贵州夜郎湖表层水体地球化学昼夜变化及其影响因素

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。     

CORROSION RESISTANCE OF INTERFERENCE FILM ON STAINLESS STEEL

IwrRODUcrlONStainlessstalhasbeenusedwidelyasbuildingrnateria1,especiallyasdecoratingrnate-rialinbuildings.Ordinarystainlesssteehasonlyonemonot0noussilverywhitCcolourwhichsomeimesdoesnotrnatchwithitSsurmundingenvironment.lnordert0improveitSdereratingperfonnaneeandexpanditsuse,muchresearchhasbeenconductedsincethe4O'st0trytoformabright,uniform,highcorrosi0nandwearresistantco1ourfilmonastainlesssteesurface.Duringtheeariystage,anirnmersionedhodwasused,i.e.inimrs-ingthestainlesssteelinahots0luti…     

CARBON DYNAMICS OF WETLAND IN THE SANJIANG PLAIN

1INTRODUCTIONWetlandsplayanimportant roleintheprocessofcar-bonstorage.Thetotalcarbonstoredindifferentkindsofwetlandsisabout15%-35%ofthetotalcarboninthegloballandsoils(POSTetal.,1982;GORHAM,1991).Inaddition,wetlandsaresignificantnaturalsources fortheatmospheric CH4 (MOORE,1994).It isestimatedthatabout110×1012gCH4 originates fromanaerobicdecompositioninthenaturalwetlands,CH4 emission fromthenaturalwetlandsis15%-30%oftheglobalCH4 emission andtheCH4 emission from thepeat land at hi…     

The masers of E-type methanol in orion KL and SGR B2

Using a simplified model the statistical equilibrium and radiative transfer equations of E-type-CH₃OH are solved for Orion KL and SgrB2. According to our calculation results and the observation data taken by Matsakiset al. (1980) and Morimotoet al. (1985a, b), the physical conditions of both sources are estimated. In theJ ₂-J ₁ E methanol maser region of Orion KL, the density, kinetic temperature, dust temperature, and the fractional abundance are 0.8–2×10⁶ cm^–3, 150, 30–90 K, 0.8–8×10^–6. In the 4_–1-3₀ E and 5_–1-4₀ E methanol maser region of Sgr B2 the correspondance physical conditions above are 10⁴ cm³, 45, 23 K, and 7×10^–7, respectively.     

Seal integrity and feasibility of CO<Subscript>2</Subscript> sequestration in the Teapot Dome EOR pilot: geomechanical site characterization

This paper reports a preliminary investigation of CO₂ sequestration and seal integrity at Teapot Dome oil field, Wyoming, USA, with the objective of predicting the potential risk of CO₂ leakage along reservoir-bounding faults. CO₂ injection into reservoirs creates anomalously high pore pressure at the top of the reservoir that could potentially hydraulically fracture the caprock or trigger slip on reservoir-bounding faults. The Tensleep Formation, a Pennsylvanian age eolian sandstone is evaluated as the target horizon for a pilot CO₂ EOR-carbon storage experiment, in a three-way closure trap against a bounding fault, termed the S1 fault. A preliminary geomechanical model of the Tensleep Formation has been developed to evaluate the potential for CO₂ injection inducing slip on the S1 fault and thus threatening seal integrity. Uncertainties in the stress tensor and fault geometry have been incorporated into the analysis using Monte Carlo simulation. The authors find that even the most pessimistic risk scenario would require ∼10 MPa of excess pressure to cause the S1 fault to reactivate and provide a potential leakage pathway. This would correspond to a CO₂ column height of ∼1,500 m, whereas the structural closure of the Tensleep Formation in the pilot injection area does not exceed 100 m. It is therefore apparent that CO₂ injection is not likely to compromise the S1 fault stability. Better constraint of the least principal stress is needed to establish a more reliable estimate of the maximum reservoir pressure required to hydrofracture the caprock.     

正压浅海湍流运动的雷诺应力封闭模型

根据湍流封闭理论,建立一种适用于正压浅海湍流运动的雷诺应力封闭模型(RSM),以代替目前三维浅海动力学模型中普遍采用的湍粘性系数的传统假设。通过直接建立并模化f—平面上正压海洋的雷诺应力传输方程,分别得到的微分形式和代数形式的RSM方程组。并讨论了进行数值计算所需要的边界条件。利用该模型可以进一步研究浅海潮流、风暴潮流及风海流等浅海流动的三维结构和湍流特性。     

秦山核电站邻近水域浮游植物的生态研究

本文分析了秦山核电站邻近水域生态零点调查四个航次的浮游植物样品,结果表明:调查区浮游植物的种数和细胞密度在时间尺度上均存在明显的季节变化趋势:夏大于秋大于春大于冬,并且与环境因子的变化密切相关,其中最主要的影响因子是温度、盐度和径流,而影响日变化的环境因子主要是潮汐。     

海藻中类胡萝卜素抗超氧自由基活性研究

在植物组织内，类胡萝卜素除具有集光功能外，还具有其他的重要生物学功能，类胡萝卜素作为光保护剂可抵抗光、氧和光敏色素的有害作用，也可作为化学反应物抵抗细胞所产生的化学物质引起的氧化损伤，保护光合系统免受光动力敏化作用的破坏。类胡萝卜素光保护作用的主要机制如下:(1)类胡萝卜素对三重线态敏化剂的淬灭；(2)类胡萝卜素对1O2的淬灭；(3)类胡萝卜素对自由基反应的抑制，它的这种生物学活性在医学领域也具有重要的应用价值。胡萝卜素在生物系统中的保护作用包括失活由电激活的单线态氧(1O2)，失活反应性的化学物质如过氧化物自由基和烷氧基，这些自由基产生于细胞内，并可能会引起有害的氧化作用。类胡萝卜素的保护功能与直接的抗氧化活性或与对细胞内抗氧化水平的调节有关(Krinsky，1990)。对于类胡萝卜素清除脂类过氧化物自由基的能力和作用机理已经进行了详细的研究(Burton et al.，1984; Burton, 1989; Terao，1989; Palozza et al.，1992b; Tsuchihashi et al.，1995)，但对于类胡萝卜素清除超氧阴离子自由基的能力尚未见有详细研究报道。本文以邻苯三酚自氧化体系作为超氧自由基的发生体系，对海藻中分离纯化制备的类胡萝卜素清除该种自由基的能力进行了初步的探讨。     

虾蟹海产品香味的前体物质的加热变化

本文研究了虾蟹海产品香味的前体物质在加热前后的变化。实验结果表明：对虾和蟹肌肉中的糖原和不饱和脂肪酸在加热前后含量下降，糖原是Ｍａｉｌｌａｒｄ反应的基础物质．不饱和脂肪酸是虾蟹肌肉香味中羰基化合物的前体物质。虾蟹肌肉中主要积累的核苷酸成分ＡＭＰ在加热后减少，而肌肉提取物中的游离氨基酸和结合氨基酸，特别是疏水氨基酸含量均增加。