Metal binding to dissolved organic matter and adsorption to ferrihydrite in shallow peat groundwaters: Application to diamond exploration in the James Bay Lowlands,Canada

The speciation and solubility of kimberlite pathfinder metals (Ni, Nd, Ba and K) in shallow peat groundwaters is investigated over the Yankee, Zulu and Golf kimberlites in the Attawapiskat region, James Bay Lowlands, Canada. The purpose of this study is to examine the relationship between dissolved organic matter (DOM) complexation with kimberlite pathfinder metals and determine the spatial distribution of those metals in shallow peat groundwaters along sampling transects over subcropping kimberlites. Nickel, Nd, Ba and K complexation with DOM and the adsorption of these metals onto ferrihydrite were calculated using Visual MINTEQ 3.0 and the NICA-Donnan database. Calculations predict almost 100% of soluble Nd, Ni and Ba form complexes with DOM at sampling sites with little to no contribution from upwelling groundwater (i.e., dissolved organic C (DOC) concentrations = 40–132 mg/L, pH = 3.9–5.5, and log ionic strength ??3). In only the most ombrotrophic peat groundwater conditions does a majority fraction of K bind to DOM. By contrast, under conditions with large contributions from upwelling groundwaters (i.e., DOC concentrations ?40 mg/L, pH = 5.5–6.5, and log ionic strength = ?3 to ?2), as little as 10% of Nd and Ni, and 0% K and Ba are predicted to complex with DOM. The modeling calculations suggest the dominant control on metal–DOM complexation, particularly with respect to Ni and Nd, is competitive effects for DOM binding sites due to elevated ionic strength where there is evidence of strong groundwater upwelling. Visual MINTEQ modeling of metal adsorption on ferrihydrite surfaces predicts that under strong upwelling conditions, Ni and Nd are scavenged from solution due to increased ferrihydrite precipitation and decreased fractions of metals complexed with DOM. Analytical geochemical data are consistent with model predictions of metal adsorption on ferrihydrite. Total dissolved Ni and Nd concentrations at sites of strong upwelling are up to five times lower than waters with little to no upwelling and log ferrihydrite saturation indices (logSI_ferr) indicate precipitation (values up to 5) at sites of strong groundwater upwelling. Where the majority of Ni and Nd complex with DOM and ferrihydrite is highly under saturated (logSI_ferr = ?18 to ?5), the concentrations of total Ni and Nd are elevated compared to other sites along sampling transects. Metal complexation with DOM effectively inhibits metal scavenging from solution via adsorption and/or from forming secondary mineral precipitates. Also, because alkaline earth metals do not compete strongly with Ni and Nd for adsorption sites on ferrihydrite surfaces, but do compete strongly for insoluble organic sites, Ni and Nd are more likely to adsorb onto ferrihydrite.     

Optimal site selection for an optical-astronomical observatory in Pakistan using Multicriteria Decision Analysis

An astronomical observatory is the core component of any astronomical research facility that connects astronomers with their lab: the Cosmos. The research quality of an astronomical facility is rooted in the precision of data, collected by its observatory. For optimal performance, an observatory is sited while considering certain astronomical, environmental, geological and social parameters. This study aims to identify the potential sites in Pakistan for locating an optical-astronomical observatory using the Multicriteria Decision Analysis(MCDA) technique. The study uses the Analytic Hierarchy Process(AHP) for deriving the influence weights of nine evaluation criteria: Photometric Night Fraction; Night-time Sky Brightness;Sky Transparency; Aerosol Concentration; Altitude; Terrain Slope; Accessibility; Seismic Vulnerability;and Landuse/Land Cover. On the basis of experts' opinions and previous studies, the evaluation criteria have been ordered in two possible preference sequences for identifying their influence weights with respect to each other for taking part in MCDA. Consequently, the process of MCDA identified certain areas with respect to each preference sequence, whereas some areas were found to be suitable according to both preference sequences. The study synchronizes the required eclectic data into an evaluation matrix that augments the process of astronomical site selection. In the future, this study will be useful for astronomical societies and for furthering astronomical research in the country.     

