Methane‐related microbial gypsum calcitization in stromatolites of a marine evaporative setting (Münder Formation,Upper Jurassic,Hils Syncline,north Germany)

Fossil stromatolites may reveal information about their hydrochemical palaeoenvironment, provided that assignment to a specific microbial community and a corresponding biogeochemical mechanism of formation can be made. Tithonian stromatolites of the Münder Formation at Thüste, north Germany, have traditionally been considered as formed by intertidal cyanobacterial communities. However, thin sections of the stromatolites show elongated angular traces of former gypsum crystals in a dense arrangement, but no algal or cyanobacterial filament traces. Moreover, high Fe²⁺ and Mn²⁺ contents, oxygen‐isotope and sulphur‐isotope ratios of carbonate‐bound sulphates, and sulphurized hydrocarbon biomarkers of the stromatolitic carbonate indicate that CaCO₃ precipitation occurred near the oxic–anoxic interface as a result of intensive bacterial sulphur cycling rather than photosynthetic activity. Furthermore, anaerobic oxidation of methane by Archaea may have driven CaCO₃ precipitation in deeper parts of the biofilm community, as reflected by high concentrations of squalane with a strongly negative δ¹³C in conjunction with evaporite pseudomorphs showing extremely low δ¹³C_Carb ratios. Consequently, the Thüste stromatolites are now interpreted as having initially formed by gypsum impregnation of biofilms. Subsequently, early Mg‐calcitic calcitization within the biofilms occurred because of combined bacterial iron, manganese and sulphate reduction, with an increasing contribution of anaerobic oxidation of methane with depth. This model plausibly explains the prominent preservation of signals derived from oxygen‐independent metabolic pathways, whereas virtually no geochemical record exists for an aerobic community that may, nevertheless, have prevailed at the stromatolite surface. Photic‐zone stromatolites with a prominent signal of anaerobic oxidation of methane may be common in, and indicative of, oxygen‐depleted sulphate‐bearing environments with high rates of methane production, conditions that possibly were fulfilled at the Archaean to Proterozoic transition.     

Cyclicity in the Main and Upper Zones of the Bushveld Complex, South Africa: Crystallization from a Zoned Magma Sheet

The major element composition of plagioclase, pyroxene, olivine,and magnetite, and whole-rock ⁸⁷Sr/⁸⁶Sr data are presented forthe uppermost 2·1 km of the layered mafic rocks (upperMain Zone and Upper Zone) at Bierkraal in the western BushveldComplex. Initial ⁸⁷Sr/⁸⁶Sr ratios are near-constant (0·7073± 0·0001) for 24 samples and imply crystallizationfrom a homogeneous magma sheet without major magma rechargeor assimilation. The 2125 m thick section investigated in drillcore comprises 26 magnetitite and six nelsonite (magnetite–ilmenite–apatite)layers and changes up-section from gabbronorite (An₇₂ plagioclase;Mg# 74 clinopyroxene) to magnetite–ilmenite–apatite–fayaliteferrodiorite (An₄₃; Mg# 5 clinopyroxene; Fo₁ olivine). The overallfractionation trend is, however, interrupted by reversals characterizedby higher An% of plagioclase, higher Mg# of pyroxene and olivine,and higher V₂O₅ of magnetite. In the upper half of the successionthere is also the intermittent presence of cumulus olivine andapatite. These reversals in normal fractionation trends definethe bases of at least nine major cycles. We have calculateda plausible composition for the magma from which this entiresuccession formed. Forward fractional crystallization modelingof this composition predicts an initial increase in total iron,near-constant SiO₂ and an increasing density of the residualmagma before magnetite crystallizes. After magnetite beginsto crystallize the residual magma shows a near-constant totaliron, an increase in SiO₂ and decrease in density. We explainthe observed cyclicity by bottom crystallization. Initiallymagma stratification developed during crystallization of thebasal gabbronorites. Once magnetite began to crystallize, periodicdensity inversion led to mixing with the overlying magma layer,producing mineralogical breaks between fractionation cycles.The magnetitite and nelsonite layers mainly occur within fractionationcycles, not at their bases. In at least two cases, crystallizationof thick magnetitite layers may have lowered the density ofthe basal layer of melt dramatically, and triggered the proposeddensity inversion, resulting in close, but not perfect, coincidenceof mineralogical breaks and packages of magnetitite layers. KEY WORDS: layered intrusion; mineral chemistry; isotopes; magma; convection; differentiation     

