First U–Pb SHRIMP age of the Hauterivian stage, Neuquén Basin, Argentina

A high-resolution ion-microprobe (SHRIMP) U–Pb zircon age from a tuff layer intercalated in the ammonoid bearing sedimentary succession of the Neuquén Basin in Argentina provides a robust geochronologic date to add to the absolute ages and to improve the relative chronology of the Early Cretaceous Hauterivian stage. The tuff layer appears interbedded between shales of the upper member (Agua de la Mula) of the Agrio Formation within the Spitidiscus riccardii ammonoid zone (base of the Late Hauterivian) yielding a date of 132.5 ± 1.3 Ma. This date confirms and supports an accurate correlation between the ammonoid biostratigraphy of the Neuquén Basin with the Western Mediterranean Province of the Tethys during the Early Cretaceous and matches with the most recently published time scale. It also casts doubts on the validity of K–Ar ages on glauconite-grains recently reported from the Lower Cretaceous of the Vocontian Basin of France.     

Variscan to eo-Alpine events recorded in European lower-crust zircons sampled from the French Massif Central and Corsica, France

Ion-microprobe U–Pb zircon dating of lower-crust metasedimentary granulite are reported on samples from two localities in Europe in order to determine (a) how this environment recorded the Variscan and eo-Alpine events, and (b) whether the transition between the two orogenic cycles was continuous or separated by a gap. The samples come from enclaves hosted by Miocene volcanoes at Bournac in the French Massif Central, and from the granulitic metasedimentary basement of the Alpine Santa Lucia nappe in Corsica, on the South European paleomargin of the Ligurian branch of the Tethys Sea. The zircon ages from Bournac range between 630 and 430 Ma and between 380 and 150 Ma with a major frequency peak at 285 Ma; the zircons older than 430 Ma are interpreted as detrital, whereas those younger than 380 Ma are considered to have formed by metamorphic processes after burial in the lower crust. Zircon ages from Santa Lucia range from to 356 to 157 Ma, with exception of one inherited Archean grain, and are interpreted like the younger Bournac zircons as having been formed by metamorphic processes.

In a granulite metamorphic environment, as opposed to an anatectic environment, new zircon growth can occur in the solid state. Once Zr has been incorporated into zircon, however, it is difficult to remobilize without dissolution; thus Zr available for new zircon growth must result from the breakdown of Zr-bearing minerals during prograde and/or retrograde events. In this light, the U–Pb zircon-age probability curves are interpreted as markers for major tectonometamorphic events, as suggested by the close correspondence between peaks in the curve and geological events recorded in the upper-crust, such as magma emplacement and basin subsidence.

Evidence of a tectonometamorphic gap between the Variscan and Alpine orogeneses is provided by the Santa Lucia zircon-age probability curve, which reveals a probable interlude during the Variscan–Alpine transition between 240 and 210 Ma. Here, the peak at 240 Ma is interpreted as the very beginning of crustal extension and the low at 210 Ma as a period of quiescence prior to the formation of an active margin and oceanization.     

On the role of flux adjustments in an idealized coupled climate model

 The effect of employing flux adjustments on the climatic response of an idealized coupled model to an imposed radiative forcing is investigated with two coupled models, one of which employs flux adjustments. A linear reduction (to the planetary longwave flux) of 4 W/m² is applied over a 70 y period and held constant thereafter. Similar model responses are found (during the initial 70 y period) for global-scale diagnostics of hemispheric air temperature due to the nearly linear surface-air temperature response to the radiative forcing. Significant regional scale differences do exist, however. As the perturbation away from the present climate grows, basin-scale diagnostics (such as meridional overturning rates) begin to diverge between flux adjusted and non-flux adjusted models. Once the imposed radiative forcing is held constant, differences in global mean air temperature of up to 0.5 °C are found, with large regional-scale differences in air temperature and overturning rates within the North Atlantic and Southern Ocean. Two additional experiments with the flux adjusted model (beginning from points further along the control integration) suggest that the elimination of much of the coupling shock before the radiative forcing is applied leads to results slightly closer to the non-flux adjusted case, although large differences still persist. In particular a dipole structure indicating an enhanced warming within the Pacific sector of the Southern Ocean, and cooling within the Atlantic sector is not reproduced by the flux adjusted models. This disparity is intimately linked to the Southern Ocean overturning cell along with the flux adjustments employed as well as the drift arising from coupling shock. If a similar form of sensitivity exists in more realistic coupled models, our results suggest: (1) perturbation experiments should not be undertaken until after the coupled model control experiment is carried out for several hundred years (thereby minimizing the coupling shock); (2) care should be exercised in the interpretation of regional-scale results (over the ocean) in coupled models which employ flux adjustments; (3) care should also be taken in interpreting even global-scale diagnostics in flux adjusted models for large perturbations about the present climate. Received: 15 November 1996 / Accepted: 4 June 1997     

Geochronology of granulites from the south Itabuna-Salvador-Curaçá Block,São Francisco Craton (Brazil): Nd isotopes and U–Pb zircon ages

