Ocean-floor hydrothermal metamorphism in the Limousin ophiolites (western French Massif Central): evidence of a rare preserved Variscan oceanic marker

The Limousin ophiolite is located at the suture zone between two major thrust sheets in the western French Massif Central. This ophiolitic section comprises mantle‐harzburgite, mantle‐dunite, wehrlites, troctolites and layered gabbros. It has recorded a static metamorphic event transforming the gabbros into undeformed amphibolites and the magmatic ultramafites into serpentinites and/or pargasite‐bearing chloritites. With various thermobarometric methods, it is possible to show that the different varieties of amphibole have registered low‐P (c. 0.2 GPa) conditions with temperature ranging from high‐T, late‐magmatic conditions to greenschist–zeolite metamorphic facies. The abundance of undeformed metamorphic rocks (which is typical of the lower oceanic crust), the occurrence of Ca–Al (–Mg) metasomatism illustrated by the growth of Ca–Al silicates in veins or replacing the primary magmatic minerals, the P–T conditions of the metamorphism and the numerous similarities with oceanic crustal rocks from Ocean Drilling Program and worldwide ophiolites are the main arguments for an ocean‐floor hydrothermal metamorphism in the vicinity of a palaeo‐ridge. Among the West‐European Variscan ophiolites, the Limousin ophiolites constitute an extremely rare occurrence that has not been involved in any HP (subduction‐related) or MP (orogenic) metamorphism as observed in other ophiolite occurrences (i.e. France, Spain and Germany).     

Diagenetic formation of gypsum and dolomite in a cold‐water coral mound in the Porcupine Seabight,off Ireland

Authigenic gypsum was found in a gravity core, retrieved from the top of Mound Perseverance, a giant cold‐water coral mound in the Porcupine Basin, off Ireland. The occurrence of gypsum in such an environment is intriguing, because gypsum, a classic evaporitic mineral, is undersaturated with respect to sea water. Sedimentological, petrographic and isotopic evidence point to diagenetic formation of the gypsum, tied to oxidation of sedimentary sulphide minerals (i.e. pyrite). This oxidation is attributed to a phase of increased bottom currents which caused erosion and enhanced inflow of oxidizing fluids into the mound sediments. The oxidation of pyrite produced acidity, causing carbonate dissolution and subsequently leading to pore‐water oversaturation with respect to gypsum and dolomite. Calculations based on the isotopic compositions of gypsum and pyrite reveal that between 21·6% and 28·6% of the sulphate incorporated into the gypsum derived from pyrite oxidation. The dissolution of carbonate increased the porosity in the affected sediment layer but promoted lithification of the sediments at the sediment‐water interface. Thus, authigenic gypsum can serve as a signature for diagenetic oxidation events in carbonate‐rich sediments. These observations demonstrate that fluid flow, steered by environmental factors, has an important effect on the diagenesis of coral mounds.     

Late Glacial stable isotope record, radiocarbon stratigraphy, pollen and mollusc analyses from the Geiseltal area, Central Germany

Combined investigations of isotopes, pollen, and molliisc shells were carried out on a Latc Glacial limnic high-resolution sediment sequence from the Geiseltal open-cast mine in Central Gcrmany. The dala confirm thc division of the Late Glacial biozones into two colder (Older and Younger Dryas) and two warmer periods (Bølling, Allcrød), which have already bccn cstablishcd lor the Central and Northern German area. Radiocarbon data, mainly based on wood material, cover a time span between c , 10 800 BP and 12 760 BP, indicating a mean sedimentation rate of c . 2 mm/yr. The stable isotope data (δ¹⁸O, δ¹³C) reflect the transition periods between the climatic phases as changes in relative air humidity (transition from dry, cold to warmer. more humid conditions). The dominance of evaporation effects, however, is superimposed on any ternpcratiirc aignal throughout the profile. Repeated conversions of the hydrologic regime (silting-up phases. lake-level variations) characterize the specific history of the lake development.     

