The Colider and Roosevelt Volcanic rocks (sw amazonian craton): geochemistry and sm-nd isotope characteristics of a silicic large igneous province

The volcanic rocks of the Colíder and Roosevelt formations are extensively exposed in the south-central portion of the Amazonian Craton where effusive and pyroclastic rocks have been mapped. Both units, topped by chemical sediments and oceanic facies as rhyolite and andesite lavas, rhyodacite, and porphyritic dacite, with frequent intercalations of pyroclastic and epiclastic deposits. Whole-rock geochemistry for 55 samples of rhyolitic to andesitic composition suggests the involvement of fertile mantle-derived components with E-MORB to OIB compositions. The analyzed rocks display calc-alkaline to shoshonitic affinity consistent with generation related to an active continental margin. The whole-rock Sm-Nd isotope data from selected felsic volcanic rocks of the Colíder and Roosevelt formations yield negative initial ε_Nd values between –3 and –9, indicating the predominantly crustal nature of the parental magmas with early Archean to late Paleoproterozoic (ca. 2.5–2.0 Ga) depleted mantle model ages.

     

Construction of Structural Geological Model Using Monte Carlo Simulation

Geotechnical and Geological Engineering - To optimize the prediction of structural geological conditions in the underground as of data collected at the surface, due to the usual great uncertainties...     

Anatexis and fluid regime of the deep continental crust: New clues from melt and fluid inclusions in metapelitic migmatites from Ivrea Zone (NW Italy)

We investigate the inclusions hosted in peritectic garnet from metapelitic migmatites of the Kinzigite Formation (Ivrea Zone, NW Italy) to evaluate the starting composition of the anatectic melt and fluid regime during anatexis throughout the upper amphibolite facies, transition, and granulite facies zones. Inclusions have negative crystal shapes, sizes from 2 to 10 μm and are regularly distributed in the core of the garnet. Microstructural and micro‐Raman investigations indicate the presence of two types of inclusions: crystallized silicate melt inclusions (i.e., nanogranitoids, NI), and fluid inclusions (FI). Microstructural evidence suggests that FI and NI coexist in the same cluster and are primary (i.e., were trapped simultaneously during garnet growth). FI have similar compositions in the three zones and comprise variable proportions of CO₂, CH₄, and N₂, commonly with siderite, pyrophyllite, and kaolinite, suggesting a COHN composition of the trapped fluid. The mineral assemblage in the NI contains K‐feldspar, plagioclase, quartz, biotite, muscovite, chlorite, graphite and, rarely, calcite. Polymorphs such as kumdykolite, cristobalite, tridymite, and less commonly kokchetavite, were also found. Rehomogenized NI from the different zones show that all the melts are leucogranitic but have slightly different compositions. In samples from the upper amphibolite facies, melts are less mafic (FeO + MgO = 2.0–3.4 wt%), contain 860–1700 ppm CO₂ and reach the highest H₂O contents (6.5–10 wt%). In the transition zone melts have intermediate H₂O (4.8–8.5 wt%), CO₂ (457–1534 ppm) and maficity (FeO + MgO = 2.3–3.9 wt%). In contrast, melts at granulite facies reach highest CaO, FeO + MgO (3.2–4.7 wt%), and CO₂ (up to 2,400 ppm), with H₂O contents comparable (5.4–8.3 wt%) to the other two zones. Our results represent the first clear evidence for carbonic fluid‐present melting in the Ivrea Zone. Anatexis of metapelites occurred through muscovite and biotite breakdown melting in the presence of a COH fluid, in a situation of fluid–melt immiscibility. The fluid is assumed to have been internally derived, produced initially by devolatilization of hydrous silicates in the graphitic protolith, then as a result of oxidation of carbon by consumption of Fe³⁺‐bearing biotite during melting. Variations in the compositions of the melts are interpreted to result from higher T of melting. The H₂O contents of the melts throughout the three zones are higher than usually assumed for initial H₂O contents of anatectic melts. The CO₂ contents are highest at granulite facies, and show that carbon‐contents of crustal magmas are not negligible at high T. The activity of H₂O of the fluid dissolved in granitic melts decreases with increasing metamorphic grade. Carbonic fluid‐present melting of the deep continental crust represents, together with hydrate‐breakdown melting reactions, an important process in the origin of crustal anatectic granitoids.     

Contextualizing social vulnerability: findings from case studies across Europe

Social vulnerability is a term that has been widely used in the natural hazards literature for quite a few years now. Yet, regardless of how scholars define the term, the approaches and indicators they use remain contested. This article presents findings from social vulnerability assessments conducted in different case studies of flood events in Europe (Germany, Italy and the UK). The case studies relied upon a common set of comparable indicators, but they also adopted a context-sensitive, qualitative approach. A shared finding across the case studies was that it was not possible to identify a common set of socio-economic–demographic indicators to explain social vulnerability of groups and/or individuals for all phases of the disastrous events. Similarly, network-related indicators as well as location- and event-specific indicators did not have the relevance we expected them to have. The results underline that vulnerability is a product of specific spatial, socio-economic–demographic, cultural and institutional contexts imposing not only specific challenges to cross-country research concerning social vulnerability to flooding but also to attempts at assessing social vulnerability in general. The study ends with some reflections upon the methodological, practical and theoretical implications of our findings.     

