Catchment properties,function, and conceptual model representation: is there a correspondence?

This study investigates the possible correspondence between catchment structure, as represented by perceptual hydrological models developed from fieldwork investigations, and mathematical model structures, selected on the basis of reproducing observed catchment hydrographs. Three Luxembourgish headwater catchments are considered, where previous fieldwork suggested distinct flow‐generating mechanisms and hydrological dynamics. A set of lumped conceptual model structures are hypothesized and implemented using the SUPERFLEX framework. Following parameter calibration, the model performance is examined in terms of predictive accuracy, quantification of uncertainty, and the ability to reproduce the flow–duration curve signature. Our key research question is whether differences in the performance of the conceptual model structures can be interpreted based on the dominant catchment processes suggested from fieldwork investigations. For example, we propose that the permeable bedrock and the presence of multiple aquifers in the Huewelerbach catchment may explain the superior performance of model structures with storage elements connected in parallel. Conversely, model structures with serial connections perform better in the Weierbach and Wollefsbach catchments, which are characterized by impermeable bedrock and dominated by lateral flow. The presence of threshold dynamics in the Weierbach and Wollefsbach catchments may favour nonlinear models, while the smoother dynamics of the larger Huewelerbach catchment were suitably reproduced by linear models. It is also shown how hydrologically distinct processes can be effectively described by the same mathematical model components. Major research questions are reviewed, including the correspondence between hydrological processes at different levels of scale and how best to synthesize the experimentalist's and modeller's perspectives. Copyright © 2013 John Wiley & Sons, Ltd.     

Wind-Driven Dissolved Organic Matter Dynamics in a Chesapeake Bay Tidal Marsh-Estuary System

Controls on organic matter cycling across the tidal wetland-estuary interface have proved elusive, but high-resolution observations coupled with process-based modeling can be a powerful methodology to address shortcomings in either methodology alone. In this study, detailed observations and three-dimensional hydrodynamic modeling are used to examine biogeochemical exchanges in the marsh-estuary system of the Rhode River, MD, USA. Analysis of observations near the marsh in 2015 reveals a strong relationship between marsh creek salinity and dissolved organic matter fluorescence (fDOM), with wind velocity indirectly driving large amplitude variation of both salinity and fDOM at certain times of the year. Three-dimensional model results from the Finite Volume Community Ocean Model implemented for the wetland system with a new marsh grass drag module are consistent with observations, simulating sub-tidal variability of marsh creek salinity. The model results exhibit an interaction between wind-driven variation in surface elevation and flow velocity at the marsh creek, with northerly winds driving increased freshwater signal and discharge out of the modeled wetland during precipitation events. Wind setup of a water surface elevation gradient axially along the estuary drives the modeled local sub-tidal flow and thus salinity variability. On sub-tidal time scales (>36 h, <1 week), wind is important in mediating dissolved organic matter releases from the Kirkpatrick Marsh into the Rhode River.     

Pattern,style and timing of British–Irish Ice Sheet advance and retreat over the last 45 000 years: evidence from NW Scotland and the adjacent continental shelf

