Wintertime rates of net primary production and nitrate and ammonium uptake in the southern Benguela upwelling system

The elevated levels of primary productivity associated with eastern boundary currents are driven by nutrient- rich waters upwelled from depth, such that these regions are typically characterised by high rates of nitrate-fuelled phytoplankton growth. Production studies from the southern Benguela upwelling system (SBUS) tend to be biased towards the summer upwelling season, yet winter data are required to compute annual budgets and understand seasonal variability. Net primary production (NPP) and nitrate and ammonium uptake were measured concurrently at six stations in the SBUS in early winter. While euphotic zone NPP was highest at the stations nearest to the coast and declined with distance from the shore, a greater proportion was potentially exportable from open-ocean surface waters, as indicated by the higher specific nitrate uptake rates and f-ratios (ratio of nitrate uptake to total nitrogen consumption) at the stations located off the continental shelf. Near the coast, phytoplankton growth was predominantly supported by ammonium despite the high ambient nitrate concentrations. Along with ammonium concentrations as high as 3.6 µmol l^–1, this strongly suggests that nitrate uptake in the inshore SBUS, and by extension carbon drawdown, is inhibited by ammonium, at least in winter, although this has also been hypothesised for the summer.     

Quantifying flows along hydrological pathways by applying a new filtering algorithm in conjunction with master recession curve analysis

Quantifying the proportion of the river hydrograph derived from the different hydrological pathways is essential for understanding the behaviour of a catchment. This paper describes a new approach using the output from master recession curve analysis to inform a new algorithm based on the Lyne and Hollick ‘one‐parameter’ signal analysis filtering algorithm. This approach was applied to six catchments (including two subcatchments of these) in Ireland. The conceptual model for each catchment consists of four main flow pathways: overland flow, interflow, shallow groundwater and deep groundwater. The results were compared with those of the master recession curve analysis, a recharge coefficient approach developed in Ireland and the semi‐distributed, lumped and deterministic hydrological model Nedbør‐Afstrømings‐Model. The new algorithm removes the ‘free variable’ aspect that is typically associated with filtering algorithms and provides a means of estimating the contribution of each pathway that is consistent with the results of hydrograph separation in catchments that are dominated by quick response pathways. These types of catchments are underlain by poorly productive aquifers that are not capable of providing large baseflows in the river. Such aquifers underlie over 73% of Ireland, ensuring that this new algorithm is applicable in the majority of catchments in Ireland and potentially in those catchments internationally that are strongly influenced by the quick‐responding hydrological pathways. Copyright © 2013 John Wiley & Sons, Ltd.     

Joint modelling of wave spectral parameters for extreme sea states

Characterising the dependence between extremes of wave spectral parameters such as significant wave height (H_S) and spectral peak period (T_P) is important in understanding extreme ocean environments and in the design and assessment of marine structures. For example, it is known that mean values of wave periods tend to increase with increasing storm intensity. Here we seek to characterise joint dependence in a straightforward manner, accessible to the ocean engineering community, using a statistically sound approach.Many methods of multivariate extreme value analyses are based on models which assume implicitly that in some joint tail region each parameter is either independent of or asymptotically dependent on other parameters; yet in reality the dependence structure in general is neither of these. The underpinning assumption of multivariate regular variation restricts these methods to estimation of joint regions in which all parameters are extreme; but regions where only a subset of parameters are extreme can be equally important for design. The conditional approach of Heffernan and Tawn (2004), similar in spirit to that of Haver (1985) but with better theoretical foundation, overcomes these difficulties.We use the conditional approach to characterise the dependence structure of H_S and T_P. The key elements of the procedure are: (1) marginal modelling for all parameters, (2) transformation of data to a common standard Gumbel marginal form, (3) modelling dependence between data for extremes of pairs of parameters using a form of regression, (4) simulation of long return periods to estimate joint extremes. We demonstrate the approach in application to measured and hindcast data from the Northern North Sea, the Gulf of Mexico and the North West Shelf of Australia. We also illustrate the use of data re-sampling techniques such as bootstrapping to estimate the uncertainty in marginal and dependence models and accommodate this uncertainty in extreme quantile estimation.We discuss the current approach in the context of other approaches to multivariate extreme value estimation popular in the ocean engineering community.     

