Managing land-use effects on Northland dune lakes: lessons from the past

The Northland region of New Zealand includes numerous high-value, macrophyte-dominated dune lakes. Recent water policy reforms offer limited guidance on managing for aquatic macrophytes. In addition, dune lake histories are poorly known as regular monitoring dates to 2005 AD. Here, ca. 4000 years of lake functional behaviour is reconstructed from sedimentary archives in two Northland dune lakes (Humuhumu and Rotokawau). Results demonstrated that macrophyte dominance is sensitive to catchment erosion and hydrological drawdown. Degradation of macrophyte communities occurred in the nineteenth and twentieth centuries, earlier at Lake Humuhumu than Lake Rotokawau (post-1880 AD and post-1930 AD, respectively). In both lakes, increased erosional influx reduced macrophyte productivity, before later increases to wider trophic state (post-1970 AD). Lake-level decline is linked to increased nutrient loading at Lake Rotokawau but less so, Lake Humuhumu which is more strongly groundwater-fed. In Northland dune lakes, water-level reduction and erosional influx from land use have driven macrophyte degradation.     

The arsenic source term for an in-pit uranium mine tailings facility and its long-term impact on the regional groundwater

Detailed field sampling and analyses and laboratory-based diffusion-cell experiments were used in conjunction with 3-D reactive transport modeling (MODFLOW and MT3D99) to quantify the fate and long-term (10 ka) transport of As in the Rabbit Lake In-pit Tailings Management Facility (RLITMF), northern Saskatchewan, Canada. The RLITMF (300 m × 425 m × 90 m thick) was engineered to ensure solute transport within the RLITMF is dominated by diffusion. Concentrations of As in the tailings pore fluids ranged from 0.24 to 140 mg/L (n = 43). Arsenic speciation analyses indicate 90% of this arsenic exists as As⁵⁺. This observation is supported by pH–Eh measurements of pore fluids (n = 135). Geochemical analyses yielded a strong inverse correlation between the Fe/As molar ratio in the tailings solids and the corresponding concentration of dissolved As, which is attributed to the adsorption of As to secondary 2-line ferrihydrite present in the tailings. Diffusion-cell testing yielded values for the effective diffusion coefficient, sorption coefficient, and effective porosity of As in the tailings of 4.5 × 10⁻¹⁰ m²/s, 2–4 cm³/g and 0.36, respectively. Reactive transport simulations using the field and laboratory data show adsorption of As to the tailings and diffusive transport of dissolved As in the tailings should reduce the source term concentration of As to between 40% and 70% of the initial concentrations over the 10 ka simulation period. Based on these simulations, the As concentrations in the regional groundwater, 50 m down gradient of the tailings facility, should be maintained at background concentrations of 0.001 mg/L over the 10 ka period. These findings suggest the engineered in-pit disposal of U mine tailings can provide long-term protection for the local groundwater regime from As contamination.     

Meanders in the Antarctic Polar Frontal Zone and their impact on phytoplankton

The Antarctic Polar Front is a complex set of meandering jets, which appear to support enhanced primary productivity. The US Joint Global Ocean Flux Study conducted a series of survey and process studies in part to study the processes regulating primary productivity in this high nutrient, low chlorophyll region. We deployed a set of surface velocity drifters, some of which were equipped with bio-optical sensors, to study the temporal and spatial scales of biological and physical processes in the Antarctic Polar Frontal Zone. There were two primary sets of deployments: November 1997 before the spring bloom and January 1998 after the spring bloom. The November deployment revealed a strong spring bloom that lasted about 10 days. In late spring, when incoming solar radiation began to increase, the vertical motions associated with the meanders strongly affected the accumulation of phytoplankton biomass, primarily through their impact on light availability. Weaker meandering was observed in the January deployment, and chlorophyll values remained relatively constant. As the bloom began to decay, it appears that nutrient availability became more important in regulating phytoplankton photosynthesis. Some of the drifters in the November deployment were deployed in coherent clusters, thus allowing us to calculate vertical velocities associated with the meanders. Estimates of fluorescence/chlorophyll suggest that areas of upwelling and downwelling alternately decrease and increase photosynthetic stress, perhaps as a result of changes in the availability of iron or light during the formation of the bloom.     

Stakeholder consultation during the planning phase of scientific programs

Stakeholder consultation is being adopted as standard practice in the planning and management of natural resource management programs. While the utility of stakeholder participation has been investigated for the evaluation and implementation phases of natural resource management programs, few studies have examined the utility of stakeholder consultation during the initial phases of developing such programs. This paper presents a case study from a project developing a marine and coastal monitoring program for the Pilbara and Kimberley region of northern Western Australia. Via a series of workshops held in the region, stakeholders were asked to prioritise future research needs using several voting procedures. During the analyses of the results from the different voting procedures, it became apparent that there were high levels of inconsistency, poor correlation, and contradiction, between participants’ responses. Despite the rigour of the selection process used to identify ‘suitable’ stakeholders for the workshops, these results show that stakeholders did not have the technical or broader contextual knowledge about marine ecosystems to effectively and objectively contribute to the research prioritisation and planning process. Based on the outcomes of this study, we argue that project designers need to be clear about why they are involving stakeholders in a project, particularly in light of the costs involved (financial, time, resources, costs to the stakeholder) in stakeholder consultation. Stakeholder involvement may be appropriate in later stages of developing natural resource management programs (implementation and management), however, stakeholder involvement is not appropriate in the initial phases of such programs, where scientific expertise is essential in formulating scientific concepts and frameworks.     