Sequence stratigraphic analysis of Eocene Rock Strata,Offshore Indus,southwest Pakistan

In this study, seismic data from two wells (Pak G2-1 and Indus Marine-1C) and age diagnostic larger benthic foraminifera (LBF) within drill cuttings has been used for the first time to identify depositional sequences within the carbonates in the Offshore Indus Basin, Pakistan. The Offshore Indus is tectonically categorized as a passive continental margin where carbonates occur as shelf carbonates in the near offshore and on volcanic seamounts in deeper waters. Seismic data analysis has indicated the presence of minor faults and carbonate buildups above the igneous basement in the south. Patterns of the seismic reflections enabled definition of three seismic facies units identified as: Unit 1 basement, represented by chaotic, moderate amplitude reflection configuration; while parallel bedding and the drape of overlying strata is typical character of Unit 2, carbonate mound facies. The younger Miocene channels represent Unit 3. The diagnosis of Alveolina vredenburgi/cucumiformis biozone confirmed the Ilerdian (55–52 Ma) stage constituting a second order cycle of deposition for the Eocene carbonates (identified as Unit 2). The carbonate succession has been mainly attributed to an early highstand system tract (HST). The environmental conditions remained favorable leading to the development of keep-up carbonates similar to pinnacle buildups as a result of aggradation during late transgressive system tract and an early HST. The carbonate sequence in the south (Pak G2-1) is thicker and fossiliferous representing inner to middle shelf depths based on fauna compared to the Indus Marine-1C in the north, which is devoid of fossils. Three biozones (SBZ 5, SBZ 6 and SBZ 8) were identified based on the occurrence of LBF. The base of the SBZ 5 zone marks the larger foraminifera turnover and the Paleocene–Eocene (P–E) boundary. The LBF encountered in this study coincides with earlier findings for the P–E boundary. Our findings indicate that the entire Ilerdian stage ranges from 55.5 to 52 Ma that was the episode of warmer water conditions on the carbonate shelves leading to the diversification of K-strategist larger foraminifera. The larger foraminiferal assemblage encountered in this study confirms the findings. The possible indication of stratigraphic-combination traps, revealed as reflection terminations, make carbonate mounds in the south a potential exploration target.     

Characteristics of snow cover in the Hindukush,Karakoram and Himalaya region using Landsat satellite data

Estimation of snow cover characteristics (snow grain size, snow contamination, snow depth and liquid water content) from satellite data are important components for many hydrological models used for the water resource management. This research aimed to use Landsat ETM+ (Enhanced Thematic Mapper Plus) data to estimate the snow pack characteristics in northern Pakistan. The Normalized Difference Snow Index (NDSI), Snow Contamination Index (SCI) and Snow Grain Size Index (SGI) are applied to estimate the snow cover characteristics in northern Pakistan for the first time. Qualitative maps are generated to show the snow cover distribution, snow contamination concentration and snow grain size distribution over snow cover area. Our results show that NDSI, SCI and SGI can be effectively used to identify snow area, contaminated snow and ageing snow. Furthermore, the results of the current study indicate that in the HKH region 99.8% of the snow is least contaminated whereas 94.50% of the area has fine snow grain size. As no such attempt in the past has been made in northern Pakistan, it is envisaged that the results of this study will be helpful in planning remote sensing data for the water resource management and in characterizing the snow cover for the climate change applications in the region. Copyright © 2011 John Wiley & Sons, Ltd.     

Helium emanometry under Australian conditions — Preliminary results

Helium has been proposed as a pathfinder in exploration for uranium deposits, hydrocarbons and geothermal energy sources, as an indicator of faults and fissures and as a possible tool for earthquake prediction. The rationale is that during the decay of ²³⁸U to ²⁰⁶ Pb, eight ⁴He atoms are produced via the intermediary of alpha particle emission. Similarly, six ⁴He atoms are produced by the decay of ²³²Th to ²⁰⁸Pb. Some of the common isotopes of the rare earths Ce, Nd and Sm are also alpha emitters, but they are unlikely to give rise to detectable helium anomalies.     