Predicting the future response of ice sheets to climate warming and rising global sea level is important but difficult. This is especially so when fast-flowing glaciers or ice streams, buffered by ice shelves, are grounded on beds below sea level. What happens when these ice shelves are removed? And how do the ice stream and the surrounding ice sheet respond to the abruptly altered boundary conditions? To address these questions and others we present new geological, geomorphological, geophysical and geochronological data from the ice-stream-dominated NW sector of the last British–Irish Ice Sheet (BIIS). The study area covers around 45 000 km² of NW Scotland and the surrounding continental shelf. Alongside seabed geomorphological mapping and Quaternary sediment analysis, we use a suite of over 100 new absolute ages (including cosmogenic-nuclide exposure ages, optically stimulated luminescence ages and radiocarbon dates) collected from onshore and offshore, to build a sector-wide ice-sheet reconstruction combining all available evidence with Bayesian chronosequence modelling. Using this information we present a detailed assessment of ice-sheet advance/retreat history, and the glaciological connections between different areas of the NW BIIS sector, at different times during the last glacial cycle. The results show a highly dynamic, partly marine, partly terrestrial, ice-sheet sector undergoing large size variations in response to sub-millennial-scale climatic (Dansgaard–Oeschger) cycles over the last 45 000 years. Superimposed on these trends we identify internally driven instabilities, operating at higher frequency, conditioned by local topographic factors, tidewater dynamics and glaciological feedbacks during deglaciation. Specifically, our new evidence indicates extensive marine-terminating ice-sheet glaciation of the NW BIIS sector during Greenland Stadials 12 to 9 – prior to the main ‘Late Weichselian’ ice-sheet glaciation. After a period of restricted glaciation, in Greenland Interstadials 8 to 6, we find good evidence for rapid renewed ice-sheet build-up in NW Scotland, with the Minch ice-stream terminus reaching the continental shelf edge in Greenland Stadial 5, perhaps only briefly. Deglaciation of the NW sector took place in numerous stages. Several grounding-zone wedges and moraines on the mid- and inner continental shelf attest to significant stabilizations of the ice-sheet grounding line, or ice margin, during overall retreat in Greenland Stadials 3 and 2, and to the development of ice shelves. NW Lewis was the first substantial present-day land area to deglaciate, in the first half of Greenland Stadial 3 at a time of globally reduced sea-level c. 26 kabp , followed by Cape Wrath at c. 24 kabp. The topographic confinement of the Minch straits probably promoted ice-shelf development in early Greenland Stadial 2, providing the ice stream with additional support and buffering it somewhat from external drivers. However, c. 20–19 kabp , as the grounding-line migrated into shoreward deepening water, coinciding with a marked change in marine geology and bed strength, the ice stream became unstable. We find that, once underway, grounding-line retreat proceeded in an uninterrupted fashion with the rapid loss of fronting ice shelves – first in the west, then the east troughs – before eventual glacier stabilization at fjord mouths in NW Scotland by ~17 kabp. Around the same time, ~19–17 kabp , ice-sheet lobes readvanced into the East Minch – possibly a glaciological response to the marine-instability-triggered loss of adjacent ice stream (and/or ice shelf) support in the Minch trough. An independent ice cap on Lewis also experienced margin oscillations during mid-Greenland Stadial 2, with an ice-accumulation centre in West Lewis existing into the latter part of Heinrich Stadial 1. Final ice-sheet deglaciation of NW mainland Scotland was punctuated by at least one other coherent readvance at c. 15.5 kabp , before significant ice-mass losses thereafter. At the glacial termination, c. 14.5 kabp , glaciers fed outwash sediment to now-abandoned coastal deltas in NW mainland Scotland around the time of global Meltwater Pulse 1A. Overall, this work on the BIIS NW sector reconstructs a highly dynamic ice-sheet oscillating in extent and volume for much of the last 45 000 years. Periods of expansive ice-sheet glaciation dominated by ice-streaming were interspersed with periods of much more restricted ice-cap or tidewater/fjordic glaciation. Finally, this work indicates that the role of ice streams in ice-sheet evolution is complex but mechanistically important throughout the lifetime of an ice sheet – with ice streams contributing to the regulation of ice-sheet health but also to the acceleration of ice-sheet demise via marine ice-sheet instabilities.     

The evolution of the terrestrial-terminating Irish Sea glacier during the last glaciation

Here we reconstruct the last advance to maximum limits and retreat of the Irish Sea Glacier (ISG), the only land-terminating ice lobe of the western British Irish Ice Sheet. A series of reverse bedrock slopes rendered proglacial lakes endemic, forming time-transgressive moraine- and bedrock-dammed basins that evolved with ice marginal retreat. Combining, for the first time on glacial sediments, optically stimulated luminescence (OSL) bleaching profiles for cobbles with single grain and small aliquot OSL measurements on sands, has produced a coherent chronology from these heterogeneously bleached samples. This chronology constrains what is globally an early build-up of ice during late Marine Isotope Stage 3 and Greenland Stadial (GS) 5, with ice margins reaching south Lancashire by 30 ± 1.2 ka, followed by a 120-km advance at 28.3 ± 1.4 ka reaching its 26.5 ± 1.1 ka maximum extent during GS-3. Early retreat during GS-3 reflects piracy of ice sources shared with the Irish-Sea Ice Stream (ISIS), starving the ISG. With ISG retreat, an opportunistic readvance of Welsh ice during GS-2 rode over the ISG moraines occupying the space vacated, with ice margins oscillating within a substantial glacial over-deepening. Our geomorphological chronosequence shows a glacial system forced by climate but mediated by piracy of ice sources shared with the ISIS, changing flow regimes and fronting environments.     

