K–Ar ages of the basaltic rocks from Far East Russia: Constraints on the tectono-magmatism associated with the Japan Sea opening

K–Ar ages of the Cenozoic basaltic rocks from the Far East region of Russia (comprising Sikhote-Alin and Sakhalin) are determined to obtain constraints on the tectono-magmatic evolution of the Eurasian margin by comparison with the Japanese Islands, Northeast China, and the formation of the back-arc basin. In the early Tertiary stage (54–26 Ma), the northwestward subduction of the Pacific Plate produced the active continental margin volcanism of Sikhote-Alin and Sakhalin, whereas the rift-type volcanism of Northeast China, inland part of the continent began to develop under a northeast–southwest-trending deep fault system. In the early Neogene (24–17 Ma), a large number of subduction-related volcanic rocks were erupted in connection with the Japan Sea opening. After an inactive interval of the volcanism ∼ 20–13 Ma ago, the late Neogene (12–5 Ma) volcanism of Sikhote-Alin and Sakhalin became distinct from those of the preceding stages and indicated within-plate geochemical features similar to those of Northeast China, in contrast to the Japan Arc which produces island arc volcanism. During the Japan Sea opening, the northeastern Eurasian margin detached and became a continental island arc system, and an integral part of continental eastern Asia comprising Sikhote-Alin, Sakhalin and Northeast China, and the Japan Arc with a back-arc basin. The convergence between the Eurasian Plate, the Pacific Plate and the Indian Plate may have contributed to the Cenozoic tectono-magmatism of the northeastern Eurasian continent.     

Postglacial stratigraphic evolution of a current-influenced sandy shelf: offshore Kujukuri strandplain,central Japan

Sandy shelf sediments are important elements of clastic sedimentary systems because of their wide distribution in the geological record and their significance as hydrocarbon reservoirs. Although many studies have investigated shelf sediments influenced by waves or tidal currents, little is known about shelf sediments influenced by oceanic currents, particularly their lithofacies characteristics and stratigraphic evolution. This study investigated the stratigraphic evolution of shelf sediments off the Kujukuri strandplain facing the Pacific Ocean, which is influenced by the strong Kuroshio Current. Sediment cores were obtained from six locations on the Kujukuri shelf (34 to 124 m water depth) using a vibrocorer. The dominant lithofacies is mud-free sand with low-angle cross-lamination associated with alternating beds of finer and coarser sand with cross-lamination. These display depositional processes influenced by storm waves and the Kuroshio Current, respectively. This finding is consistent with the previously presented modern and historical observations of the Kuroshio Current and estimates of the storm-wave base. Radiocarbon dates show that the sediment succession formed during the last transgressive and highstand stages after 13·1 ka. The depositional processes during the stages represent a transition from storm waves with abundant sediment supply to both storm waves and the Kuroshio Current with sediment starvation mainly due to its trapping in the strandplain. Comparison to other Holocene–Modern shelf systems suggests that the sandy shelf successions are strongly influenced by oceanic currents under conditions of limited riverine input and open coastal geometry. The resultant sand-dominated succession is characterized by reversal of the proximal to distal grain-size trend compared to the fining for most other recognized wave/storm-dominated shelf successions. This is because of seaward increase in the influence of the Kuroshio Current. Thus, shelf deposits are naturally complex, and these may be further complicated by the additional influence of oceanic currents above the usual wave-dominated and tide-dominated end members.     

Adsorption of tributyltin by tributyltin resistant marine Pseudoalteromonas sp. cells

The isolate, Pesudoalteromonas sp. TBT1, could grow to overcome the toxicity of tributyltin chloride (TBTCl) up to 30 microM in the absence of Cl(-) in the medium until the cells reached an exponential phase of growth. The viability, however, was reduced after the cells reached a stationary phase. The degradation products, such as dibutyltin (DBT) and monobutyltin (MBT), were not detected in the growth medium, indicating that the isolate has no ability to degrade TBT into less toxic DBT and MBT. Up to about 10(7.5) TBT molecules were adsorbed by a single cell. The observation of morphological changes with an electron microscope showed that the cell surface became wrinkled after exposure to the lethal concentration of 10 mM TBTCl. These results indicate that the resistance of the isolate toward the toxicity of TBTCl is not related to the unique cell surface, which seems to play an important role in preventing the diffusion of TBTCl into the cytoplasm.     

