Chemical fingerprints of life in terrestrial soils and their possible use for the detection of life on Mars and other planets

Organic carbon in oxidizable forms and nitrogen are the only elements among some 40 elements studied that are significantly enriched in terrestrial soils as compared to the crust. This enrichment is due to and reflecting life activity in soils, and is characterized by a unique profile distribution. It is suggested that these facts can constitute the basis for the future chemical-biological search for life in planetary soils.     

Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.     

Glacial Erosion in the Abisko Mountains: Kärkevagge and Vassivagge, Northern Sweden

This paper discusses direct current resistivity soundings and geomorphological studies of Quaternary deposits in two glacial troughs in the Abisko Mountains of northern Sweden. The subject of the fieldwork is the depth of Pleistocene glacial erosion. Studies were carried out in 1998 and 2003 in the Kärkevagge and Vassivagge. The estimated thickness of Quaternary deposits and bedrock properties are discussed in the broader context of glacial erosion studies in the Abisko area. Geophysical and geomorphological studies suggest that the depth of glacial erosion was highly differentiated from –190 m in the Torneträsk basin to the metric overall erosion on the upland plateau. In medium‐sized valleys several kilometres long, erosion depth measures 30–50 m. Present‐day stream channel patterns reveal a strong relation to the bedrock configuration in valley floors     

Geochemistry and Rb–Sr geochronology of a ductile shear zone in the Orlica-Śnieżnik dome (West Sudetes, Poland)

Amphibolite-facies orthogneisses of the Orlica-vnie™nik dome in the West Sudetes (Poland) show a local continuous transition from weakly deformed augen gneisses to finely laminated mylonites. Field evidence indicates that ductile shearing developed pre- or syntectonically to a migmatization event. Bulk-rock compositions of variably deformed samples yield no indications for deformation- and/or fluid-enhanced element mobility and redistribution. ⁸⁷Rb-⁸⁶Sr geochronology (biotite, phengite, whole rock) places time constraints on the deformation process and the post-orogenic cooling history. Phengite- and biotite-whole-rock pairs yield Rb-Sr ages of 340 to 334 Ma and 335 to 294 Ma, respectively, independent of the degree of deformation. The weighted mean of phengite-whole-rock pairs indicates an age of 337.4DŽ.3 Ma. Combining most of the biotite-whole-rock data yields a weighted mean age of 328.6dž.4 Ma. Because of their different closure temperatures for the Rb-Sr system, these differences are interpreted to date cooling after a thermal event. Direct dating of the deformation is not possible, but the cooling history record defines a minimum age for the development of ductile shearing and the last migmatization event. These time constraints provide evidence for the initiation of crustal collapse during or immediately following peak metamorphic conditions. The results of this study further document the importance of Variscan metamorphism in the Orlica-vnie™nik dome.     

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.     

Ba同位素揭示上地幔中广泛存在再循环的沉积物

正Ba同位素由于具有在低温环境中分馏的特性,相比放射性同位素与微量元素,可以更好地示踪地球深部动力学过程中的再循环物质。研究表明沉积物与蚀变洋壳具有明显不同的Ba同位素组成(沉积物富集来自重晶石的Ba),使得Ba同位素成为研究表层与地幔储库间物质交换的有力工具。最近美国伍兹霍尔海洋研究所报道了来自全球洋中脊的21个MORB样品的Ba、Sr、Nd同位素和微量元素组成以及两个钻井中沉积物和蚀变洋壳     

Chlorinated hydrocarbons in fish-eating birds wintering in the Gdańsk Bay, 1981–82 and 1982–83

Seventy-four samples of adipose fat of 10 species of fisheating birds commonly wintering in Gdańsk Bay and one of little auk, a rare species in this area, have been analysed for residues of HCB, ΣBHC, ΣDDT and PCBs. Auks (guillemot, black guillemot and razorbill), which probably stay a whole year in the Baltic area, contained in their fat twice the level of PCBs as mergansers, and 5–6 times as much as in divers and grebes—birds which stay in the sea mainly after the breeding season. ΣDDT levels were somewhat higher but comparable in auks and grebes, and lower in mergansers and divers. ΣBHC and HCB levels were 3–4 times and 5–10 times higher, respectively, in auks than in birds from other families studied. When comparing residue levels found in adipose fat of birds taken during the wintering seasons of 1981–1982 and 1982–1983 with those taken in 1975–1976 or 1980–1981, an initially rapid, but in recent years a rather slow decline in ΣDDT level is detectable for grebes, mergansers and divers, and in the case of PCBs the residue levels fell slightly. In auks, the ΣDDT residue level fell by half, but remains rather stable in recent years, while there are only minor fluctuations in the residue level of PCBs.     

Chlorinated hydrocarbons in fish-eating birds wintering in the Gdańsk Bay,Baltic Sea, 1980–1981

Further samples of the chlorinated hydrocarbon content in adipose tissue of fish-eating birds wintering in the South Baltic show high concentrations of PCB compared with ΣDDT, HCB, alpha- and gamma-BHC. The great crested grebe presently examined had approximately four times higher PCB/ΣDDT ratios than specimens taken during 1975–1976.     

The grade of metamorphism of Polish coals and their natural and activated floatability

This paper reviews research results on the floatability of Polish hard coals as a function of their grade of metamorphism. The materials used for this were species of pure carbonic rocks. Natural floatability as well as different kinds of activated floatability were determined. It was shown that under equal conditions for all tested coals natural and activated floatabilities increased proportionally to the loss of oxygen (active functional oxygen groups) in the coal. It was observed that, in spite of the lack of functional oxygen groups, coals with the highest grade of metamorphism showed a decrease in floatability. The probable reason lies in the occurrence of π electrons and the important susceptibility for polarization. Using the optimal conditions for any given coal, all coals tested presented a high floatability.