A method for quantitatively analysing dynamic recrystallization in deformed quartzitic rocks

Quantification of the microstructural changes brought about by dynamic recrystallization is essential for the interpretation of deformation mechanism histories and for the understanding of recrystallization as a syn-kinematic process. A method is presented for analysing the degree of dynamic recrystallization and for reconstructing the original grain-size distribution from that measured in the deformed specimen. This is based on size distribution measurements and comparative volume calculations between subsets of grains which contain rutile inclusions and subsets which do not. Application of the method to some quartzites from the Kilmory Bay Syncline, S. W. Highlands, Scotland, demonstrates that up to 25% of the apparent matrix grains are new grains produced by the dynamic recrystallization of porphyroclasts, and that the new grains alone compose more than 12% of the total rock volume. These figures are 2–3 times larger than estimates made by normal petrographic inspection. It is also shown that grain-size distributions alone convey little information about the microstructural changes and that grain-size vs volume fraction graphs are more meaningful.     

Chemical equilibration of the Earth's core and upper mantle

The oxygen fugacity (fO₂) of the Earth's upper mantle appears to lie somewhat above that of the iron-wüstite buffer, its fO₂ is assumed to have been similar to the present value at the time of core formation. In the upper mantle, the Fe-rich liquid protocore that would form under such conditions of fO₂ at elevated temperatures would lie predominantly in the system Fe-S-O. Distribution coefficients for Co, Cu, Ni, Ir, Au, Ir, W, Re, Mo, Ag and Ga between such liquids and basalt are known and minimum values are known for Ge. From these coefficients, upper mantle abundances for the above elements can be calculated by assuming cosmic abundances for the whole Earth and equilibrium between the Fe-S-O protocore and upper mantle. These calculated abundances are surprisingly close to presently known upper mantle abundances; agreements are within a factor of 5, except for Cu, W, and Mo. Therefore, siderophile element abundances in the upper mantle based on known distribution coefficients do not demand a late-stage meteoritic bombardment, and a protocore formed from the upper mantle containing S and O seems likely.As upper mantle abundances fit a local equilibrium model, then either the upper mantle has not been mixed with the rest of the mantle since core formation, or else partition coefficients between protocore and mantle were similar for the whole mantle regardless of $\text{P}$, $\text{T}$, and fO₂. The latter possibility seems unlikely over such a $\text{P-T}$ range.     

Oxide minerals in lithic fragments from Luna 20 fines

One hundred and seventy-six oxide mineral grains in the Luna 20 samples were analyzed by electron microprobe. Spinel is the most abundant oxide, occurring in troctolite fragments. Next most abundant is ilmenite, which occurs in all rock types except those containing spinel. Chromite also occurs in all rock types except those containing spinel. Minor amounts of ulvöspinel, armalcolite, zirkelite, baddeleyite and an unidentified TiO₂-rich phase were also found.Spinel grains are predominantly spinel-hercynite solid solutions, commonly with very minor chromite. The $\text{Fe}\text{(Fe + Mg)}$ ratio is generally lower than in spinel from Apollo 14 rocks. Chromites in non-mare rocks are similar to those from mare rocks. Ilmenite of mare origin is Mg-poor and Zr-rich compared to non-mare ilmenite; these elements may therefore be useful in determining the origin of ilmenite grains.Phase equilibria considerations suggest that spinel troctolite crystallized from a melt high in alumina; a likely candidate is the high-alumina basalt of Prinzet al. (1973a).Sub-micron wide rods of metallic Fe occur in plagioclase grains and may have formed by sub-solidus reduction processes.     

A lunar core of Fe-Ni-S

Several workers have proposed that lunar samples were magnetized by a field created by a lunar core of molten Fe. Low abundances of siderophile elements in lunar rocks are compatible with formation of a metallic lunar core. A molten Fe core requires that the bulk of the Moon was above, or close to, the melting point, a requirement which disagrees with most models of the lunar thermal regime.A core (or perhaps a layer or pockets) of molten Fe-Ni-S, at or close to the eutectic composition would act as a lunar dynamo, and be at a temperature (approx. 1000°C) consistent with some reasonable models of lunar thermal history. The existence of a Fe-Ni-S core would also partly explain the depletion in volatile elements in lunar basalts. Such a core, occupying up to 20 per cent of the Moon's radius requires a bulk S content for the moon of only 0.3 wt per cent.     

The lunar crust: a product of heterogeneous accretion or differentiation of a homogeneous Moon?

The outer portion of the Moon including the Al-rich crust and the source regions of mare basalts was either accreted heterogeneously or was the product of widespread differentiation of an originally homogeneous source. A number of constraints make the heterogeneous accretion model unlikely; the differentiation model appears more plausible.If the differentiation model is correct, a series of cumulate rocks complimentary to the Al-rich crustal rocks must exist. The mare basalts may have been derived from such a complimentary cumulate for several reasons. For example, Philpottset al. (1973) on the basis of REE studies, suggest that Apollo 11 and 17 mare basalts were formed by partial melting of a cumulate rich in a phase(s) containing high Ti and heavy REE. The high Ti of Apollo 11 and 17 basalts is not readily explained in terms of partial melting of an undifferentiated mantle, but is consistent with partial melting of a pyroxene cumulate enriched in Fe, Ti oxides. The characteristic Fe-rich nature of mare basalts would be partly a consequence of melting of oxide cumulate minerals. It is postulated that the plagioclase-poor source region of mare basalts was enriched in an intercumulus residual liquid. During the partial melting that produced mare basalts, this material was largely incorporated into the melt, thus explaining the ancient model ages observed in most mare basalts. If the cumulate model is correct, then samples derived from the true (undifferentiated) lunar mantle have not been identified.