GLACIAL VARVE THICKNESS AND 127 YEARS OF INSTRUMENTAL CLIMATE DATA: A COMPARISON

Annually laminated sediments (glacial varves) from Lake Silvaplauna, a High Alpine proglacial lake in the Central Swiss Alps, were compared with glacier monitoring data and instrumental climate data from 1864 to 1990. Long-term and short-term responses to climatic change as well as anthropogenic influence can be traced separately in the varve succession. Economic development in the lake catchment has resulted in higher autochthonous production in recent years. Autochthonous components contribute around 10% to the total amount of sediment accumulated annually since 1960 but their contribution is negligible before this date. Decadal-scale varve thickness trends correlate with glacier size-variations. A stepwise, running multiple regression analysis demonstrates that interannual changes in varve thickness are strongly correlated with changes in mean summer temperatures, but cannot be sufficiently explained without considering summer precipitation and the number of days with snow per year. The wide range of observed correlation coefficients reveals the sensitivity of the archive to temporal variability of the climatic forcing factors and makes the development of transfer functions ambiguous.     

Early diagenesis in Pleistocene coral reefs, southern Sinai, Egypt: response to tectonics, sea-level and climate

The uplifted Pleistocene terraces along the coast of southern Sinai exhibit a well developed reef system formed during isotope stage 9, and a younger one formed during isotope stage 5. An intermediate reef corresponding to isotope stage 7 occurs only as an erosional relic in the study area. The sediments comprise reefal framestones, peri-reefal facies, coral rubble, and siliciclastic-dominated beach and aeolian facies. The compositional and textural complexity of the sediments leads to a highly variable spatial distribution of diagenetic features. However, the geometric relationships and elemental analyses allow a reconstruction of the general diagenetic evolution: during the major eustatic sea-level highstand of isotope stage 9, the Older Reef was constructed and cemented with aragonite and high-Mg calcite. Climate was probably semiarid with some rainy periods which permitted the installation of ephemeral freshwater lenses, especially during the minor sea-level lowstand within isotope stage 9. In these lenses, and during the subsequent major sea-level lowstand, some freshwater dissolution occurred. The highstand during isotope stage 7 led to the construction of the Intermediate Reef. In the Older Reef, some high-Mg calcite precipitated at that time. Dolomite cement formed either in marine interstitial waters modified by some freshwater input, or in a hypersaline context. Phreatic-meteoric low-Mg calcite cement covers, and partly replaces, previous marine cements and dolomite, but is still attributed to the major highstand of isotope stage 7 when freshwater lenses could develop during minor sea-level lowstands. The subsequent major sea-level lowstand was dominated by an arid climate, and only a little freshwater corrosion occurred. The Younger Reef formed during the major highstand of isotope stage 5. Aragonite and high-Mg calcite cements, as well as some dolomite, are common within the reef, whereas freshwater cements are limited to beach and aeolian facies. Due to tectonic uplift, only the lower part of the Older Reef was reflooded during isotope stage 5, and only some aragonite crystals precipitated on top of dolomite or low-Mg calcite. The interrelationships between tectonics, sea-level variations of different orders, and climatic changes thus had a profound impact on the diagenetic history of these reef systems.     

