Osmium Isotopic Evidence for Crust-Mantle Interaction in the Genesis of Continental Intraplate Basalts from the Newer Volcanics Province, Southeastern Australia

Basalts from the Quaternary Newer Volcanics Province in southeasternAustralia have a large diversity in their chemical and Nd, Srand Os isotopic compositions. Plains series olivine tholeiitesand Cones series nepheline hawaiites have distinctive isotopiccompositions and are clearly not related to each other by asimple genetic process. The Cones series nepheline hawaiiteshave trace element abundances and Nd (     

Stardust impact analogs: Resolving pre‐ and postimpact mineralogy in Stardust Al foils

Abstract– The grains returned by NASA’s Stardust mission from comet 81P/Wild 2 represent a valuable sample set that is significantly advancing our understanding of small solar system bodies. However, the grains were captured via impact at ～6.1 km s^?1 and have experienced pressures and temperatures that caused alteration. To ensure correct interpretations of comet 81P/Wild 2 mineralogy, and therefore preaccretional or parent body processes, an understanding of the effects of capture is required. Using a two‐stage light‐gas gun, we recreated Stardust encounter conditions and generated a series of impact analogs for a range of minerals of cometary relevance into flight spare Al foils. Through analyses of both preimpact projectiles and postimpact analogs by transmission electron microscopy, we explore the impact processes occurring during capture and distinguish between those materials inherent to the impactor and those that are the product of capture. We review existing and present additional data on olivine, diopside, pyrrhotite, and pentlandite. We find that surviving crystalline material is observed in most single grain impactor residues. However, none is found in that of a relatively monodisperse aggregate. A variety of impact‐generated components are observed in all samples. Al incorporation into melt‐derived phases allows differentiation between melt and shock‐induced phases. In single grain impactor residues, impact‐generated phases largely retain original (nonvolatile) major element ratios. We conclude that both surviving and impact‐generated phases in residues of single grain impactors provide valuable information regarding the mineralogy of the impacting grain whilst further studies are required to fully understand aggregate impacts and the role of subgrain interactions during impact.     

Modelling reservoir sedimentation and estimating historical deposition rates using a data-based mechanistic (DBM) approach

Abstract

The data-based mechanistic (DBM) modelling methodology is applied to the study of reservoir sedimentation. A lumped-parameter, discrete-time model has been developed which directly relates rainfall to suspended sediment load (SSL) at the reservoir outflow from the two years of measured data at Wyresdale Park Reservoir (Lancashire, UK). This nonlinear DBM model comprises two components: a rainfall to SSL model and a second model, relating the SSL at the reservoir inflow to the SSL at the reservoir spillway. Using a daily measured rainfall series as the input, this model is used to reconstruct daily deposition rates between 1911 and 1996. This synthetic sediment accretion sequence is compared with the variations in sand content within sediment cores collected from the reservoir floor. These profiles show good general agreement, reflecting the importance of low reoccurrence, high magnitude events. This preliminary study highlights the potential of this DBM approach, which could be readily applied to other sites.     

Primitive Magma From the Jericho Pipe, N.W.T., Canada: Constraints on Primary Kimberlite Melt Chemistry

We report the first estimates of primary kimberlite melt compositionfrom the Slave craton, based on samples of aphanitic kimberlitefrom the Jericho kimberlite pipe, N.W.T., Canada. Three samplesderive from the margins of dykes where kimberlite chilled againstwall rock (JD51, JD69 and JD82) and are shown to be texturallyconsistent with crystallization from a melt. Samples JD69 andJD82 have geochemical characteristics of primitive melts: theyhave high MgO (20–25 wt %), high mg-numbers (86–88),and high Cr (1300–1900 ppm) and Ni (800–1400 ppm)contents. They also have high contents of CO₂ (10–17 wt%). Relative to bulk macrocrystal kimberlite, they have lowermg-numbers and lower MgO but are enriched in incompatible elements(e.g. Zr, Nb and Y), because the bulk kimberlite compositionsare strongly controlled by accumulation of mantle olivine andother macrocrysts. The compositions of aphanitic kimberlitefrom Jericho are similar to melts produced experimentally bypartial melting of a carbonate-bearing garnet lherzolite. Onthe basis of these experimental data, we show that the primarymagmas from the Jericho kimberlite could represent 0·7–0·9%melting of a carbonated lherzolitic mantle source at pressuresand temperatures found in the uppermost asthenosphere to theSlave craton. The measured CO₂ contents for samples JD69 andJD82 are only slightly lower than the CO₂ contents of the correspondingexperimental melts; this suggests that the earliest hypabyssalphase of the Jericho kimberlite retained most of its originalvolatile content. As such these samples provide a minimum CO₂content for the primary kimberlite magmas from the Slave craton. KEY WORDS: kimberlite; melt; primitive; primary magma; Slave craton     

Deposition and derivation of clastic carbonates on a Mesozoic continental margin, Othris, Greece