Seasonal variation of global surface pressure and water vapor

Previous studies have shown that the seasonal variation of global-mean surface pressure ( p _s) results from variation of global-mean water vapor pressure ( p _w). The current study, employing the global data generated by Version 1 of the Goddard Earth Observing System (GEOS-1) Data Assimilation System, shows that seasonal variations of regional p _s and p _w tend to be out of phase (particularly in the subtropics of the two hemispheres) and that the magnitude of the former variation is generally much larger than that of the latter. The seasonal variations of these two quantities are maintained by airmass and water vapor transports by the global divergent circulation, which is driven by the latent heat released by cumulus convection over the water vapor sink, as the "water mass forcing" mechanism predicted. Since p _w and p _s are used often in depicting the climate system, assessments of climate change in terms of the global-mean and regional variations of these two variables should be interpreted with caution.     

Effects of benzene and dimethylnaphthalene on homeostatic processes in two species of crabs

Long-term exposure of animals to sub-lethal doses of toxicants such as benzene (B) and dimethylnaphthalene (DMN) may result in subtle changes in their physiology and biochemistry. In crustaceans such changes include decreased rate of limb regeneration, extended time to molt and decreased growth increment at molt.^1,2 These processes depend upon an adequate supply of stored nutrients in the tissues and appropriate release of neuroendocrine substances from the central nervous system.^3,4 We are examining the effects of sub-lethal doses of B and DMN on osmotic and ionic regulation and on nutrient storage in the blue crab, Callinectes sapidus, and the green crab, Carcinus maenas. Disturbances in these physiological processes may reflect alterations in neuroendocrine functions brought about by the presence of toxicants. We find that exposure of C. maenas to B or DMN, followed by transfer to a dilute medium, results in impaired osmoregulatory capacity, while addition of these compounds to a dilute medium to which the animal is already acclimated does not affect their regulatory ability. Storage of carbohydrate in the midgut gland (hepatopancreas) is decreased by B or DMN, while the accessory storage tissues (gill, muscle) are not significantly affected.     

The delivery of organic matter from asteroids and comets to the early surface of Mars

Carbon delivered to the Earth by interplanetary dust particles may have been an important source of pre-biotic organic matter (Anders, 1989). Interplanetary dust is shown to deliver an order-of-magnitude higher surface concentration of carbon onto Mars than onto Earth, suggesting interplanetary dust may be an important source of carbon on Mars as well.     

The colours of the Sun

We compile a sample of Sun-like stars with accurate effective temperatures, metallicities and colours (from the ultraviolet to the near-infrared). A crucial improvement is that the effective temperature scale of the stars has recently been established as both accurate and precise through direct measurement of angular diameters obtained with stellar interferometers. We fit the colours as a function of effective temperature and metallicity, and derive colour estimates for the Sun in the Johnson–Cousins, Tycho, Strömgren, 2MASS and SDSS photometric systems. For  ( B − V )_⊙  , we favour the 'red' colour 0.64 versus the 'blue' colour 0.62 of other recent papers, but both values are consistent within the errors; we ascribe the difference to the selection of Sun-like stars versus interpolation of wider colour– T _eff–metallicity relations.     