Microspar development during early marine burial diagenesis: a comparison of Pliocene carbonates from the Bahamas with Silurian limestones from Gotland (Sweden)

Comparison of ultrastructures in Pliocene periplatform carbonates from the Bahamas with Silurian limestones from Gotland (Sweden) reveals that despite the differences in primary sediment composition and age, they reflect a similar mechanism of lithification. In both sequences calcite microspar was formed as a primary cement at an early stage of marine burial diagenesis. Neither significant compression nor meteoric influence are necessary for the formation of calcite microspar. A model is proposed for the process of microsparitic cementation of fine-grained aragonite needle muds comprising four stages: (1) unconsolidated, aragonite-dominated carbonate mud; (2) precipitation of microspar that engulfs aragonite needles; (3) dissolution of aragonite, resulting in pitted surfaces of the microspar crystals; and (4) slight recrystallization. Our results contradict the widespread opinion that microspar necessarily is a product of secondary recrystallization of a previously lithified micrite.     

Sedimentary model and high-frequency cyclicity in a Mediterranean, shallow-shelf, temperate-carbonate environment (uppermost Miocene, Agua Amarga Basin, Southern Spain)

Uppermost Tortonian to lower Messinian temperate carbonates crop out in the Agua Amarga Basin (SE Spain). They consist of four units. The lower three units can be tentatively assigned to the lowstand systems tract of a fourth-order sequence, constituting in turn the lowstand (‘megatrough unit’), transgressive (‘breccia unit’) and highstand (‘bedded unit’) stages of a higher-order cycle. All these materials were deposited in a small pull-apart basin related to the sinistral Carboneras strike-slip fault system. The best represented is the bedded unit (up to 25 m thick), which consists of bioclastic, bryozoan/bivalve-dominated calcarenites/calcirudites with abundant fragments of echinoids, barnacles, benthic foraminifers, coralline algae, brachiopods and solitary corals. Facies trends within this unit are roughly arranged in an E-W direction, with the coastline to the north of the basin. The depositional model is that of a gentle ramp with prograding beaches and shoals in its higher parts. Seaward of the shoals was the ‘factory area’, where most organisms lived and maximum carbonate production took place. From this area some of the skeletons were washed landwards by waves and/or currents during storms and incorporated into the shoals and beaches, and others moved downslope along the ramp as mass-flows, accumulating to form the ‘fan-bedded zone’. The factory-area and fan-bedded sediments intercalate five well-defined, thick beds of calcarenites/fine-grained calcirudites. They show bar morphologies (single or amalgamated), or make up sand-waves with very consistent tabular cross-bedding pointing landwards. These beds formed in a very shallow, wave/current-influenced, coastal environment. The bars and sand waves in the fan-bedded zone developed during lowstands, while those located higher up in the ramp interbedded with the factory facies are related to transgressive stages. Prograding beaches, shoals, factory facies and fan-bedded layers developed during the highstands. Net skeletal production occurred mainly during the highstands. Sediment-accretion values of these sediments are similar to those of present and ancient shallow-marine, temperate carbonates considering that the whole bedded unit was deposited in a 100 000-year interval (equivalent to the short eccentricity cycle). The five cycles inside the bedded unit would therefore correspond to the c. 20 000-year precession cycles of the Milankovitch band.     

Intraplutonic Quench Zones in the Kap Edvard Holm Layered Gabbro Complex, East Greenland