The Othris Mountains of eastern Greece contain a calcareous continental margin/ocean basin sequence exposed in a stack of Cretaceous thrust sheets. Upper Triassic to Lower Cretaceous shelf, submarine fan and basinal successions overlie shallow marine units of Lower Triassic and Permian age. In off-shelf sequences the older sediments are separated from the younger by a horizon of alkaline ‘early-rifting’ basalts. Ophiolites overthrust the marginal sequence. Pre-rifting sediments are represented by a varied suite of limestones and clastics resting on metamorphic basement and include distinctive, green lithic arenites. In the thrust sheet immediately over the para-autochthonous shelf sequence, pre-rifting sediments are separated from the rift basalts by an intermittent horizon of calcareous sandstones and conglomerates reworked from uplifted basement and older sediments. Textural and petrographic immaturity suggests that these are probably deposits derived from fault scarps, produced in an early phase of rifting. Above the basalts in the same sheet is a suite of calciclastic sediment-gravity-flow deposits, apparently sedimented on a submarine fan. Progressive downslope modification of calcirudites suggests deposition from evolving, high concentration flows. Massive calcarenite facies (? grain flows) are unusually abundant; a possible reflection of a shallow palaeo-shelf break since provenance and palaeocurrent evidence proves the clastic carbonates to have been derived from a calcareous shelf. In addition to limestone lithoclasts the calcirudites, but not the massive calcarenites, contain fragments of pre-rifting lithologies including the distinctive arenites. Since the shelf sequence in Othris is totally nondetrital these clasts imply derivation of coarse sediment from an off-shelf position; probably the walls of a submarine canyon. This may have occurred either by direct erosion of wall rock, or by reworking of material from an older clastic sequence. In the latter case the inferred fault-scarp deposits are a likely source.     

The origin of crystalline residues in Stardust Al foils: Surviving cometary dust or crystallized impact melts?

Abstract– Samples returned by the Stardust mission from comet 81P/Wild 2 provide an unequaled opportunity to investigate cometary formation and evolution. Crystalline silicates have been identified in impact craters in Stardust Al foil, yet their origin is ambiguous. They may be original cometary components, or they may have grown from melt generated by impact. We have now studied experimental impacts of the calcium silicate mineral wollastonite, using scanning and transmission electron microscopy to document the relationship between impact feature shape and crystal lattice orientation in impact residue. Wollastonite can have a characteristic acicular habit, forming crater shapes that indicate crystal orientation upon impact. From extracted impact residue, we determined the lattice orientation of crystalline material for comparison with the whole particle orientation. We assume that crystallization from melt, without surviving seed nuclei, should result in randomly oriented crystallite growth, with no preferred direction for individual crystals. However, we find that the majority of crystalline material in the residue retains b‐axis orientation parallel to the long axis of the crater form. This, together with impact parameter calculations and lack of Al incorporation by the residue (suggesting melting did not occur), indicates that these crystals and, by analogy, the majority of Al‐free crystalline silicates in Stardust foil, are surviving remnants of the impactor. Furthermore, amorphous wollastonite residue probably did not form via melting and subsequent quenching, but instead by high‐pressure amorphization or degradation of unquenchable phases. Finally, one crystal studied appears to be a new high‐pressure/temperature polymorph of CaSiO₃, indicating that such polymorphs may be observed in Stardust residues in craters.     

The preservation of fossil biomarkers during meteorite impact events: Experimental evidence from biomarker‐rich projectiles and target rocks

Abstract– A Devonian siltstone from Orkney, Scotland, shows survival of biomarkers in high‐velocity impact experiments. The biomarkers were detected in ejecta fragments from experiments involving normal incidence of steel projectiles at 5–6 km s^?1, and in projectile fragments from impact experiments into sand and water at 2–5 km s^?1. The associated peak shock pressures were calculated to be in the range of 110–147 GPa for impacts of the steel projectiles into the siltstone target, and hydrocode simulations are used to show the variation of peak pressure with depth in the target and throughout the finite volume projectiles. Thermally sensitive biomarker ratios, including ratios of hopanoids and steranes, and the methylphenanthrene ratio, showed an increase in thermal maturity in the ejecta, and especially the projectile, fragments. Measurement of absolute concentrations of selected biomarkers indicates that changes in biomarker ratios reflect synthesis of new material rather than selective destruction. Their presence in ejecta and projectile fragments suggests that fossil biomarkers may survive hypervelocity impacts, and that experiments using biomarker‐rich rock have high potential for testing survival of organic matter in a range of impact scenarios.     

Comet 81P/Wild 2: The size distribution of finer (sub‐10 μm) dust collected by the Stardust spacecraft

Abstract– The fluence of dust particles <10 μm in diameter was recorded by impacts on aluminum foil of the NASA Stardust spacecraft during a close flyby of comet 81P/Wild 2 in 2004. Initial interpretation of craters for impactor particle dimensions and mass was based upon laboratory experimental simulations using projectiles less than >10 μm in diameter and the resulting linear relationship of projectile to crater diameter was extrapolated to smaller sizes. We now describe a new experimental calibration program firing very small monodisperse silica projectiles (470 nm–10 μm) at approximately 6 km s^?1. The results show an unexpected departure from linear relationship between 1 and 10 μm. We collated crater measurement data and, where applicable, impactor residue data for 596 craters gathered during the postmission preliminary examination phase. Using the new calibration, we recalculate the size of the particle responsible for each crater and hence reinterpret the cometary dust size distribution. We find a greater flux of small particles than previously reported. From crater morphology and residue composition of a subset of craters, the internal structure and dimensions of the fine dust particles are inferred and a “maximum‐size” distribution for the subgrains composing aggregate particles is obtained. The size distribution of the small particles derived directly from the measured craters peaks at approximately 175 nm, but if this is corrected to allow for aggregate grains, the peak in subgrain sizes is at <100 nm.