西菲律宾海2万年以来浮游有孔虫壳体重量变化

为探讨2万年以来浮游有孔虫的壳体重量变化及其影响因素,对取自西菲律宾海MD06-3052岩芯的浮游有孔虫表层种Globigerinoides ruber进行壳体重量分析,基于氧同位素年龄模式,获得了2万年以来有孔虫传统壳体重量(WMS)和标准化壳体重量(WSN)变化特征。对比两种壳体重量指标,发现在本海区标准化壳体重量指标更为准确。结果表明,2万年以来,浮游有孔虫WSN具有不断变轻的趋势,整体表现为冰期时壳体重量较重,而全新世时壳体重量相对较轻的特征。末次冰盛期(Last Glacial Maximum,LGM)以来浮游有孔虫WSN变化曲线同大气CO2浓度变化曲线具有较好的相似性,推测在该海区控制壳体重量的主要因素为与全球大气CO2相关的表层海水的CO32–浓度。     

伊犁盆地伊昭井田煤层煤质特征研究

伊昭井田位于伊犁盆地中西部,煤层资源储量36亿t。赋煤层位为侏罗世水西沟群西山窑组,共含煤12层,其中可采煤层6层,3号煤层和5号煤层为井田主采煤层。对各煤层特征进行了研究,总结了各煤层特征及赋存规律及各煤层煤质特征及工业利用方向。对指导伊犁盆地的煤炭勘查、开发利用及生产布局具有积极意义。     

Sea surface temperature and salinity reconstruction based on stable isotopes and Mg/Ca of planktonic foraminifera in the western Pacific Warm Pool during the last 155 ka

Changes in sea surface temperature(SST), seawater oxygen isotope(δ 18 O sw), and local salinity proxy(δ 18 O sw-ss) in the past 155 ka were studied using a sediment core(MD06-3052) from the northern edge of the western Pacifi c Warm Pool(WPWP), within the fl ow path of the bifurcation of the North Equatorial Current. Our records reveal a lead-lag relationship between paired Mg/Ca-SST and δ 18 O during Termination II and the last interglacial period. Similarity in SST between our site and the Antarctic temperature proxy and in CO 2 profi le showed a close connection between the WPWP and the Antarctic. Values of δ 18 O sw exhibited very similar variations to those of mean ocean δ 18 O sw, owing to the past sea-level changes on glacial-interglacial timescale. Calculated values of δ 18 O sw-ss refl ect a more saline condition during high local summer insolation(SI) periods. Such correspondence between δ 18 O sw-ss and local SI in the WPWP may refl ect complex interaction between ENSO and monsoon, which was stimulated by changes in solar irradiance and their infl uence on the local hydrologic cycle. This then caused a striking reorganization of atmospheric circulation over the WPWP.     

再探温跃层有孔虫B/Ca与温度和[CO32-]的依赖性及其在24 ka以来热带西太平洋次表层碳酸盐系统重建中的应用

The B/Ca ratio of planktonic foraminifer shells has been used as a proxy for reconstructing past ocean carbonate chemistry. However, recent studies have revealed significant uncertainties associated with this proxy, such as whether seawater temperature or [ CO_3~(2-)] is the dominant control on the partition coefficient(K_D) of planktonic foraminiferal B/Ca. To address these uncertainties and thus improve our understanding of the planktonic foraminiferal B/Ca proxy, we analysed B/Ca ratios in the tests of Neogloboquadrina dutertrei(300–355 μm) and Pulleniatina obliquiloculata(355–400 μm) in surface sediment samples from the tropical western Pacific and South China Sea. The relationship between these B/Ca ratios and bottom water calcite saturation states(Δ[ CO_3~(2-)]) is weak, thus suggesting only a small dissolution effect on the B/Ca of the two species. The correlation coefficients(R~2) between the B/Ca ratios of N. dutertrei and P. obliquiloculata and environmental parameters(e.g., temperature, salinity, phosphate, DIC and ALK) in the tropical western Pacific and South China Sea are not high enough to justify using B/Ca ratios as a palaeoenvironmental proxy in the study areas. The significant correlation between K_D values of N. dutertrei and P. obliquiloculata and carbonate system parameters(e.g.,[ CO_3~(2-)], DIC, ALK, pH and [ HCO_3~-]) in the study area reflect chemical links between the K_D denominator and these variables. Based on our surface sediment calibration, an empirical relationship between the K_D of N.dutertrei and temperature is proposed in the tropical western Pacific. We also generated a record of B/Ca ratios in N. dutertrei(300–355 μm) from Core MD06-3052 in the tropical western Pacific over the past 24 ka to evaluate the application of the revised B/Ca proxy method. Based on the reconstructed empirical relationship for B/Ca and subsurface seawater ALK, we estimated subsurface seawater carbonate system parameters in the tropical western Pacific since 24 ka. In general, the estimated subsurface seawater pH and [ CO_3~(2-)] show an increase with time, and the record of subsurface seawater pCO_2 shows a decrease with time, in the tropical western Pacific over the past 24 ka. The consistent trends in subsurface seawater pCO_2 and opal flux during deglaciation may imply that the reported increase in subsurface water pCO_2 in the study area was promoted by enhanced upwelling in the Southern Ocean.     