Recent progress on combining geomorphological and geochronological data with ice sheet modelling,demonstrated using the last British–Irish Ice Sheet

Palaeo-ice sheets are important analogues for understanding contemporary ice sheets, offering a record of ice sheet behaviour that spans millennia. There are two main approaches to reconstructing palaeo-ice sheets. Empirical reconstructions use the available glacial geological and chronological evidence to estimate ice sheet extent and dynamics but lack direct consideration of ice physics. In contrast, numerically modelled simulations implement ice physics, but often lack direct quantitative comparison with empirical evidence. Despite being long identified as a fruitful scientific endeavour, few ice sheet reconstructions attempt to reconcile the empirical and model-based approaches. To achieve this goal, model-data comparison procedures are required. Here, we compare three numerically modelled simulations of the former British–Irish Ice Sheet with the following lines of evidence: (a) position and shape of former margin positions, recorded by moraines; (b) former ice-flow direction and flow-switching, recorded by flowsets of subglacial bedforms; and (c) the timing of ice-free conditions, recorded by geochronological data. These model–data comparisons provide a useful framework for quantifying the degree of fit between numerical model simulations and empirical constraints. Such tools are vital for reconciling numerical modelling and empirical evidence, the combination of which will lead to more robust palaeo-ice sheet reconstructions with greater explicative and ultimately predictive power.     

Titanite dates crystallization: Slow Pb diffusion during super‐solidus re‐equilibration

Titanite can be found in rocks of wide compositional range, is reactive, growing or regrowing during metamorphic and hydrothermal events, and is generally amenable to U–Pb geochronology. Experimental evidence suggest that titanite has a closure temperature for Pb ranging from 550 to 650°C, and thus titanite dates are commonly interpreted as cooling ages. However, this view has been challenged in recent years by evidence from natural titanite which suggests the closure temperature may be significantly higher (up to 800°C). Here, we investigate titanite in an enclave of migmatitic gneiss included within a granite intrusion. The titanite crystals exhibit textural features characteristic of fluid‐mediated mass transfer processes on length scales of <100 µm. These textural features are associated with variation in both Pb concentrations and distinct U–Pb isotopic compositions. Zr‐in‐titanite thermometry indicates that modification of the titanite occurred at temperatures in excess of 840°C, in the presence of a high‐T silicate melt. The Pb concentration gradients preserved in these titanite crystals are used to determine the diffusivity of Pb in titanite under high‐T conditions. We estimate diffusivities ranging from 2 × 10^?22 to 5 × 10^?25 m²/s. These results are significantly lower than experimental data predict yet are consistent with other empirical data on natural titanites, suggesting that Pb diffusivity is similar to that of Sr. Thus our data challenge the wide‐held assumption that U–Pb titanite dates only reflect cooling ages.     

Experimental determination of REE partition coefficients between zircon,garnet and melt: a key to understanding high‐T crustal processes

The partitioning of rare earth elements (REE) between zircon, garnet and silicate melt was determined using synthetic compositions designed to represent partial melts formed in the lower crust during anatexis. The experiments, performed using internally heated gas pressure vessels at 7 kbar and 900–1000 °C, represent equilibrium partitioning of the middle to heavy REE between zircon and garnet during high‐grade metamorphism in the mid to lower crust. The D_REE (zircon/garnet) values show a clear partitioning signature close to unity from Gd to Lu. Because the light REE have low concentrations in both minerals, values are calculated from strain modelling of the middle to heavy REE experimental data; these results show that zircon is favoured over garnet by up to two orders of magnitude. The resulting general concave‐up shape to the partitioning pattern across the REE reflects the preferential incorporation of middle REE into garnet, with D_Gd (zircon/garnet) ranging from 0.7 to 1.1, D_Ho (zircon/garnet) from 0.4 to 0.7 and D_Lu (zircon/garnet) from 0.6 to 1.3. There is no significant temperature dependence in the zircon–garnet REE partitioning at 7 kbar and 900–1000 °C, suggesting that these values can be applied to the interpretation of zircon–garnet equilibrium and timing relationships in the ultrahigh‐T metamorphism of low‐Ca pelitic and aluminous granulites.     