Campanian-Maastrichtian phosphorites of Iraq

Mineralium Deposita - Bedded marine sedimentary phosphate rocks of Campanian-Maastrichtian age are exposed in the Western Desert of Iraq, forming part of the Tethyan phosphate province. The studied...     

Geochemistry of a pseudo-gossan developed on a black shale dolerite contact Killara, Western Australia

Ironstones from Killara, 56 km northeast of Meekatharra, Western Australia, contain up to 1800 ppm Cu or up to 600 ppm Zn. A Cu anomaly is shown by the plus 8 and 8 to 36-mesh fractions of the soils but no indication is given by the finer fractions. No Zn anomaly is shown by any soil size fraction. Closely spaced percussion drilling along the Cu anomaly showed that the ironstones overlie carbonaceous shales intruded by metadolerites; the maximum Cu content of these rocks is 190 ppm. The shales and, in particular, the dolerites have traces of sulphides, mostly primary and secondary pyrite and, in places, chalcopyrite. The highest Cu contents in the weathered zone occur mostly at contacts between the shales and dolerites, where copper is concentrated in iron oxides and, to a lesser extent, manganese oxides. On artificial weathering, the shales and dolerites give pH readings of 4.3 and 7.0, respectively; the optimum redox conditions for the coprecipitation of copper with goethite and the precipitation of manganese oxides appear to occur close to the contacts, at the interface between the two environmentsThe absence of the common pathfinder elements and the lack of a hydromorphic dispersion halo around the ironstones are indicative of pseudo-gossans but are not diagnostic criteria. However, these features may assist in determining priorities in the selection of drilling targets.     

Helium in soil and overburden gas as an exploration pathfinder — an assessment

Orientation surveys were conducted over five deposits to test the potential of determining helium in overburden gas as a pathfinder for uranium mineralization and other deposits containing uranium or thorium. Samples were collected via fixed tubes emplaced at depths of 6 m in backfilled holes drilled for this purpose. Compared to the atmospheric background value of 5.24 ppm v/v He, a variable weak anomaly (maximum 5.45–5.65 ppm He) was found over part of the Angela uranium deposit, N.T., in an arid area where mineralization is mostly at a depth of 60–90 m, at or below the water-table. Helium contents were mostly at background levels over a uranium deposit in the Officer Basin, W.A., where mineralization is at the water-table at 30–35 m, although radon gave a marked anomaly. Neither helium nor radon indicated the Manyingee deposit, W.A., which has uranium mineralization in a confined aquifer at 60–110 m. Similarly, no helium anomalies were found over the uranium- and thorium-rich Mt. Weld carbonatite or mineral sands at Eneabba.There appeared to be no correlation between helium distributions shown by groundwater and overburden-gas sampling at Manyingee or Mt. Weld. At Mt. Weld, groundwaters contained 0.06 to 13.60 μ/l He and overburden gases 5.24–5.47 ppm He, with the higher gas concentrations over country rock, where waters had background helium contents. It is presumed that equilibration between overburden gas and the atmosphere is far more rapid than that between overburden gas and groundwater, so that any helium released from the water is quickly dispersed.Overburden-gas helium concentrations were found to vary according to overburden type, being 5.24–5.32 ppm where sandy and porous and 5.30–5.50 ppm where clay-rich and less permeable. These background variations, which are greater than the total background-anomaly contrasts reported in the literature for shallow soil gases, have not been accounted for in most trial surveys, nor has the possibility of similar variations being due to analytical error. From the data obtained, there is little evidence that helium can be considered an effective pathfinder for blind or concealed deposits using soil gas or overburden gas as sample media. Previous work on the use of soil and soil-gas helium determinations in uranium exploration is reviewed in the light of these findings and the concept and techniques assessed.