POST‐LITTLE ICE AGE PATTERNED GROUND DEVELOPMENT ON TWO PYRENEAN PROGLACIAL AREAS: FROM DEGLACIATION TO PERIGLACIATION

This study aims to observe post‐Little Ice Age glacier retreat and the constitutive patterned ground development at two French Pyrenean glacier forelands (Taillon Glacier and Pays Baché Glacier). Periglacial feature observations are associated with periods of deglaciation using aerial photos and archive files. Four conclusions are drawn. (1) The two glaciers have lost respectively 68% and 92% of their surface since 1850, which corroborates observations on other Pyrenean glaciers. (2) Patterned ground can develop very rapidly, sometimes only 10 years after deglaciation. (3) Patterned ground size does not systematically increase as a function of the time elapsed since deglaciation. (4) All the forms, even those developing near the Little Ice Age moraines, are active. We propose that the location, activity and size of patterned ground are more probably linked to drift characteristics and local wetness conditions than to the time elapsed since deglaciation.     

Vegetation and climate history in the Westeifel Volcanic Field (Germany) during the past 11 000 years based on annually laminated lacustrine maar sediments

Lakes Holzmaar and Meerfelder Maar are located in the Westeifel Volcanic Field less than 10 km apart. Both maar lakes are well known for their annually laminated (varved) sediments covering the past 15 000 years. Here, we focus on reconstructing the history of Holocene vegetation, human impact and climate using high-resolution pollen data. Detailed correlation between the two records using palynologically defined tie-points provides for the first time a test of the precision of the individual varve chronologies. The high-resolution pollen records of both Holzmaar and Meerfelder Maar show continuous natural successions of vegetation during the early and mid-Holocene controlled by the development of soil, climate, immigration and competitive expansion of thermophilous tree species. From 6500 varve yr BP onwards, human impact became an increasingly more important factor. Given the high chronological precision of both records, regional similarities, but also local differences of anthropogenically influenced vegetation changes, can be recognized. The reconstructed July temperature between 8500 and 5000 varve yr BP is around 1 °C higher than today, most likely in response to higher summer insolation related to orbital forcing. High variability of reconstructed July and January temperatures as well as annual precipitation around 5000 varve yr BP is a prominent climatic signal. This is consistent with other records in several areas of Europe which also identify this period as climatically highly variable.     

Cessation and partial reversal of deep water freshening in the northern North Atlantic: observation-based estimates and attribution

Recent decadal salinity changes in the Greenland-Scotland overflow-derived deep waters are quantified using CTD data from repeated hydrographic sections in the Irminger Sea. The Denmark Strait Overflow Water salinity record shows the absence of any net change over the 1980s–2000s; changes in the Iceland–Scotland Overflow Water (ISOW) and in the deep water column (σ₀ > 27.82), enclosing both overflows, show a distinct freshening reversal in the early 2000s. The observed freshening reversal is a lagged consequence of the persistent ISOW salinification that occurred upstream, in the Iceland Basin, after 1996 in response to salinification of the northeast Atlantic waters entrained into the overflow. The entrainment salinity increase is explained by the earlier documented North Atlantic Oscillation (NAO)-induced contraction of the subpolar gyre and corresponding northwestward advance of subtropical waters that followed the NAO decline in the mid-1990s and continued through the mid-2000s. Remarkably, the ISOW freshening reversal is not associated with changes in the overflow water salinity. This suggests that changes in the NAO-dependent relative contributions of subpolar and subtropical waters to the entrainment south of the Iceland–Scotland Ridge may dominate over changes in the Nordic Seas freshwater balance with respect to their effect on the ISOW salinity.     

