荧光分光光度法测定海洋生物中的谷胱甘肽

对应用荧光分光光度法测定海洋生物中还原型谷胱甘肽（GSH）含量的方法进行了研究，并测定了分属于鱼、虾、贝、藻的10种海洋生物中谷胱甘肽的含量。利用邻苯二甲醛与GSH反应构成的荧光体系，在激发波长为365nm，发射波长为425nm的条件下，方法的回收率为99．22％-99．69％，变异系数为2．16％。应用此方法测得10种海洋生物中谷胱甘肽的含量为：红笛鲷（Lutjanus sanguineus）0．399mg／g，银鲳（Pampus argenteus）0．352mg／g，大海鲢（Megalops cyrinoides）0．561mg/g，尖紫蛤（Sanguinolaria acuta）0．289mg/g，菲律宾蛤仔（Ruditapes philippinarun）0．287mg／g，墨吉对虾（Penaeus merguiensis）0．892mg／g，凡纳滨对虾（Litopenaeus vannamei）1．434mg／g，囊藻（Colpomenia sinuose）0．221mg／g，石莼（Ulva lactucal）0．727mg／g，马尾藻（Sargassum muticum）0．137mg／g。     

基于GF-1卫星的海上溢油定量监测——以青岛溢油事故为例

基于GF-1卫星数据对2013年11月22日青岛黄潍输油管道爆炸造成的海面溢油进行定量监测。研究首先采用2013年11月26日GF-1卫星数据对海面溢油进行提取,其统计面积为0.67 km2;其次,结合肖剑伟提出的油膜厚度单波段反演模型估算油膜厚度,最终计算得到溢油量为0.28 t;最后,对Band 1反射率与油膜厚度结果进行灰度分割,将溢油污染程度分为6级,对比发现两者分级结果较为一致。由此得出,通过反射率直接进行灰度分割可以对溢油污染进行有效的等级评定。     

深海观测平台技术

介绍了深海观测平台的重要性,以及国内外在此项技术上的发展现状,并提出了一套深海观测平台技术的设计构想以及对于未来发展方向的建议和展望。     

沉降监测多项式回归分析与神经网络预测

使用多项式和切比雪夫(Tchebyshev)多项式分别对沉降监测数据进行回归分析以预测未来沉降值,其中切比雪夫多项式的外推效果较好;应用前向BP神经网络对两种不同的单因子输入模式进行非线性函数逼近,并进行了不同采样步长的比较,实例表明将时间点作为网络的输入对沉降进行预测效果较好。     

福州市马尾地区第四纪地层划分及海相层分析

通过对该区钻孔剖面贡料,结合~(14)C、古地磁、孢粉及微体古生物等资料综合分析研究,对该区第四纪地层提出划分意见和自第四纪晚期以来,地层中存在着典型两期海侵所形成的海相层。     

Calculating Pollution Indices by Heavy Metals in Ecological Geochemistry Assessment and a Case Study in Parks of Beijing

Pollution index is a powerful tool for ecological geochemistry assessment. The commonly used pollution indices by heavy metals in soils and sediments were classified as two types of single index and integrated index in an algorithm point of view. Four single indices of contamination factor (or concentration factor), ecological risk factor, enrichment factor, and index of geo-accumulation were illustrated, and the reference values for calculating single indices were distinguished into background levels and threshold pollution values. Eight integrated indices were divided into two groups. One group is suitable for the normal distribution single indices including the sum, average, weighted average,vector modulus, and Nemerow pollution indices, and the other for log-normal distribution including the product, root of product, and weighted power product pollution indices. Using background levels as reference values, five contamination classes were divided, and the terminologies are suggested for the single and integrated indices to unify the assessment results. Software of EGAPI was developed in a single document interface to calculate the four single and eight integrated indices by heavy metals to assess the quality of soil and sediment ecological geochemistry. Pollution indices by heavy metals of Cu,Pb, and Zn in soils in parks of Beijing were calculated using EGAPI software, and these five contamination classes and terminologies suggested in this study were evaluated and used. Results ofintegrated indices of Cu, Pb, and Zn in soils indicated that the soil qualities are unpolluted as a whole and varied from low polluted to unpolluted status from the center to the outskirts of Beijing City.     

胶东半岛大磨曲家金矿床成矿流体物理化学条件演化

胶东大磨曲家金矿床流体包裹体包括水溶液包裹体、富CO2包裹体和高盐卤水包裹体3种类型,前两者发育较多,高盐卤水包裹体发育极少。流体包裹体显微测温及盐度、密度、压力估算显示,水溶液包裹体均一温度为98~376℃,据冰点温度估算,盐度为0.53%~8.28%,水溶液包裹体均一压力低于50×105Pa;富CO2包裹体完全均一温度为255~348℃,盐度为2.42%~11.43%,均一压力为1 000×105~2 500×105Pa;富CO2包裹体中CO2均一温度为23.0~32.4℃,指示该类包裹体可能含有数量不等的CH4或H2S。静水压力体制下,根据纯CO2包裹体均一压力估算成矿深度约为1 km。在270℃左右,均一压力从富CO2包裹体到水溶液包裹体急剧降低,指示成矿流体在270℃左右可能发生过一次减压沸腾过程,成矿流体盐度和密度在270℃左右也有显著的变化。因此,沸腾作用及其引起的成矿流体物理化学条件的急剧变化可能是导致大磨曲家金矿床成矿物质沉淀的重要机制。     

利用矿物方解石进行水体除磷实验研究

为探索解决水体富营养化问题的新方法,利用矿物方解石对含磷溶液进行了除磷实验。实验结果表明,方解石晶芽可以促进磷的沉淀,降低溶液磷浓度;其降磷效果与溶液初始磷浓度有关,初始磷浓度为1.2mg/L,除磷率为12.68%,初始磷浓度为3mg/L,除磷率为69.94%,初始磷浓度为5mg/L,除磷率为88.48%;同样,实验温度升高,可使方解石降磷效果明显提高。经透射电子显微镜测试,除磷沉淀物没有明显的晶质体特征。     

河南桐柏围山城层控金银成矿带同位素地球化学

河南省桐柏山区的围山城金银成矿带包括破山特大型银矿、银洞坡大型金矿、银洞岭大型银多金属矿床及一些矿点,赋矿地层是新元古界歪头山组,矿体产状与地层产状一致,形态呈似层状、鞍状或透镜状,层控特征显著。氢-氧-碳同位素地球化学研究指示早、中阶段的成矿流体主要为变质水,晚阶段有大量大气降水加入成矿流体系统。碳-硫-铅同位素指示成矿物质来自于歪头山组地层;钾-氩同位素表明成矿作用(100~140Ma)发生在秦岭陆陆碰撞造山的高峰期之后碰撞挤压向伸展转变的背景下。综合考虑矿带的成矿流体来源、成矿物质来源以及矿床地质特征,认为围山城成矿带属典型的层控造山型金银成矿系统,形成于中生代扬子与华北板块的陆陆碰撞造山体制。