The Kaidun meteorite: Clasts of alkaline‐rich fractionated materials

Abstract— Clasts of alkaline (the second find in meteorites) and subalkaline rocks were found in the Kaidun meteorite. One of them (#d4A) is a large crystal of albite with inclusions of fluorapatite, arfvedsonite, aenigmatite, and wilkinsonite. The two latter minerals were previously unknown in meteorites. Another clast (#d[3–5]D) has a melt crystallization texture of mainly feldspar (oligoclase) composition and contains relict grains of both high‐Ca and low‐Ca pyroxene and fluorapatite. The mineralogical characteristics of these clasts suggest a genetic relationship and an origin from the same parent body. The textural and mineralogical characteristics of the clasts indicate origin by extensive igneous differentiation. Such processes most likely took place in a rather large differentiated body. The material of clast #d(3–5)D is similar in some mineralogical respects to basaltic shergottites.     

Numerical modelling of stratified tidal flow over a fjord sill

Field observations of tidally driven stratified flow in the sill area of Knight Inlet (British Columbia) revealed a very complicated structure, which includes solitary waves, upstream bifurcation, hydraulic jump and mixing processes. Recent observations suggest that the flow instabilities on the plunging pycnocline at the lee side of the sill may contribute to solitary wave generation through a subharmonic interaction. The present study reports on a series of numerical experiments of stratified tidal flow in Knight Inlet performed with the help of a fine resolution fully non-linear non-hydrostatic numerical model. The model reproduces all important stages of the baroclinic tidal dynamics observed in Knight Inlet. Results demonstrate that solitary waves are generated apart from the area of hydrodynamic instability. Accelerating tidal flux forms a baroclinic hydraulic jump just above the top of the sill, whereas the bifurcations and zones of shear instabilities are formed downstream of the sill. The first baroclinic mode having the largest velocity escapes from the generation area and propagates upstream, disintegrating further into a packet of solitary waves reviling the classical “non-subharmonic” mechanism of generation. The remaining part of the disturbance (slow baroclinic modes) is arrested by tidal flow and carried away to the lee side of the obstacle, where shear instability, billows and mixing processes are developed. Some sensitivity runs were performed for different value of tidal velocity.     

Experimental studies of Ta2O5 and columbite–tantalite solubility in fluoride solutions from 300 to 550°C and 50 to 100 MPa

It is well established that the fractionation of Li–F granitic magmas at depth leads to the accumulation of flux elements such as F and Li, and metal cations such as Ta and Nb in residual melts. However, it remains to be determined whether magmatic fractionation is sufficient to concentrate Nb and Ta into economically significant quantities, and what role hydrothermal–metasomatic processes play in the formation of such ore deposits. In the literature, reliable data about the solubility of Ta and Nb in hydrothermal solutions is missing or incomplete. This study provides a quantitative experimental estimation of the possible contribution from hydrothermal processes in Ta enrichment in cupolas of albitized and greisenized Li–F granite. Experimental studies of Ta₂O₅ and columbite–tantalite (Mn,Fe)(Nb,Ta)₂O₆ solubility were carried out in fluoride solutions consisting of HF, NaF, KF, and LiF. At low fluoride concentrations (0.01 and 0.1 m), Ta₂O₅ solubility at 550°C and 100 MPa under Co–CoO oxidizing conditions is low (near 10^?5–10^?4 m) in all fluoride solutions (HF, NaF, KF, LiF). At high fluoride concentrations (1 and 2 m) the highest Ta₂O₅ concentrations (10^?1 m) were detected in HF solutions. In KF, NaF, and LiF solutions, the Ta₂O₅ solubility is also high (10^?3–10^?2 m). The dependence of columbite–tantalite (Nb₂O₅-59 wt. %, Ta₂O₅-18 wt. %) solubility as a function of solution composition, T, and P has also been investigated. Tantalum and Nb concentrations have the highest values in HF solutions at reduced conditions (up to 10^?3 to 10^?2 m Ta in 1 m HF). In 1 m NaF solutions, the concentrations of Nb and Ta are, respectively, 2.5 and 3 orders of magnitude less than those in the 1 m HF solutions. Solubility of Ta and Nb in KF solutions has intermediate values. It is established that in NaF and KF solutions the dependence of solubility on pressure is distinctly negative. The Nb and Ta contents increase with increasing concentrations of HF and KF in solution, however, they do not change with increasing NaF concentration. In NaHCO₃, Na₂CO₃, and HCl solutions columbite–tantalite solubility is low. Even in 1 m chloride solutions the content is within the limits of 10^?5 m for Nb and 10^?6 to 10^?8 m for Ta. We conclude that hydrothermal transport of Ta and Nb is possible only in concentrated fluoride solutions.     

The NLTE Formation of Iron Lines Used in Solar Polarimetry

We study in some detail one-dimensional NLTE effects in solar Fei lines. The lines selected are frequently used in solar polarimetry, and also in studies of line asymmetries and for abundance determinations. Our model atom for Fei–Feii–Feiii is realistic: it takes account of multiplet structure and it includes over 200 bound–bound and bound–free transitions in detail. We use very efficient iterative methods for the self-consistent solution of the kinetic and radiative transfer equations (Auer, Fabiani Bendicho, and Trujillo Bueno, 1994). We have applied these fast methods of solution because they are suitable for the investigation of 2D and 3D NLTE transfer effects with multilevel atoms, which constitutes the next step of our ongoing research project on the iron line formation problem.     

