Cation distribution in pentlandites (Fe,Ni)9S8: Dependence on pressure and temperature and kinetics of the cation exchange reaction

This paper describes the distribution of Fe and Ni between the octahedral and tetrahedral sites in pentlandite (Fe,Ni)₉S₈. The dependence of the distribution on pressure and temperature and the activation energy of the cation exchange reaction were determined through annealing experiments. Synthetic crystals were annealed at 433–723 K and pressures up to 4 GPa, and natural crystals were annealed at 423, 448 and 473 K in evacuated silica capillary tubes for various durations. The cation distributions in the synthetic crystals were determined with an X-ray powder method employing the anomalous dispersion effect of CuK. and FeK radiations, while those of natural crystals were calculated from the cell dimensions. The values of U, S and V for the Fe/Ni exchange reaction are –6818 J mol^–1, 20.52 J K^–1 mol^–1, and 6.99 × 10^–6 m³ mol^–1, respectively. The dependence of the Fe/Ni distribution on pressure (Pa) and temperature (Kelvin) was determined as lnK = 2.47+8.20 × 10² T ^–1+8.41 x 10^–7 T ^–1 P, where K = (Fe/Ni)_octahedral /(Fe/Ni)_tetrahedral. The activation energy of the cation exchange reaction was 185 kJ mol^–1.     

The design and flight performance of the PoGOLite Pathfinder balloon-borne hard X-ray polarimeter

In the 50 years since the advent of X-ray astronomy there have been many scientific advances due to the development of new experimental techniques for detecting and characterising X-rays. Observations of X-ray polarisation have, however, not undergone a similar development. This is a shortcoming since a plethora of open questions related to the nature of X-ray sources could be resolved through measurements of the linear polarisation of emitted X-rays. The PoGOLite Pathfinder is a balloon-borne hard X-ray polarimeter operating in the 25-240 keV energy band from a stabilised observation platform. Polarisation is determined using coincident energy deposits in a segmented array of plastic scintillators surrounded by a BGO anticoincidence system and a polyethylene neutron shield. The PoGOLite Pathfinder was launched from the SSC Esrange Space Centre in July 2013. A near-circumpolar flight was achieved with a duration of approximately two weeks. The flight performance of the Pathfinder design is discussed for the three Crab observations conducted. The signal-to-background ratio for the observations is shown to be 0.25 ±0.03 and the Minimum Detectable Polarisation (99 % C.L.) is (28.4 ±2.2) %. A strategy for the continuation of the PoGOLite programme is outlined based on experience gained during the 2013 maiden flight.     

Perturbed physics ensemble using the MIROC5 coupled atmosphere–ocean GCM without flux corrections: experimental design and results

In this study, we constructed a perturbed physics ensemble (PPE) for the MIROC5 coupled atmosphere–ocean general circulation model (CGCM) to investigate the parametric uncertainty of climate sensitivity (CS). Previous studies of PPEs have mainly used the atmosphere-slab ocean models. A few PPE studies using a CGCM applied flux corrections, because perturbations in parameters can lead to large radiation imbalances at the top of the atmosphere and climate drifts. We developed a method to prevent climate drifts in PPE experiments using the MIROC5 CGCM without flux corrections. We simultaneously swept 10 parameters in atmosphere and surface schemes. The range of CS (estimated from our 35 ensemble members) was not wide (2.2–3.2?°C). The shortwave cloud feedback related to changes in middle-level cloud albedo dominated the variations in the total feedback. We found three performance metrics for the present climate simulations of middle-level cloud albedo, precipitation, and ENSO amplitude that systematically relate to the variations in shortwave cloud feedback in this PPE.     

GIS-based weights-of-evidence modelling of rainfall-induced landslides in small catchments for landslide susceptibility mapping

Landslide susceptibility mapping is a vital tool for disaster management and planning development activities in mountainous terrains of tropical and subtropical environments. In this paper, the weights-of-evidence modelling was applied, within a geographical information system (GIS), to derive landslide susceptibility map of two small catchments of Shikoku, Japan. The objective of this paper is to evaluate the importance of weights-of-evidence modelling in the generation of landslide susceptibility maps in relatively small catchments having an area less than 4 sq km. For the study area in Moriyuki and Monnyu catchments, northeast Shikoku Island in west Japan, a data set was generated at scale 1:5,000. Relevant thematic maps representing various factors (e.g. slope, aspect, relief, flow accumulation, soil depth, soil type, land use and distance to road) that are related to landslide activity were generated using field data and GIS techniques. Both catchments have homogeneous geology and only consist of Cretaceous granitic rock. Thus, bedrock geology was not considered in data layering during GIS analysis. Success rates were also estimated to evaluate the accuracy of landslide susceptibility maps and the weights-of-evidence modelling was found useful in landslide susceptibility mapping of small catchments.     

