biomass dosage. The Cr(VI) removal was influenced by the initial chromium compound concentration. Langmuir and Freundlich adsorption isotherm models were used to represent the equilibrium data. The Freundlich isotherm model was fitted very well with the equilibrium data when compared to Langmuir isotherm model. The sorption results were analyzed for pseudo‐first order and pseudo‐second order kinetic model. It was observed that the kinetic data fitted very well with the pseudo‐second order rate equation when compared to the pseudo‐first order rate equation. Fourier transform infrared spectrum showed the presence of different functional groups in the biomass. The surface morphology of the sorbent was exemplified by SEM analysis. Aquatic weeds seem to be a promising biosorbent for the removal of chromium ions from water environment. This paper reports the research findings of a laboratory‐based study on the removal of Cr(VI) from the synthetic solution using the dried stem of N. rubra as a biosorbent.     

Dust ion-acoustic shock waves in nonextensive dusty plasma

A parametric survey on the propagation characteristics of the dust ion-acoustic (DIA) shock waves showing the effect of nonextesivity with nonextensive electrons in a dissipative dusty plasma system has been carried out using the reductive perturbation technique. We have considered continuity and momentum equations for inertial ions, q-distributed nonextensive electrons, and stationary charged dust grains, to derive the Burgers equation. It has been found that the basic features of DIA shock waves are significantly modified by the effects of electron nonextensivity and ion kinematic viscosity. Depending on the degree of nonextensivity of electrons, the dust ion-acoustic shock structures exhibit compression and rarefaction. The implications of our results would be useful to understand some astrophysical and cosmological scenarios like stellar polytropes, hadronic matter and quark-gluon plasma, protoneutron stars, dark-matter halos, etc., where effects of nonextensivity can play the significant roles.     

Nonlinear propagation of dust-acoustic waves in a magnetized nonextensive dusty plasma

A theoretical investigation has been made of obliquely propagating dust-acoustic solitary waves in a magnetized three-component dusty plasma, which consists of a negatively charged dust fluid, ions, and nonextensive electrons. The reductive perturbation method has been employed to derive the Korteweg-de Vries equation which admits a solitary wave solution. It has been shown that the combined effects of external magnetic field (obliqueness), ions, and electron nonextensivity change the behavior of these electrostatic solitary structures that have been found to exist with positive and negative potential in this dusty plasma model. The implications of our results in astrophysical and cosmological scenarios like vicinity of the Moon, magnetospheres of Jupiter and Saturn, dark-matter halos, hadronic matter, quark-gluon plasma, protoneutron stars, stellar polytropes etc. have been mentioned.