Phase equilibria modelling and LASS monazite petrochronology: P–T–t constraints on the evolution of the Priest River core complex,northern Idaho

Phase equilibria modelling, laser‐ablation split‐stream (LASS)‐ICP‐MS petrochronology and garnet trace‐element geochemistry are integrated to constrain the P–T–t history of the footwall of the Priest River metamorphic core complex, northern Idaho. Metapelitic, migmatitic gneisses of the Hauser Lake Gneiss contain the peak assemblage garnet + sillimanite + biotite ± muscovite + plagioclase + K‐feldspar ± rutile ± ilmenite + quartz. Interpreted P–T paths predict maximum pressures and peak metamorphic temperatures of ~9.6–10.3 kbar and ~785–790 °C. Monazite and xenotime ²⁰⁸Pb/²³²Th dates from porphyroblast inclusions indicate that metamorphism occurred at c. 74–54 Ma. Dates from HREE‐depleted monazite formed during prograde growth constrain peak metamorphism at c. 64 Ma near the centre of the complex, while dates from HREE‐enriched monazite constrain the timing of garnet breakdown during near‐isothermal decompression at c. 60–57 Ma. Near‐isothermal decompression to ~5.0–4.4 kbar was followed by cooling and further decompression. The youngest, HREE‐enriched monazite records leucosome crystallization at mid‐crustal levels c. 54–44 Ma. The northernmost sample records regional metamorphism during the emplacement of the Selkirk igneous complex (c. 94–81 Ma), Cretaceous–Tertiary metamorphism and limited Eocene exhumation. Similarities between the Priest River complex and other complexes of the northern North American Cordillera suggest shared regional metamorphic and exhumation histories; however, in contrast to complexes to the north, the Priest River contains less partial melt and no evidence for diapiric exhumation. Improved constraints on metamorphism, deformation, anatexis and exhumation provide greater insight into the initiation and evolution of metamorphic core complexes in the northern Cordillera, and in similar tectonic settings elsewhere.     

Significance of post‐peak metamorphic reaction microstructures in the ultrahigh temperature Eastern Ghats Province,India

Ultrahigh temperature (UHT) granulites in the Eastern Ghats Province (EGP) have a complex P–T–t history. We review the P–T histories of UHT metamorphism in the EGP and use that as a framework for investigating the P–T–t history of Mg–Al‐rich granulites from Anakapalle, with the express purpose of trying to reconcile the down‐pressure‐dominated P–T path with other UHT localities in the EGP. Mafic granulite that is host to Mg–Al‐rich metasedimentary granulites at Anakapalle has a protolith age of c. 1,580 Ma. Mg–Al‐rich metasedimentary granulites within the mafic granulite at Anakapalle were metamorphosed at UHT conditions during tectonism at 960–875 Ma, meaning that the UHT metamorphism was not the result of contact metamorphism from emplacement of the host mafic rock. Reworking occurred during the Pan‐African (c. 600–500 Ma) event, and is interpreted to have produced hydrous assemblages that overprint the post‐peak high‐T retrograde assemblages. In contrast to rocks elsewhere in the EGP that developed post‐peak cordierite, the metasedimentary granulites at Anakapalle developed post‐peak, generation ‘2’ reaction products that are cordierite‐absent and nominally anhydrous. Therefore, rocks at Anakapalle offer the unique opportunity to quantify the pressure drop that occurred during so‐called M2 that affected the EGP. We argue that M2 is either a continuation of M1 and that the overall P–T path shape is a complex counter‐clockwise loop, or that M1 is an up‐temperature counter‐clockwise deviation superimposed on the M2 path. Therefore, rather than the rocks at Anakapalle having a metamorphic history that is apparently anomalous from the rest of the EGP, we interpret that other previously studied localities in the EGP record a different part of the same P–T path history as Anakapalle, but do not preserve a significant record of pressure decrease. This is due either to the inability of refractory rocks to extensively react to produce a rich mineralogical record of pressure decrease, or because the earlier high‐P part of the rocks history was erased by the M1 loop. Irrespective of the specific scenario, models for the tectonic evolution of the EGP must take the substantial pressure decrease during M2 into account, as it is probable the P–T record at Anakapalle is a reflection of tectonics affecting the entire province.