This work provides five new U–Pb zircon dating and the corresponding Nd isotope data for felsic granulites from the south Itabuna-Salvador-Curaçá Block (ISCB), in the São Francisco Craton, Brazil. Three major sets of felsic granulites can be recognised. The oldest set is tonalitic in composition and of TTG affinity. It is Archaean in age with magmatic zircon cores dated at 2675 ± 11 Ma by LA-ICPMS and up to ca 2.7–2.9 Ga by SHRIMP on an other sample. It exhibits epsilon Nd values between ?8 and ?11 at 2.1 Ga. This Nd signature is similar to that of granulites found in the western Archaean Jequié Block. Cartographically, this set of Archaean terrains represents at least 50% of the granulites in the studied area. The second set corresponds to a Palaeoproterozoic calc-alkaline tonalitic suite with zircon ages from 2019 ± 19 Ma to 2191 ± 10 Ma and epsilon Nd values between ?3 and ?4 at 2.1 Ga, corresponding partially to a newly formed crust. The third set of granulites is also Palaeoproterozoic. It is shoshonitic to monzonitic in composition and synchronous with the high grade metamorphism dated by metamorphic zircons at 2086 ± 7 Ma (average of five samples). The Nd isotope signature for this alkaline set is similar to that of the Palaeoproterozoic calc-alkaline one. Nd isotopes appear to be a very efficient tool to distinguish Archaean from Palaeoproterozoic felsic protoliths in granulitic suites of the Itabuna-Salvador-Curaçá Block (ISCB). Finally, the southern part of the ISCB is composed of a mixture of Archaean and Palaeoproterozoic protoliths, in similar amounts, suggesting that it was probably an active margin between 2.1 and 2.2 Ga located on the eastern border of the Archaean Jequié Block. A major crustal thickening process occurred at ca 2.09 Ga in the ISCB and seems significantly younger towards the west, in the Jequié granulites, where an average of 2056 ± 9 Ma is determined for the high grade event.     

A Cambrian mixed carbonate–siliciclastic platform in SW Gondwana: evidence from the Western Sierras Pampeanas (Argentina) and implications for the early Paleozoic paleogeography of the proto-Andean margin

International Journal of Earth Sciences - The Western Sierras Pampeanas (WSP) of Argentina record a protracted geological history from the Mesoproterozoic assembly of the Rodinia supercontinent to...     

The lack of inorganic removal of dissolved silica during river-ocean mixing

The significance of the inorganic removal of dissolved silica from estuarine zones was investigated at three river mouths: the Orinoco, the Savannah and the Mississippi. Particular attention was given to the Mississippi river plume, where extensive inorganic silica uptake had been reported. Mixing curves and laboratory dilution experiments provided little evidence that the phenomenon was widespread. Because of an uncertain fresh water tie point, some inorganic uptake could not be completely ruled out for the Orinoco, but, in the plumes of the Savannah and Mississippi rivers, no inorganic silica removal was indicated. In contrast to published experiments on river sediments, laboratory dilution studies on suspended matter from the Mississippi river showed release of dissolved silica instead of uptake.     

Models of corundum origin from alkali basaltic terrains: a reappraisal

Corundums from basalt fields, particularly in Australia and Asia, include a dominant blue-green-yellow zoned “magmatic” suite (BGY suite) and subsidiary vari-coloured “metamorphic” suites. The BGY corundums have distinctive trace element contents (up to 0.04 wt% Ga₂O₃ and low Cr/Ga and Ti/Ga ratios <1). Different melt origins for BGY corundums are considered here from their inclusion and intergrowth mineralogy, petrologic associations and tectonic setting. Analysed primary inclusion minerals (over 100 inclusions) cover typical feldspars, zircon and Nb-Ta oxides and also include hercynite-magnetite, gahnospinel, rutile-ilmenite solid solution, calcic plagioclase, Ni-rich pyrrhotite, thorite and low-Si and Fe-rich glassy inclusions. This widens a previous inclusion survey; New England, East Australia corundums contain the most diverse inclusion suite known from basalt fields (20 phases). Zircon inclusion, intergrowth and megacryst rare earth element data show similar patterns, except for Eu which shows variable depletion. Temperature estimates from magnetite exsolution, feldspar compositions and fluid inclusion homogenization suggest that some corundums crystallized between 685–900 °C. Overlap of inclusion Nb, Ta oxide compositions with new comparative data from niobium-yttrium-fluorine enriched granitic pegmatites favour a silicate melt origin for the corundums. The feasibility of crystallizing corundum from low-volume initial melting of amphibole-bearing mantle assemblages was tested using the MELTS program on amphibole-pyroxenite xenolith chemistry from basalts. Corundum appears in the calculations at 720–880 °C and 0.7–1.1 GPa with residual feldspathic assemblages that match mineral compositions found in corundums and their related xenoliths. A model that generates melts from amphibole-bearing lithospheric mantle during magmatic plume activity is proposed for BGY corundum formation. Received: 3 January 1997 / Accepted: 8 July 1998     