The Kap Edvard Holm Layered Gabbro Complex is a large layeredgabbro intrusion (>300 km²) situated on the opposite sideof the Kangerdlugssuaq fjord from the Skaergaard Intrusion.It was emplaced in a continental margin ophiolite setting duringearly Tertiary rifting of the North Atlantic. Gabbroic cumulates, covering a total stratigraphic thicknessof >5 km, have a typical four-phase tholeiitic cumulus mineralogy:plagioclase, clinopyroxene, olivine, and Fe–Ti oxides.The cryptic variation is restricted (plagioclase An_81–51,olivine Fo_85–66, clinopyroxene Wo_43–41 En_46–37Fs_20–11) and there are several reversals in mineral chemistry.Crystallization took place in a low-pressure, continuously fractionatingmagma chamber system which was periodically replenished andtapped. Fine-grained (0•2–0•4 mm) equigranular, thin(0•5–3 m), laterally continuous basaltic zones occurwithin an {small tilde}1000 m thick layered sequence in theTaco Point area. Twelve such zones define the bases of individualmacrorhythmic units with an average thickness of {small tilde}80m. The fine-grained basaltic zones grade upwards, over a fewmetres, into medium-grained (>1 mm) poikilitic, olivine gabbrowith smallscale modal layering. Each fine-grained basaltic zoneis interpreted as an intraplutonic quench zone in which magmachilled against the underlying layered gabbros during influxalong the chamber floor. Supercooling by {small tilde}50C isbelieved to have caused nucleation of plagioclase, olivine,and clinopyroxene in the quench zone. The nucleation rate isbelieved to have been enhanced as the result of in situ crystallizationin a continuously flowing magma. The transition to the overlyingpoikilitic olivine gabbro reflects a decreasing degree of supercooling. Compositional variation in the Taco Point sequence is typicalfor an open magma chamber system: olivine (Fo_{77–68 5})and plagioclase cores (An_80–72) show a zig-zag crypticvariation pattern with no overall systematic trend. Olivinehas the most primitive compositions in the quench zones andmore evolved compositions in the olivine gabbro; plagioclasecores show the opposite trend. Although plagioclase cores arebelieved to retain their original compositions, olivines re-equilibratedby reaction with trapped liquid. Some plagioclase cores containrelatively sodic patches which retain quench compositions. Whole-rock compositions of nine different quench zones varyover a range from 10 to 18% MgO although the mg-number remainsconstant at {small tilde}0•78. The average composition(47•7% SiO₂, 13•3%MgO, 1•57% Na₂O+K₂O) is takenas a best estimate of the parental magma composition, and isequivalent to a high-magnesian olivine tholeiite. The compositionalvariation of the quench zones is believed to reflect burstsof nucleation and growth of olivine and plagioclase during quenching. Magma emplacement is believed to have taken place by separatetranquil influxes which flowed along the interface between alargely consolidated cumulus pile and the residual magma. Theresident magma was elevated with little or no mixing. At certainlevels in the layered sequence the magma drained back into thefeeder system; such a mechanism is referred to as a surge-typemagma chamber system.     

Late Weichselian to early Holocene sedimentation in a steep fjord/valley setting, Visdalen, Edgeøya, eastern Svalbard: glacial deposits, alluvial/colluvial-fan deltas and spit-platforms

The Visdalen valley, situated at the northwestern corner of Edgeøya, was investigated with respect to lithostratigraphy and depositional environments of the Quaternary sediments. Eight major lithostratigraphic units are recognised of which seven were deposited during the Late Weichselian to early Holocene glaciation, deglaciation and the subsequent emergence of the area, and one unit deposited prior the last glaciation. Till deposition from a west-flowing glacier was followed by glaciomarine and later marine deposition of fine-grained sediments. Coarse-grained colluvial and alluvial-fan deltas were deposited along the mountainsides in the Visdalen palaeo-bay, and distal sediment gravity-flow deposits from these deltas were interbedded with the glaciomarine-marine sediments. A spit-platform (riegel) was built up across the Visdalen bay contemporaneously with the alluvial fan-deltas. Its formation was time-transgressive, with its highest part in the south close to the marine limit at 85 m a.s.l. and its lowest part in the north at ca 65 m a.s.l. The sediment source was alluvial and colluvial debris, which was entrained by longshore currents along the more exposed coast south of Visdalen and transported northwards to the final place of deposition. The bulk part of the riegel ridge is composed of progradational successions of steep foresets dipping towards NW, N and NE, and clearly rejects an earlier ice-contact model. Datings suggest that the fan-delta deposition and the riegel formation ended before 9,000 BP. A meltwater-fed lagoon with a highest level at >50m a.s.l. was formed behind the riegel ridge in which, according to varve counting, glaciolacustrine sedimentation lasted more than 250 years and occurred within the time span 9,000-8,500 BP. Gradual uplift of the area resulted in drainage of the glaciolacustrine lagoon. Beachface processes and fluvial down-cutting took place during the emergence of the area.