The late Miocene to Pleistocene ice-rafting history of southeast Greenland

Analysis of a Miocene-Pleistocene ice-rafted debris (IRD) record from the western Irminger Basin provides evidence for the initiation and long-term behavior of the SE portion of the Greenland Ice Sheet. In the late Miocene (~7.3 Ma), IRD supply to Ocean Drilling Program site 918 increased significantly indicating that glaciers large enough to reach sea level were present in SE Greenland long before the onset of widespread Northern Hemisphere glaciation. IRD accumulated at this site throughout the Pliocene and Pleistocene, supporting the hypothesis that SE Greenland was a key nucleation area for the formation of the Greenland Ice Sheet. Since glacial onset, the western Irminger Basin IRD record is characterized by a succession of episodes with high IRD mass accumulation rates (MARs). The site 918 IRD record indicates that greatest iceberg production in SE Greenland occurred during major climatic transitions (e.g. widespread Northern Hemisphere glacial expansion at 2.7 Ma and the mid-Pleistocene climate shift at 0.9 Ma), and that SE Greenland sometimes also led the northern North Atlantic region in glacial response to climatic forcing (e.g. glacial intensification at ~4.8 and, along with NE Greenland, at ~3.5 Ma).     

Interplanetary dust particles collected from the stratosphere: physical, chemical, and mineralogical properties and implications for their sources

The suggestion that significant quantities of interplanetary dust are produced by both main-belt asteroids and comets is based on the Infrared Astronomical Satellite detection of dust trails or bands associated with these objects. Gravitational focusing strongly biases all near-Earth collections of interplanetary dust in favor of particles with the lowest geocentric velocities, that is the dust from main-belt asteroids spiraling into the Sun under the influence of Poynting-Robertson radiation drag.

The major dust bands in the main-belt appear to be associated with the catastrophic disruptions which produced the Eos, Themis and Koronis families of asteroids. If dust particles are produced in the catastrophic collision process, then Poynting-Robertson radiation drag is such an efficient transport mechanism from the main-belt to 1 AU that near-Earth collections of interplanetary dust should include, and perhaps be dominated by, this material. The physical, chemical and mineralogical properties of this asteroidal dust can provide constraints on the properties of the asteroidal parent bodies.

Interplanetary dust particles from 5 to 100 μm in diameter have been recovered from the stratosphere of the Earth by NASA sampling aircraft since the mid1970s. The densities of a large fraction of these interplanetary dust particles are significantly lower than the densities of their constituent silicate mineral phases, indicating significant porosities. Direct examination of ultra-microtome thin-sections of interplanetary dust particles also shows significant porosities. The majority of the particles are chemically and mineralogically similar to, but not identical to, the carbonaceous chondrite meteorites.

Most stony interplanetary dust particles have carbon contents exceeding those of Allende, a carbonaceous chondrite meteorite having a low albedo. The population of interplanetary dust does not appear to exhibit the full range of compositional diversity inferred from reflection spectroscopy of the main-belt asteroids. In particular, higher albedo particles corresponding to S-type asteroids are underrepresented or absent from the stratospheric collections, and primitive carbonaceous particles seem to be overrepresented in the stratospheric collections compared to the fraction of mainbelt asteroids classified as primitive. This suggests that much of the interplanetary dust may be generated by a stochastic process, probably preferentially sampling a few most recent collisional events.     

On the origin of high-eccentricity halo stars

The present-day chemical and dynamical properties of the Milky Way are signatures of the Galaxy's formation and evolution. Using a self consistent chemodynamical evolution code we examine these properties within the currently favoured paradigm for galaxy formation – hierarchical clustering within a CDM cosmology. Our Tree N-body/Smoothed Particle Hydrodynamics code includes a self-consistent treatment of gravity, hydrodynamics, radiative cooling, star formation, supernova feedback and chemical enrichment. Two models are described which explore the role of small-scale density perturbations in driving the evolution of structure within the Milky Way. The relationship between metallicity and kinematics of halo stars are quantified and the implications for galaxy formation discussed. While high-eccentricity halo stars have previously been considered a signature of `rapid collapse', we suggest that many such stars may have come from recently accreted satellites. This revised version was published online in August 2006 with corrections to the Cover Date.