Adsorption of methylene blue and crystal violet on low-cost adsorbent: waste fruits of <Emphasis Type="Italic">Rapanea ferruginea</Emphasis> (ethanol-treated and H<Subscript>2</Subscript>SO<Subscript>4</Subscript>-treated)

This study assesses the ability of two low-cost adsorbents made from waste of Rapanea ferruginea treated with ethanol (WRf) and its H₂SO₄-treated analog (WRf/H₂SO₄) for the removal of two cationic dyes methylene blue (MB) and crystal violet (CV) from aqueous solutions. The adsorbent was characterized by scanning electron microscopy, Fourier transform infrared spectrometry, thermogravimetric analysis, point of zero charge (pH_pzc), specific surface, and functional groups. The adsorption of dye onto the adsorbents was studied as a function of pH solution (2–12), contact time (up to 120 min) and initial concentration (20–120 mg/L), and temperature (25, 35, and 55 °C). The influence of these parameters on adsorption capacity was studied using the batch process. The response surface methodology (RSM) was used in the experimental design, modeling of the process, and optimizing of the variables and was optimized by the response involving Box–Behnken factorial design (15 runs). The results show that the data correlated well with the Sips isotherm. The maximum adsorption capacities of MB and CV onto WRf were found to be 69 and 106 mg/g, and onto WRf/H₂SO₄, the adsorption capacities were 33 and 125 mg/g, respectively. The kinetic data revealed that adsorption of cationic dyes onto the adsorbents closely follows the pseudo-second-order kinetic model. Regression analysis showed good fit of the experimental data to the second-order polynomial model, with coefficient of determination (R²) values for MB (R²?=?0.9685) and MB (R²?=?0.9832) for WRf and CV (R²?=?0.9685) and CV (R²?=?0.9832) for WRf/H₂SO₄ indicated that regression analysis is able to give a good prediction of response for the adsorption process in the range studied. The results revealed that waste from R. ferruginea is potentially an efficient and low-cost adsorbent for adsorption of MB and CV.     

Epidemiological analysis of malaria and its relationships with hydrological variables in four municipalities of the State of Amazonas,Brazil

Abstract

This work comprises a spatial, temporal and statistical analysis of the epidemiology of malaria occurrence in four municipalities of the State of Amazonas, Brazil: Coari, Codajás, Manacapuru and Manaus, for the period 2003–2009. The number of malaria cases, precipitation, water level and temperature data were analysed in this study. The strength of the relationship between these hydrological/meteorological variables and the occurrence of malaria was determined by employing the Spearman rank correlation coefficient. Seasonal peaks of malaria were registered, on average, about 1–2 months before the annual maximum temperature and after the river’s seasonal high-water level. The phenomenon called repiquete (notable variations in the water level) was observed during periods of between 9 and 56 days. The results showed a statistically significant correlation between malaria, temperature, precipitation and water level. Temperature influenced malaria occurrence the least, while rainfall was the most important factor, especially in the municipality of Coari. Water level had an important influence on the records of malarial occurrence in the municipality of Manacapuru.

Editor Z.W. Kundzewicz

Citation Wolfarth, B.R., Filizola, N., Tadei, W.P., and Durieux, L., 2013. Epidemiological analysis of malaria and its relationships with hydrological variables in four municipalities of the State of Amazonas, Brazil. Hydrological Sciences Journal, 58 (7), 1495–1504.     

An analysis of debris-flow events in the Sardinia Island (Thyrrenian Sea, Italy)

On 6 December 2004, the Villagrande Strisaili area (middle-east Sardinia), was struck by debris flows; 330 mm of rainfall took place within 3 h with an hourly intensity of 120 mm, which is far more above than normal for the study area. In the urban center stony and driftwood deposits accounted for a total volume estimated as 10,000 m³. The event claimed huge amount of infrastructural loss and two human lives. According to the chronicle reports, the area experienced two debris-flow events in the last century. The present paper is the outcome of an intensive study of such debris-flow events including their physical processes and geomorphological effects through both field survey and laboratory analysis.     

Water retention characteristics of swelling clays in different compaction states

The soil–water retention (SWR) characteristics of the clays play an important role in controlling their engineering behaviour, particularly, in the unsaturated state. Although, researchers have attempted to understand the water retention characteristics of the clays in their reconstituted or remoulded state, such studies are rare for the clays in their intact state. In this context, it becomes important to understand the influence of initial state of compaction, which would create different pore and fabric structure (viz., microstructure), on the water retention characteristics of the clays. With this in view, SWR behaviour was experimentally determined for the swelling clays (dried from different compaction states, viz., intact, reconstituted and remoulded) by employing Dewpoint PotentiaMeter (WP4C®). The changes in the pore size distribution of the clays at different stages of drying cycle were also studied by employing the Mercury Intrusion Porosimetry. The study reveals that the SWR curves for the intact and reconstituted specimens of the clays converge beyond a certain stage of drying. Also, a critical analysis of changes in the pore structure of the swelling clay specimens, during drying, indicates that the progressively deforming pore structure plays an important role in controlling its water retention characteristics to a great extent.     

Strength and stiffness of compacted chalk putty–cement blends

Chalk breaks easily when subjected to human action such as mechanical handling, earthworks operations or pile installation. These actions break the cemented structure of chalk, which turns into a degraded material known as putty, with lower strength and stiffness than the intact chalk. The addition of Portland cement can improve the behaviour of chalk putties. Yet, there are no studies determining the tensile strength of chalk putty–cement blends, the initial stiffness evolution during the curing time and other design parameters such as friction angle and cohesion of this material. This paper addresses this knowledge gap and provides an interpretation of new experimental results based on the dimensionless index expressed as the ratio between porosity and volumetric content of cement (η/C_iv) or its exponential modification (η/C_iv^a). This index aids the selection of the amount of cement and density for key design parameters of compacted chalk putty–cement blends required in geotechnical engineering projects such as road foundations and pavements, embankments, and also bored concrete pile foundations.