Source Rock Characterization and Petroleum Systems in North Ghadames Basin,Southern Tunisia

This paper presents geochemical analysis of drilled cutting samples from the OMZ‐2 oil well located in southern Tunisia. A total of 35 drill‐cutting samples were analyzed for Rock‐Eval pyrolysis, total organic carbon (TOC), bitumens extraction and liquid chromatography. Most of the Ordovician, Silurian and Triassic samples contained high TOC contents, ranging from 1.00 to 4.75% with an average value of 2.07%. The amount of hydrocarbon yield (pyrolysable hydrocarbon: S2b) expelled during pyrolysis indicates a good generative potential of the source rocks. The plot of TOC versus S2b, indicates a good to very good generative potential for organic matter in the Ordovician, Silurian and Lower Triassic. However, the Upper Triassic and the Lower Jurassic samples indicate fair to good generative potential. From the Vankrevelen diagram, the organic matter in the Ordovician, Silurian and Lower Triassic samples is mainly of type II kerogen and the organic matter from the Upper Triassic and the Lower Jurassic is dominantly type III kerogen with minor contributions from Type I. The thermal maturity of the organic matter in the analyzed samples is also evaluated based on the T_max of the S2b peak. The Ordovician and Lower Silurian formations are thermally matured. The Upper Silurian and Triassic deposits are early matured to matured. However, Jurassic formations are low in thermal maturity. The total bitumen extracts increase with depth from the interval 1800–3000 m. This enrichment indicates that the trapping in situ in the source rocks and relatively short distance vertical migration can be envisaged in the overlying reservoirs. During the vertical migration from source rocks to the reservoirs, these hydrocarbons are probably affected by natural choromatography and in lower proportion by biodegradation.     

Plume-Lithosphere Interaction and the Origin of Continental Rift-related Alkaline Volcanism--the Chyulu Hills Volcanic Province, Southern Kenya

Geochemical data are presented for primitive alkaline lavasfrom the Chyulu Hills Volcanic Province of southern Kenya, situatedsome 100 km east of the Kenya Rift Valley. In addition to theirprimitive compositions, a striking and ubiquitous feature isa strong but variable depletion in K relative to other highlyincompatible elements when normalized to primitive mantle values.Semi-quantitative models are developed that best explain thepetrogenesis of these lavas in terms of partial melting of asource that contained residual amphibole (but not phlogopite).The presence of amphibole implies a source in the subcontinentallithosphere rather than the asthenosphere. It is suggested thatthe amphibole is of metasomatic origin and was precipitatedin the lithospheric mantle by infiltrating fluids and/or meltsderived from rising mantle plume material. A raised geothermas a consequence of the continued ascent of the plume materialled to dehydration melting of the metasomatized mantle and generationof the Chyulu Hills lavas. It is proposed that the Chyulu HillsVolcanic Province represents an analogue for the earliest stagesof continental rift initiation, during which interaction betweena plume and initially refractory lithosphere may lead to thegeneration of lithospheric melts. KEY WORDS: rift-related alkaline volcanism; residual amphibole; subcontinental lithosphere     

Palaeopedological marker horizons in northern central Europe: characteristics of Lateglacial Usselo and Finow soils

Lateglacial buried soil horizons, which occur widely in sandy aeolian sequences of northern central Europe, were analysed in order to evaluate their regional pedostratigraphical and palaeoenvironmental potential. Data on stratigraphy, sedimentology, pedology, geochronology and palaeobotany from 29 palaeosol-bearing profiles at terrestrial sites are presented. Greyish Ahb and Eb horizons occur, as well as brownish Bwb and BwAhb horizons. They are 5–30 cm thick, showing similar pedological properties except colour, and they frequently bear charcoal typically from pine. Soil classification results in Albic Arenosols (Dystric) and Brunic Arenosols (Dystric) representing palaeosols of the Usselo and Finow types, respectively. Radiocarbon dating of the palaeosols reveals a dominance of Allerød ages followed by Younger Dryas and Preboreal ages. Most luminescence ages on overlying aeolian sands date into the Allerød–Younger Dryas interval. Mapping of all Usselo and Finow soil occurrences ( n =96) in northern central Europe known so far reveals a nearly closed Finow soil province between Usselo soil areas in NW Germany and central Poland, mainly situated in NE Germany. Most Usselo soils compiled contain charcoal, indicating widespread and repeated fires. Recent claims that the Usselo soil represents an event layer from rapid aeolian sedimentation caused by an extraterrestrial impact is rejected. Instead, both Usselo and Finow soils can be assumed to be pedostratigraphical marker horizons in northern central Europe and beyond.