Adsorption of tributyltin by tributyltin resistant marine Pseudoalteromonas sp. cells

The isolate, Pesudoalteromonas sp. TBT1, could grow to overcome the toxicity of tributyltin chloride (TBTCl) up to 30 μM in the absence of Cl⁻ in the medium until the cells reached an exponential phase of growth. The viability, however, was reduced after the cells reached a stationary phase. The degradation products, such as dibutyltin (DBT) and monobutyltin (MBT), were not detected in the growth medium, indicating that the isolate has no ability to degrade TBT into less toxic DBT and MBT. Up to about 10^7.5 TBT molecules were adsorbed by a single cell. The observation of morphological changes with an electron microscope showed that the cell surface became wrinkled after exposure to the lethal concentration of 10 mM TBTCl. These results indicate that the resistance of the isolate toward the toxicity of TBTCl is not related to the unique cell surface, which seems to play an important role in preventing the diffusion of TBTCl into the cytoplasm.     

High-pressure X-ray diffraction studies on β- and γ-Mg2SiO4

Pressure effects on the lattice parameters of β- and γ-Mg₂SiO₄ have been measured at room temperature and at pressures up to 100 kbar using a multi-anvil high-pressure X-ray diffraction apparatus. The volume changes (ΔV/V₀) at 90 kbar are 5.4 · 10^?2 and 4.2 · 10^?2 for β- and γ-Mg₂SiO₄, respectively. Isothermal bulk moduli at zero pressure have been calculated from least-square fits of the data to straight lines. They turn out to be 1.66 ± 0.4 and 2.13 ± 0.1 Mbar for β- and γ-Mg₂SiO₄, respectively. The α → γ transition obeys Wang's linear V_φ?ρ relation but the α → β transition does not.     

Chemostratigraphy of the Ediacaran basinal setting on the Yangtze platform,South China: Oceanographic and diagenetic aspects of the carbon isotopic depth gradient

The Ediacaran Yangtze platform in South China, which represents depositional settings ranging from coastal to basinal, provides valuable information for understanding climate changes and animal evolution during the Ediacaran Period. Although the shallower settings have been investigated, research on the basinal sections has been limited. This has hampered efforts to establish stratigraphic correlations and understand the oceanographic setting of the Yangtze platform. In this paper, the chemostratigraphy of a basinal section at Fengtan, Hunan Province, is reported based on analyses of stable carbon isotope profiles in carbonates (δ¹³C_carb), organic matter (δ¹³C_org), total organic carbon, ⁸⁷Sr/⁸⁶Sr ratios, and Mn, Rb, and Sr concentrations. The basinal section of the Doushantuo Formation, which is represented at Fengtan, provides data supporting regional correlations and oceanography. Three intervals in the Doushantuo Formation are correlated with the Three Gorges: (i) a negative δ¹³C_carb anomaly with stable δ¹³C_org values and altered ⁸⁷Sr/⁸⁶Sr ratios in the lower section can be correlated to the boundary between Doushantuo Members 2 and 3 (Interval A); (ii) a relatively high δ¹³C_carb anomaly with unaltered ⁸⁷Sr/⁸⁶Sr ratios (up to 0.7086) in the middle section corresponding to the lower part of Doushantuo Member 3 (Interval B); and (iii) a negative δ¹³C_carb anomaly with lowered δ values in the upper section can be correlated to the long interval of negative δ¹³C_carb (Interval C). The Gaskiers glaciation is likely represented in Interval A, and Interval C corresponds to the Shuram excursion reported for other Ediacaran localities. Our correlations confirm the depth gradient of δ¹³C_carb in the Yangtze platform and imply that reductive conditions prevailed in the basinal section from the Early to Middle Ediacaran. Under such conditions, anaerobic degradation of organic carbon or methane perturbed the inorganic carbon isotopic compositions and was at least partly responsible for the depth gradient of δ¹³C_carb.