Summertime land–sea thermal contrast and atmospheric circulation over East Asia in a warming climate—Part I: Past changes and future projections

Land–sea surface air temperature (SAT) contrast, an index of tropospheric thermodynamic structure and dynamical circulation, has shown a significant increase in recent decades over East Asia during the boreal summer. In Part I of this two-part paper, observational data and the results of transient warming experiments conducted using coupled atmosphere–ocean general circulation models (GCMs) are analyzed to examine changes in land–sea thermal contrast and the associated atmospheric circulation over East Asia from the past to the future. The interannual variability of the land–sea SAT contrast over the Far East for 1950–2012 was found to be tightly coupled with a characteristic tripolar pattern of tropospheric circulation over East Asia, which manifests as anticyclonic anomalies over the Okhotsk Sea and around the Philippines, and a cyclonic anomaly over Japan during a positive phase, and vice versa. In response to CO₂ increase, the cold northeasterly winds off the east coast of northern Japan and the East Asian rainband were strengthened with the circulation pattern well projected on the observed interannual variability. These results are commonly found in GCMs regardless of future forcing scenarios, indicating the robustness of the East Asian climate response to global warming. The physical mechanisms responsible for the increase of the land–sea contrast are examined in Part II.     

Seasonally asymmetric transition of the Asian monsoon in response to ice age boundary conditions

Modulation of a monsoon under glacial forcing is examined using an atmosphere?Cocean coupled general circulation model (AOGCM) following the specifications established by Paleoclimate Modelling Intercomparison Project phase 2 (PMIP2) to understand the air?Csea?Cland interaction under different climate forcing. Several sensitivity experiments are performed in response to individual changes in the continental ice sheet, orbital parameters, and sea surface temperature (SST) in the Last Glacial Maximum (LGM: 21?ka) to evaluate the driving mechanisms for the anomalous seasonal evolution of the monsoon. Comparison of the model results in the LGM with the pre-industrial (PI) simulation shows that the Arabian Sea and Bay of Bengal are characterized by enhancement of pre-monsoon convection despite a drop in the SST encompassing the globe, while the rainfall is considerably suppressed in the subsequent monsoon period. In the LGM winter relative to the PI, anomalies in the meridional temperature gradient (MTG) between the Asian continents minus the tropical oceans become positive and are consistent with the intensified pre-monsoon circulation. The enhanced MTG anomalies can be explained by a decrease in the condensation heating relevant to the suppressed tropical convection as well as positive insolation anomalies in the higher latitude, showing an opposing view to a warmer future climate. It is also evident that a latitudinal gradient in the SST across the equator plays an important role in the enhancement of pre-monsoon rainfall. As for the summer, the sensitivity experiments imply that two ice sheets over the northern hemisphere cools the air temperature over the Asian continent, which is consistent with the reduction of MTG involved in the attenuated monsoon. The surplus pre-monsoon convection causes a decrease in the SST through increased heat loss from the ocean surface; in other words, negative ocean feedback is also responsible for the subsequent weakening of summer convection.     

Evolution of Dentary Diastema in Iguanodontian Dinosaurs

The dentary diastema of iguanodontians has been considered to be related to its unique jaw mechanism for herbivorous adaptation.The dentary and diastema lengths of iguanodontians were measured and compared to elucidate the evolution of iguanodontian diastema.A gap in ratios between most non-hadrosaurid iguanodontians and hadrosaurids was observed,suggesting that all non- hadrosaurid iguanodontians,expect for Ouranosaurus nigeriensis and Protohadros byrdi,lack a diastema or have a short diastema,although ...     