How Bayesian data assimilation can be used to estimate the mathematical structure of a model

In previous work, we presented a method for estimation and correction of non-linear mathematical model structures, within a Bayesian framework, by merging uncertain knowledge about process physics with uncertain and incomplete observations of dynamical input-state-output behavior. The resulting uncertainty in the model input-state-output mapping is expressed as a weighted combination of an uncertain conceptual model prior and a data-derived probability density function, with weights depending on the conditional data density. Our algorithm is based on the use of iterative data assimilation to update a conceptual model prior using observed system data, and thereby construct a posterior estimate of the model structure (the mathematical form of the equation itself, not just its parameters) that is consistent with both physically based prior knowledge and with the information in the data. An important aspect of the approach is that it facilitates a clear differentiation between the influences of different types of uncertainties (initial condition, input, and mapping structure) on the model prediction. Further, if some prior assumptions regarding the structural (mathematical) forms of the model equations exist, the procedure can help reveal errors in those forms and how they should be corrected. This paper examines the properties of the approach by investigating two case studies in considerable detail. The results show how, and to what degree, the structure of a dynamical hydrological model can be estimated without little or no prior knowledge (or under conditions of incorrect prior information) regarding the functional forms of the storage–streamflow and storage–evapotranspiration relationships. The importance and implications of careful specification of the model prior are illustrated and discussed.     

The Kaidun meteorite: Composition and origin of inclusions in the metal of an enstatite chondrite clast

Abstract— Metal nodules are one of the major textural components of Kaidun sample #01.3.06 EH3-4. In terms of structure, the nodules are of three types: (1) globular, (2) zoned with a massive core and globular mantle, and (3) nodules with no internal structure. The size and composition of the globules in the nodules and grains of metal of the matrix are almost identical: no greater than 20 μm and Ni, 5.95; Si, 3.33 wt%. The nodules contain small (usually <5 μm) inclusions of SiO₂; albitic glass; enstatite; roedderite; and a mixture of SiO₂ and Na₂S₂. This is the first reported occurrence of a simple sulfide of an alkaline metal in nature. The formation of the inclusions appears to be related to condensation of material onto the surfaces of metal grains. The nodules appear to have formed by aggregation of separate grains (globules) of metal, with conservation of condensates on the grain surfaces as inclusions. The inclusions probably condensed over a significant temperature range from 1400 to 600 K. The aggregation of metal grains and formation of the nodules probably occurred simultaneously with condensation.     

Climatology of Precipitation of Different Genesis in Northern Eurasia

A method for discriminating among different types of precipitation is presented. The method is based on surface observations of precipitation, present and past weather, and the morphological types of clouds. The climatology of showery, nonshowery, and drizzle precipitation in Northern Eurasia is studied using the data of 529 Russian weather stations for the period of 1966–2014. Showery precipitation dominates in Northern Eurasia. In general, showery precipitation has greater temporal (monthly and diurnal) and spatial variability than nonshowery precipitation. The majority of showers are registered in summer (the maximum is in July), whereas the high est total monthly nonshowery precipitation is observed in autumn (the maximum is in October). The daily intensity values of showery and nonshowery precipitation are generally close, the maximum intensity is recorded in July–August. For three-hour in tervals, the shower in tensity is by 1.1–1.5 times higher. The drawbacks of the presented methodology are discussed.     

Insights into the structure of the Wyville Thomson Ridge overflow current from a fine-scale numerical model

One of the major pathways in the northern part of the Meridional Overturning Circulation (MOC) is that of the deep water in the Nordic Seas that runs through the Faroe-Shetland Channel (FSC) and Faroe Bank Channel (FBC), as well as crossing the Wyville Thomson Ridge (WTR), on its way into the Atlantic Ocean. The WTR overflow cascades down the southern side of the ridge via the narrow Ellett Gully to the Cirolana Deep (CD) which, at 1700 m, is the deepest hole in the extreme north of the Rockall Trough. The overflow accounts for nearly 1/10th of the total Faroe-Shetland Channel Bottom Water (FSCBW) discharged through the Faroese channels and is an important intermediate water mass in the Rockall Trough. Over a period of only seven days in April 2003 bottom water temperatures cooled dramatically, from 4.46 to 3.03 °C in the CD and from 3.93 to 2.54 °C in the Ymir Trough (YT). A numerical general circulation model (MITgcm) has been applied in order to reproduce the details of this dense water overflow event. Model results were consistent with the observed cooling and total water transport. It was found that the descending gravity current forms a pair of mesoscale eddies with cyclonic and anticyclonic vorticity at the exit to the CD. Analysis of mixing processes were obtained when a passive tracer was included in the model. It was found that downstream flow is characterized by an explosive detrainment regime in the CD. The model sensitivity runs revealed that the final depth to which the overflow descends depends on the initial upstream velocity of the overflow, as well as the buoyancy difference. It is argued that models of overflows need to have realistic representations of the density structure of the overflow, and sufficiently fine vertical resolution, for the subsequent fate of the overflow to be accurately represented.