Using Memoranda of Understanding to facilitate marine management in Canada

Like many other coastal states, management of Canada’s offshore areas is complicated by the division of authority among differing government departments and agencies. However, as a Confederation, this administrative complexity in Canada is further exacerbated by the jurisdictional division of powers between the Federal Parliament and the Provincial Legislatures. The most common tool for overcoming this division and facilitating cooperation are formalized non-binding agreements known as Memoranda of Understanding (MOUs). While there are a large number of MOUs in existence in Canada, few are being implemented. In part, this is because the non-binding nature of the agreement means that either party may discard their obligations at will. This has led to many useful MOUs being discarded and years of work and resources expended negotiating these agreements being wasted. This paper discusses the findings from three such agreements, each focusing on efforts to manage Canada’s offshore resources. It highlights the importance of six factors capable of increasing the likelihood that any given MOU aimed at collaboration between different authorities will be successful. These factors include: a foundation of cooperation, clear statement of priorities, feasible and adaptable work plans, integration at various management levels, a legislative foundation, and adequate financial resources.     

Paleozoic tectonism on the East Gondwana margin: Evidence from SHRIMP U–Pb zircon geochronology of a migmatite–granite complex in West Antarctica

The Fosdick Mountains migmatite–granite complex in West Antarctica records episodes of crustal melting and plutonism in Devonian–Carboniferous time that acted to transform transitional crust, dominated by immature oceanic turbidites of the accretionary margin of East Gondwana, into stable continental crust. West Antarctica, New Zealand and Australia originated as contiguous parts of this margin, according to plate reconstructions, however, detailed correlations are uncertain due to a lack of isotopic and geochronological data. Our study of the mid-crustal exposures of the Fosdick range uses U–Pb SHRIMP zircon geochronology to examine the tectonic environment and timing for Paleozoic magmatism in West Antarctica, and to assess a correlation with the better known Lachlan Orogen of eastern Australia and Western Province of New Zealand.NNE–SSW to NE–SW contraction occurred in West Antarctica in early Paleozoic time, and is expressed by km-scale folds developed both in lower crustal metasedimentary migmatite gneisses of the Fosdick Mountains and in low greenschist-grade turbidite successions of the upper crust, present in neighboring ranges. The metasedimentary rocks and structures were intruded by calc-alkaline, I-type plutons attributed to arc magmatism along the convergent East Gondwana margin. Within the Fosdick Mountains, the intrusions form a layered plutonic complex at lower structural levels and discrete plutons at upper levels. Dilational structures that host anatectic granite overprint plutonic layering and migmatitic foliation. They exhibit systematic geometries indicative of NNE–SSW stretching, parallel to a first-generation mineral lineation. New U–Pb SHRIMP zircon ages for granodiorite and porphyritic monzogranite plutons, and for leucogranites that occupy shear bands and other mesoscopic-scale structural sites, define an interval of 370 to 355 Ma for plutonism and migmatization.Paleozoic plutonism in West Antarctica postdates magmatism in the western Lachlan Orogen of Australia, but it coincides with that in the central part of the Lachlan Orogen and with the rapid main phase of emplacement of the Karamea Batholith of the Western Province, New Zealand. Emplaced within a 15 to 20 million year interval, the Paleozoic granitoids of the Fosdick Mountains are a product of subduction-related plutonism associated with high temperature metamorphism and crustal melting. The presence of anatectic granites within extensional structures is a possible indication of alternating strain states (‘tectonic switching’) in a supra-subduction zone setting characterized by thin crust and high heat flow along the Devonian–Carboniferous accretionary margin of East Gondwana.     

Tackling illegal, unregulated, and unreported trade towards Humphead wrasse (Cheilinus undulatus) recovery in Sabah, Malaysia

The live reef food fish trade (LRFFT) has caused severe depletion of the Humphead wrasse (Cheilinus undulatus) populations globally, a species considered endangered by the International Union for the Conservation of Nature. In 2010, signatories to the Convention on International Trade in Endangered Species of Wild Fauna and Flora recognized that illegal, unregulated, and unreported (IUU) activities in the LRFFT were undermining the efforts to protect this species. Management recommendations have yet to be effectively implemented at national and local levels where the fish is harvested. This paper analyzes the threats to, and socio-economic impacts of, Humphead wrasse recovery in Sabah, Malaysia, and offers both short- and longer-term recommendations for the local recovery of the species. Key issues addressed centre around understanding the threats to recovery, specifically the role of IUU and the context-specific considerations, including the socio-economic aspects of the IUU trade in Sabah. The analysis confirms that deliberate management planning and action at multiple levels are required to prevent local-scale extinction. Lessons for other species and countries involved in the LRFFT suggest that to be effective, broad management frameworks must be tailored to local situations and must focus on gaining support and participation of fish harvesters if the recovery and long-term sustainability of both the Humphead wrasse and the LRFFT are to be achieved.