Prediction of strong ground motion at EURO-SEISTEST site using the empirical Green's function method

This paper presents some tests on the empirical Green's function method, performed in order to check its effectiveness to predict strong ground motion during future large earthquakes. These investigations basically consist of blind or pseudo-blind tests using part of the data set obtained at the Volvi (Greece) test-site within the framework of the EURO-SEISTEST project. In a first step, a moderate event (M_L=4.1) is simulated by using a small event (M_L=2.5), and taking into account the a priori knowledge of the relevant source parameters (magnitude and stress-drop) for both the base and target events. This check emphasizes the sensitivity of the prediction to the stress-drop values. In a second step, a pseudo-blind prediction is carried out in which the information on the target event is only the magnitude (M_L=5.3) besides the geometrical parameters such as source location, strike and dip. The other important parameters (seismic moment, fault area, stress-drop) are determined on the basis of specific empirical scaling laws derived from several small and moderate events occurring in the area. The synthetic motions are computed for two nearby sites, which are located on the southern edge and in the center of the Mygdonian graben, respectively, and correspond to much different site conditions: weathered rock and thick sediments. They are found in good agreement with the observations, which were unveiled after the simulation. In particular, the amplitude and the phase of the late, local surface waves generated on the southern edge of the graben, are very well reproduced at valley center. Finally, the last step is an attempt to predict strong ground motion for a hypothetical large earthquake of magnitude M_L=6.5. The results are shown to depend very significantly on the scaling laws.     

Late cretaceous to early paleogene paleomagnetic results from Sikhote Alin, far eastern Russia: implications for deformation of East Asia

Welded tuffs in the Bogopol and Sijanov groups were sampled at 27 sites from 12 caldera formations in the Sikhote Alin mountain range around Kavalerovo (44.3°N, 135.0°E) for chronological and paleomagnetic studies. KAr age dates show that the welded tuffs erupted between 66 Ma and 46 Ma. All sites yield reliable paleomagnetic directions, with unblocking temperatures higher than 560°C. The high-temperature component at 12 sites and the medium-temperature component at 3 sites in the Bogopol Group show reversed polarity (D = 193.7°, I = −57.6°,₉₅ = 8.1°). The high-temperature component at 11 sites in the Sijanov Group showed both reversed and normal polarities and its mean direction reveals no detectable deflection from north (D = −2.9°, I = 59.6°,₉₅ = 11.2°). The combined paleomagnetic direction of the two groups yields a paleomagnetic pole of 250.5°E, 84.1°N (A₉₅ = 8.8°), which falls near Cretaceous paleomagnetic poles from Outer Mongolia, Inner Mongolia, the North China Block and the South China Block. The Sikhote Alin area appears not to have been subjected to detectable motion with respect to East Asia since about 50 Ma. This implies that the Sikhote Alin area behaved as an integral part of East Asia during the opening of the Japan Sea at about 15 Ma. However, significant separation between the paleomagnetic poles of East Asia and Europe during the Jurassic-Paleogene implies a major relative movement between these two blocks since the Paleogene.     

Phase transitions in ilvaite,a mixed-valence iron silicate

Ilvaite, Ca(Fe²⁺, Fe³⁺) Fe²⁺Si₂O₇O(OH), a mixed-valence iron silicate shows an insulator-semimetal transition with a band gap of 0.13 eV due to thermally induced charge delocalization between Fe²⁺ and Fe³⁺ ions (A sites) in double octahedral chains. The charge delocalization induces a second order crystallographic phase transition on heating from monoclinic (P2₁/a) to orthorhombic (Pnam) symmetry at 346 K. The unit cell dimensions within the 295–420 K range and the crystal structures at 295, 320, 340, 360, 380 and 400 K have been determined by high temperature single crystal X-ray diffraction. The degree of charge delocalization determined from the sizes of the Fe(Ao) and Fe(Am) octahedra is the primary order parameter, Q which couples linearly with the spontaneous strain component, ₁₃. The order parameter coupling and the associated free energy expression is given. The calculated normal modes of the space group symmetry change are consistent with the experimentally observed atomic displacements, which are parallel and antiparallel to c. Formation of antiphase lamellar twin domains parallel to (001) in the monoclinic phase is predicted to occur as a result of the phase transition. Above T_c (= 346 K), the slow asymptotic decrease of ₁₃ attaining a zero value at 380 K indicates the presence of fluctuating precursor clusters with considerable short-range order above T_c. A peak in the specific heat (C_p) measurements coincides with the onset of longrange order at 380 K, whereas ⁵⁷Fe Mössbauer measurements indicate the onset of charge localization at a considerbly higher temperature (470 K). The coupling of the d⁶ electron of the Fe²⁺ (A) ion with a longitudinal optic phonon with the polarization vector along c ^* is the likely mechanism to drive the phase transition. The electronphonon coupling also provides a charge conduction mechanism through electron hopping, whereby the short-bonded Fe²⁺-Fe³⁺ pair containing the d⁶ electron (intermediate polaron) will break up and re-form, thereby propagating the electron one step along the c axis.