MIS 6期以来西菲律宾海表层营养物质水平演化及其控制因素:浮游有孔虫Globigerinoides ruber的Cd/Ca证据

通过西菲律宾海MD06-3052孔浮游有孔虫Globigerinoides ruber的n(Cd)/n(Ca)[n(Cd)和n(Ca)分别指示Cd元素和Ca元素的物质的量]变化研究及其与陆源物质输入、海水结构以及海洋初级生产力等重建结果对比,从营养物质来源和利用两方面,探究了MIS6期以来该区域表层营养物质水平演化及其控制因素,从而为热带西太平洋生物泵作用和营养物质循环提供新思路和新证据。MIS6期以及MIS 2—3期研究区吕宋岛来源的陆源物质输入增多,导致了研究区MIS 6晚期、MIS 3早期和MIS2期浮游有孔虫G. ruber n(Cd)/n(Ca)的升高。而在MIS 3晚期,尽管陆源物质输入量大、次表层营养物质上涌,但初级生产力对于营养物质的利用量大于前两者营养物质输入量之和,最终形成研究区浮游有孔虫G. ruber n(Cd)/n(Ca)在MIS 3晚期呈现逐渐降低的趋势。海平面的迅速升高导致营养物质来源短期不足引起MIS 6/5冰消期浮游有孔虫G. ruber n(Cd)/n(Ca)呈现低值。而MIS 5e期研究区陆源物质输入的增多,又促使浮游有孔虫G. ruber n(Cd)/n(Ca)出现高值。此外, MIS 4—5d期,陆源物质输入较低、次表层营养物质仍受到阻碍,但研究区初级生产力在MIS4—5d期则逐渐升高,致使研究区浮游有孔虫G.rubern(Cd)/n(Ca)呈现下降趋势。研究结果反映不同时期浮游有孔虫G.rubern(Cd)/n(Ca)的受控因素不同,需要对其从营养物质来源和利用两方面因素加以考虑,才能获得更为准确的研究结果。总之,本文对西菲律宾海浮游有孔虫n(Cd)/n(Ca)指标的探究,不仅为该指标在热带西太平洋区域的古海洋学研究打下了基础,还为该指标在其他海域更为准确的探究提供了新的思路。     

西北太平洋MD06-3054孔浮游有孔虫表层海水温度估算

在古海洋学研究中,常用浮游有孔虫来恢复表层海水温度(SST),然而基于浮游有孔虫恢复SST的这些方法之间存在一定的差异.为了说明各方法的特点,在浮游有孔虫鉴定和浮游有孔虫表层种Globigerinoides ruber Mg/Ca比值测试的基础上,分别利用转换函数FP12-E,现代类比(Modern Analog Te...     

微量生物碳酸盐ICP-OES 元素分析中的仪器优化

为优化电感耦合等离子体发射光谱仪(ICP-OES)测试微量生物碳酸盐中元素含量的工作条件, 在Thermo-Fisher 公司生产的iCAP 6300 Radial 型ICP-OES 上, 对1 050 组仪器条件、32 种不同组成的标准溶液、36 个谱线对和两种仪器校正工作曲线进行了测试; 借助开源科学计算软件Scilab 数据插值和可视化技术对测试数据进行了比较分析。结果表明, 该仪器测试微量生物碳酸盐中Mg/Ca 和Sr/Ca 比值的最佳条件为: 雾化器, 0.1 mL/min 同心雾化器; 冷却气流量, 缺省设置12 L/min; 辅助气流量, 0.5L/min; 雾化气压力, 0.24 MPa; 蠕动泵速, 16 r/min; RF 功率, 1 000 W; 观察高度, 15 mm; 谱线, Ca373.690 nm, Mg 279.553 nm {121}, Sr 407.771 nm; 仪器校准工作曲线为强度-浓度工作曲线。     

高有机质输入对底栖有孔虫的抑制作用——以西北太平洋菲律宾海MD06-3054孔为例

底栖有孔虫古生产力指标-底栖有孔虫堆积速率(Benthic Foraminifera Accumulation Rate,简称BFAR)和小泡虫超科的Uvigerina与Bulimina两属在种群中的百分含量(简称"U+B含量")是目前古海洋学研究的常用方法.然而,从MD06-3054孔的记录中发现,两指标与有机质输入之间不仅不存在很好的线性关系.而且当有机质输入大于阀值时,两指标均随沉积物中总有机碳(Total Organic Carbon,简称TOC)含量的增加而明显地降低,说明过高有机质的输入还会抑制底栖有孔虫的生长和繁盛.另外,还发现当TOC含量较高时,U+B含量指标较BFAR指标相对更适用.     

微量生物碳酸盐ICP-OES元素分析中的仪器优化

为优化电感耦合等离子体发射光谱仪（ICP-OES）测试微量生物碳酸盐中元素含量的工作条件,在Thermo—Fisher公司生产的iCAP6300 Radial型ICP—OES上,对1050组仪器条件、32种不同组成的标准溶液、36个谱线对和两种仪器校正工作曲线进行了测试;借助开源科学计算软件Scilab数据插值和可视化...     

西太平洋暖池北部15万年以来的碳同位素低值事件

对取自西太平洋暖池北部的MD06-3052孔的浮游有孔虫表层种Globigerinoides ruber进行了稳定氧碳同位素测试与分析,在所建立的年龄模式基础上,揭示了该孔150 ka以来氧碳同位素的变化特征及其碳同位素低值事件的时间。结果表明,150 ka以来碳同位素总体上显示出逐渐变重的趋势,其变化不同于氧同位素,并未表现出冰期-间冰期尺度的变化特征,且全新世和末次间冰期碳同位素差异较大。在所识别出的6次碳同位素的低值事件中,除倒数第二次冰消期与岁差低值有相位差以外,其余均与岁差低值都有很好的对应。幅度较大的3次发生于冷期/暖期的过渡期,其中末次冰消期的碳同位素记录受到浊流的侵蚀作用,有部分缺失;该孔与其他海区记录的相似性进一步证实了3次冰消期的δ13C低值事件的普遍性。