海南岛石碌矽卡岩铁矿石中石榴子石的熔融包裹体及其意义

对石碌铁矿一块具有代表性的新鲜矽卡岩铁矿石标本进行了岩石薄片显微镜观察、电子探针和喇曼光谱分析研究.在石榴子石中发现了熔融包裹体.这些包裹体主要特点是大小悬殊和成群或成带分布,最大者达98μm×5μm,最小者为1μm×1μm,多数包裹体长约5～30μm,宽约2～7μm,也有不少呈孤立状散布在石榴子石中.其形态多样,呈纺锤形、哑铃形,串珠状,藕形,近圆形和不规则状.研究的矽卡岩主要由钙铁榴石组分高的石榴子石、磁铁矿、石英、透闪石和透辉石组成,还有呈定向和星点分布的磷灰石,少量锆石与榍石;石榴子石中的熔融包裹体捕获的熔体由含Ca、Fe、Al和挥发分(H2O和CO2)的硅酸盐熔融体组成.在熔融包裹体冷却过程中,由于温度缓慢降低,赤铁矿、钙铁榴石、石英、方解石和透辉石从上述硅酸盐熔体中析出,剩下的残余熔体不混溶,变成含有Ca和Si等杂质的铁质熔体、含si、Fe的碳酸盐熔体和含Ca、Al、Fe的硅酸盐熔体.喇曼光谱测定显示,石榴子石中熔融包裹体含有石榴子石、赤铁矿和方解石,个别含少量水蒸气.磁铁矿含有可疑的Fe、Sj熔融包裹体和Sj、Fe熔融包裹体.在透辉石-透闪石矽卡岩铁矿石的石榴子石里发现大量熔融包裹体的事实无疑.矽卡岩铁矿石石榴子石中熔融包裹体的首次发现,它可能有助于石碌铁矿床挖掘老矿潜力和拓宽找矿的新思路.     

Influence of annealing conditions on impurity species in arsenic-doped HgCdTe grown by molecular beam epitaxy

Based on our previous work, the influence of annealing conditions on impurity species in in-situ arsenic (As)-doped Hg_1-xCd_xTe (x≈ 0.3) grown by molecular beam epitaxy has been systematically investigated by modulated photoluminescence spectra. The results show that (i) the doped-As acting as undesirable shallow/deep levels in as-grown can be optimized under proper annealing conditions and the physical mechanism of the disadvantage of high activation temperature, commonly assumed to be more favourable for As activation, has been discussed as compared with the reports in the As-implanted HgCdTe epilayers (x≈ 0.39), (ii) the density of V_textrmHg has an evident effect on the determination of bandgap (or composition) of epilayers and the excessive introduction of V_Hg will lead to a short-wavelength shift of epilayers, and (iii) the V_textrmHg prefers forming the V_Hg-As_Hg complex when the inactivated-As (As_Hg or related) coexists in a certain density, which makes it difficult to annihilate V_Hg in As-doped epilayers. As a result, the bandedge electronic structures of epilayers under different conditions have been drawn as a brief guideline for preparing extrinsic p-type epilayers or related devices.     

红外偏振效应和偏振遥感研究进展

光的偏振信息在当前快速发展的光电子学和光学研究中是缺失的,利用偏振特征不仅可以提取探测物和研究对象的额外信息,而且延伸了探测的维度和提高了灵敏度。本文主要从基础研究和应用研究两个方面分析讨论红外偏振效应测量技术及红外遥感的若干进展,期望从不同的角度来考察偏振效应所带来的潜在应用。在上述背景下,本文介绍了红外椭圆偏振光谱技术及其在探测无机和有机薄膜体系光学性质的应用,并且归纳了红外偏振光学仪器理论及相关进展,特别是在空间遥感上的应用潜力。