The Role of Organic Matter During Metal Enrichment in Permian Kupferschiefer of the Rudna Mine,Southwest Poland

The bulk composition of organic matter and saturated and aromatic hydrocarbons extracted from 16 samples collected from two Kuperschiefer profiles in the Rudna mine,Southwest Poland has been analyzed to study the role of organic matter during base metal enrichment in the Kupferschiefer shale.The results indicated that the extract yields and saturated hydrocarbon yields decreased with increasing base metal contents.GC and GC/MS analyses indicated that n -alkanes and alkylated aromatic compounds were depleted and may have served as hydrogen donators for thermochemical sulfate reduction.The enrichment of base metal is closely connected with the destruction of hydrocarbons.     

Composition of Kerogen in Kupferschiefer from Southwest Poland

Thirty-seven Kupferschiefer samples from southwestern Poland were analyzed by microscopy, Rock-Eval approach and instrumental neutron activation analysis to understand the geochemical and morphological characteristics of kerogen present in the samples. The analytical results indicate that there are two different types of kerogens. One type was only subjected to thermal alteration processes, and the other was further oxidized after deposition of the sediment.In the oxidized samples migrabitumen was transformed into pyrobitumen. Rock-Eval analyses show a significant decrease in HI values in the oxidized samples and an increase in OI values in relation to the samples that were not influenced by oxidation. Variations in S2 versus Corg contents indicate a change in kerogen from Type II to Type III with progressing oxidation. The presence of pyrobitumen and the depletion of hydrogen in the altered kerogen allow one to conclude that the kerogen was used as hydrogen donor for thermochemical sulfate reduction(TSR).     

沈北煤田煤中琥珀的植物来源和稳定同位素的古环境意义

琥珀是由古代植物代谢产生的树脂聚合物形成的化石。琥珀中的有机质保存环境稳定、封闭,能很好地记载其形成时期的古植物和古环境等信息。本次研究运用气象色谱质谱联用仪（GC-MS）和元素分析稳定同位素质谱仪（EA-IRMS）等测试方法,研究了沈北煤田煤中琥珀的有机地球化学组成、稳定同位素和化合物单体碳同位素特征。结果表明,琥珀中的饱和烃以二萜化合物为主（占73.45%）,芳香烃以松香烷型化合物为主（56.17%）;高含量的贝壳杉烷、雪松烷、扁枝烷和松香烷型化合物指示琥珀来源于松柏类植物,且以柏科植物为主。沈北琥珀的δ13C值为-22.8‰ ~ -21.2‰,与同时期其他地区琥珀的δ13C值相似;氢同位素变化范围较小（-297.2‰ ~ -276.0‰）,氧同位素值为17.4‰ ~ 31.6‰。琥珀的稳定同位素组成（碳、氢和氧）进一步证明琥珀来源于裸子植物。琥珀的δ13C值主要与其形成时的全球气温变化和大气组成有关。沈北琥珀的氢和氧同位素组成主要受植物种类（松柏类）以及植物生长的局部气温和降水条件有关。琥珀稳定碳同位素有望成为研究古气候和古大气组成的良好载体,琥珀的氢和氧同位素可以反映形成时期的古环境条件,但仍需进一步深入研究。     

波兰西南部盆地卤水对Antracosia页岩中碳氢化合物的影响

在波兰西南部,早二叠世赤底统由一套充满盆地卤水的人山碎屑岩和沉积岩组成。赤底统和下伏石炭系地层中的盆地卤水向上流入晚二叠世镁灰岩统,与镁灰岩底部地层发生化学反应形成著名的欧洲二叠纪含铜页岩。但是,在赤底统的中部还有两层页岩,即上Antracosia页岩和下Antracosia页岩。上Antracosia页岩厚0.3～0.4m。最大有机碳含量可达2.2％。下Antracosia页岩厚20m。最大有机碳含量可达3.1％。它们是很好的烃源岩层。但是由于矿化度低,其研究程度远远低于镁灰岩底部的含铜页岩。     

鄂尔多斯盆地侏罗纪煤中古野火事件及其对古气候的影响

[研究目的]野火是陆地生态系统的一个重要组成部分,燃烧产生的温室气体会对气候环境产生影响.对地史时期古野火的研究可以获得野火对生态系统的潜在长期影响.[研究方法]采集了鄂尔多斯盆地侏罗纪延安组5个主采煤层的56个样品,并对其进行了宏观煤岩观察、煤岩显微组分定量、惰质组反射率测定、微观形貌观察.[研究结果]结果显示在煤层...     

黄县盆地褐煤与油页岩的泥炭沼泽类型分析

对黄县第三纪褐煤与油页岩共生盆地中煤₁和油₁的煤岩学特征及煤相参数特征的分析表明,黄县盆地煤₁形成于较深覆水的森林沼泽,油₁形成于湖泊沼泽,而海水侵入控制着盆地的覆水变化,进而影响了植物群落的演化与更叠。      

Relationship of polycyclic aromatic sulfur compounds and gold enrichment in the Kupferschiefer from Poland and Germany

1INTRODUCTION ORGANICALLY BOUNDSULFURCOMPOUNDSWEREPREVI OUSLYDETECTEDINTHEKUPFERSCHIEFER(P櫣TTMANNAND GO EL,1990;ROSPONDEKETAL.,1994).P櫣TTMANN ANDGO EL(1990)INVESTIGATEDTHEEXTRACTABLEORGANIC MATTERINTHEKUPFERSCHIEFERFROMTHENORTH SUDETIC SYNCLINEANDPROPOS…     

黄县盆地褐煤与油页央的泥炭沼泽类型分析

对黄县第三纪褐煤与油页岩共生盆地中煤1和油1的煤岩学特征及煤相参数特征的分析表明，黄县盆地煤1形成于较深覆水的森林沼泽，油1形成于湖泊沼泽，而海水侵入控制着盆地的覆水变化，进而影响了植物群落的演化与更叠。     

长期低温模拟实验下松柏萜类化合物的早期演化特征

为了研究萜类化合物的早期演化特征, 对松柏类有机质样品进行了长期(超过5年)的低温(80 ℃)模拟实验研究.使用色谱和色谱-质谱联用技术, 测定了样品模拟早期(1年)和模拟后期(5年半)的饱和烃组成特征, 实验结果表明萜类化合物和直链烷烃在沉积后发生了明显的早期演化.利用质谱鉴定出了地质体中较少报道的两种杜松四烯, 一种松香四烯和三种降松香四烯等中间演化产物.据此给出了相对完整的杜松类倍半萜和松香类三环二萜的早期演化途径, 发现该过程主要生成了萜类的各种芳构化衍生物, 细菌等微生物应起到了重要的生物化学促进作用.      

岩相、生物相、古地理与微细粒金矿矿源层的关系初探——以黔西南为例

本文以黔西南二叠系—三叠系为例,探讨微细粒浸染型金矿的矿源层与古地理、岩相、岩性、化石群落的关系;认为盆地边缘相、台盆相的含金量高于其他相。金往往在泥岩、粘土岩和富含软体动物的层位中富集。