Paleosol at the Archean—Proterozoic contact in NW India revisited: Evidence for oxidizing conditions during paleo-weathering?

A number of fine-grained sericite bearing pelitic, schistose lithologies occur along the Archean (Banded Gneiss Complex)-Proterozoic (Aravalli Supergroup) contact (APC) in the Udaipur valley in NW Indian craton. These Al-rich lithologies (subsequently metamorphosed) have been described as ‘paleosols’, developed over a 3.3 Ga old Archean gneissic basement and are overlain by Paleoproterozoic Aravalli quartzite. The paleosol was developed between 2.5 and 2.1, coincident with the globally recognized Great Oxidation Event (GOE). In previous studies these paleosol sections were interpreted to have developed under reducing environment, however, the finding of a ‘ferricrete’ zone in the upper part of Tulsi Namla section (east of Udaipur) during the present study (in addition to earlier reported lithologies) has led to an alternative suggestion of oxygen-rich conditions during paleosol development. The Tulsi Namla paleosol section shows all the features characteristic of a complete paleosol section described from other Archean cratons. The paleosol includes sericite schist with kyanite as the prevalent Al-silicate in the lower part of profile while chloritoid and Fe-oxides typify the Fe-rich upper part. Alumina has remained immobile during the weathering process while Fe and Mn show a decrease in the lower part of the section and an abrupt rise in the upper part, in the ferricrete zone. The field and geochemical data indicate that the Tulsi Namla section is an in situ weathering profile and at least the upper part shows evidence of oxidizing conditions.     

Umbral oscillations and penumbral waves in Hα

We present examples of umbral oscillations observed on Big Bear H filtergram movies and investigate the relation between umbral oscillations and running penumbral waves occurring in the same sunspot. Umbral oscillations near the center of the umbra are probably physically independent of the penumbral waves because the period of these umbral oscillations (150 s) is shorter than the penumbral wave period (270 s) but not a harmonic. We also report dark puffs which emerge from the edge of the umbra and move outward across the penumbra, and which have the same period as the running penumbral waves. We interpret these dark puffs to be the extension of chromospheric umbral oscillations at the edge of the umbra. It is suggested that the dark puffs and the running penumbral waves have a common source: photospheric oscillations just inside the umbra.     

Markets, ethnicity and environment in a vulnerable landscape: the case of small-scale vegetable production on the Jos Plateau, Nigeria, 1991–2001

This paper explores changing socio-environmental interactions in the vegetable producing areas of the Jos Plateau over the decade 1991–2001. It considers the pressures of market forces and ethnic competition and the tensions which arise as interactions between the two are played out in a fragile physical, social and institutional environment. The region has seen a remarkable expansion in irrigated vegetable production, as dry season surveys in 1991 and 2001 attest. Local farmers appear extremely positive in their perceptions of change, pointing not only to expanded production, but also to other improvements, like growing percentages of children in school and improved transport. But behind this rosy view of change there are tensions and a series of unresolved questions which may soon have to be addressed. We examine the changing nature of socio-environmental interactions over the decade and ask whether and how current levels of production can be sustained in the context of a currently largely unregulated production system and growing competition for land. Given the important role of the Plateau as a source of temperate fruit and vegetables in West Africa, these questions have significance far beyond the Plateau region itself.     

Feature

Numerous world class mineral deposits make the Kola Peninsula a 'Mecca' for mineralogists, and key economic deposits make it one of Russia's most important industrial areas. For geologists there is the challenge of explaining how this situation has come about.     

Late Holocene δC and pollen records of paleosalinity from tidal marshes in the San Francisco Bay estuary, California

Records of stable carbon isotopes (δ¹³C) are presented from cores collected from four San Francisco Bay marshes and used as a proxy for changes in estuary salinity. The δ¹³C value of organic marsh sediments are a reflection of the relative proportion of C₃ vs. C₄ plants occupying the surface, and can thus be used as a proxy for vegetation change on the marsh surface. The four marshes included in this study are located along a natural salinity gradient that exists in the San Francisco Bay, and records of vegetation change at all four sites can be used to infer changes in overall estuary paleosalinity. The δ¹³C values complement pollen data from the same marsh sites producing a paleoclimate record for the late Holocene period in the San Francisco Bay estuary. The data indicate that there have been periods of higher-than-average salinity in the Bay estuary (reduced fresh water inflow), including 1600-1300 cal yr B.P., 1000-800 cal yr B.P., 300-200 cal yr B.P., and ca. A.D. 1950 to the present. Periods of lower-than-average salinity (increased fresh water inflow) occurred before 2000 cal yr B.P., from 1300 to 1200 cal yr B.P. and ca. 150 cal yr B.P. to A.D. 1950. A comparison of the timing of these events with records from the California coast, watershed, and beyond the larger drainage of the Bay reveals that the paleosalinity variations reflected regional precipitation.     

Hybrid mafic dykes from Delwara Shear Zone,Mt. Abu,NW India

Mafic dykes intrude the composite Mt. Abu granite batholith as a minor and the last phase of magmatism. The dykes are sub-vertical, variable in width and visibly compact, however, features of alteration and shearing can be seen. The dykes occurring within the recently identified and described, Delwara Shear Zone (DWSZ), from the western margin of the Mt. Abu batholith are intensely to moderately sheared and intricately mixed with the host granitoids. The mafic dykes occurring within the shear zone bear evidence of assimilating the host granitoids during their ascent, seen as relicts, streaks and sub-rounded K-feldspar clasts in mafic dykes. The hybridization has resulted in unusual geochemical signatures of the mafic dykes such as higher silica levels, erratic and high incompatible trace element abundances and lack of any systematic trends. Mixing line calculations on the mafic dyke samples reveal between 30 to 60% felsic input into the mafic dykes. Mafic dykes outside the shear zone in the Mt. Abu are meter scale in width and generally free of felsic inclusions owing to small volumes of mafic melts. Large volume of mafic melts are required for assimilating up to 60% felsic component which has been identified as approximately 100 m wide zone within the DWSZ. Shearing has played an important role in providing the channel ways and for sustained high temperatures to allow such hybridization.     

Activity-composition relations in FeTiO3-MnTiO3 ilmenite solid solutions from EMF measurements at 1050–1300 K

The activity of FeTiO₃ in the binary ilmenitepyrophanite (FeTiO₃-MnTiO₃) solid solution has been determined for the temperature range 1050–1300 K by displacement of the reaction: 2 FeTiO₃=2 Fe+2 TiO₂+O₂ in T-O₂ space, using an electrochemical technique with calcia- and yttria-stabilized zirconia solid electrolytes. The activities show small positive deviations from ideality, which, although the data are unusually precise, may be perfectly described by the simple regular solution model, with an interaction parameter, W _Fe-Mn ^ilm , of 2.2±0.3 kJ g-atom^–1, which is independent of temperature. This value, together with the experimental data on the partitioning of Fe and Mn between ilmenite and garnet (Pownceby et al. 1987), gives W _Fe-Mn ^gt =1.2±0.5 kJ g-atom^–1 for the almandine-spessartine (Fe₃Al₂Si₃O₁₂-Mn₃Al₂Si₃O₁₂) solid solution.