Mono- and dicyclic unsaturated triterpenoid hydrocarbons in sediments from Lake Masoko (Tanzania) widely extend the botryococcene family

A mixture of C₃₃–C₃₇ botryococcenes and partially reduced derivatives was isolated from ca. 32,000 year old sediment from Lake Masoko, a freshwater crater lake in the Rungwe Range area (Tanzania). Botryococcenes and derivatives accounted for 246 μg/g dry sediment and for >92% of the hydrocarbon fraction; 1D and 2D nuclear magnetic resonance spectroscopy (NMR) and mass spectrometry allowed the structure of the dominant botryococcene (43% of hydrocarbon fraction) to be established, after purification using high performance liquid chromatography (HPLC). The compound is a novel tetraunsaturated dicyclic C₃₄ botryococcene and is named C₃₄ masokocene. Overall, the structures of six other novel botryococcenes and four partially reduced derivatives were tentatively assigned. The structures of the new biomarkers, three dicyclic C₃₄–C₃₆ botryococcenes (or masokocenes) and seven monocyclic C₃₄–C₃₇ analogues are discussed along with their biosynthetic relationship. The high abundance of such polyunsaturated compounds preserved in 32,000 year old sediment from the lake indicates an aquatic ecosystem dominated at the time by the green alga Botryococcus braunii, as well very good preservation of the organic matter.     

A multidisciplinary multi-scale framework for assessing vulnerabilities to global change

Terrestrial ecosystems provide a number of vital services for people and society, such as food, fibre, water resources, carbon sequestration, and recreation. The future capability of ecosystems to provide these services is determined by changes in socio-economic factors, land use, atmospheric composition, and climate. Most impact assessments do not quantify the vulnerability of ecosystems and ecosystem services under such environmental change. They cannot answer important policy-relevant questions such as 'Which are the main regions or sectors that are most vulnerable to global change?’ 'How do the vulnerabilities of two regions compare?’ 'Which scenario is the least harmful for a sector?’This paper describes a new approach to vulnerability assessment developed by the Advanced Terrestrial Ecosystem Analysis and Modelling (ATEAM) project. Different ecosystem models, covering biodiversity, agriculture, forestry, hydrology, and carbon sequestration are fed with the same Intergovernmental Panel on Climate Change (IPCC) scenarios based on the Special Report on Emissions Scenarios (SRES). Each model gives insights into specific ecosystems, as in traditional impact assessments. Moreover, by integrating the results in a vulnerability assessment, the policy-relevant questions listed above can also be addressed. A statistically derived European environmental stratification forms a key element in the vulnerability assessment. By linking it to other quantitative environmental stratifications, comparisons can be made using data from different assessments and spatial scales.     

Temperature and Salinity Effects on Alkenone Ratios Measured in Surface Sediments from the Indian Ocean

We compare alkenone unsaturation ratios measured on recent sediments from the Indian Ocean (20°N–45°S) with modern sea oceanographic parameters. For each of the core sites we estimated average seasonal cycles of sea surface temperature (SST) and salinity, which we then weighted with the seasonal productivity cycle derived from chlorophyll satellite imagery. The unsaturation index (U₃₇^K′) ranges from 0.2 to 1 and correlates with water temperature but not with salinity. TheU₃₇^K′versus SST relationship for Indian Ocean sediments (U₃₇^K′= 0.033 SST + 0.05) is similar to what has been observed for core tops from the Pacific and Atlantic oceans and the Black Sea. A global compilation for core tops givesU₃₇^K′= 0.031 T + 0.084 (R= 0.98), which is close to a previously reported calibration based on particulate organic matter from the water column. For temperatures between 24° and 29°C, however, the slope seems to decrease to about 0.02U₃₇^K′unit/°C. For Indian Ocean core tops, the ratios of total C₃₇alkenones/total C₃₈alkenones and the slope of theU₃₇^K′-SST relationship are similar to those previously observed for cultures ofEmiliania huxleyibut different from those previously published forGephyrocapsa oceanica.EitherE. huxleyiis a major producer of alkenones in the Indian Ocean or strains ofG. oceanicaliving in the northern Indian Ocean behave differently from the one cultured. In contrast with coccolithophorid assemblages, the ratios of C₃₇alkenones to total C₃₈alkenones lack clear geographic pattern in the Indian Ocean.     

Solar modulation of cosmogenic nuclide production over the last millennium: comparison between C and Be records

For about the last 30 years it has been recognized that the high frequency component of the tree rings ¹⁴C/¹²C record is dominated by the modulation of the cosmic ray flux by the solar wind. In particular, it has been demonstrated that the three most recent periods of low sunspot occurrence were characterized by high values of atmospheric ¹⁴C/¹²C. During the last millennium other periods of high ¹⁴C/¹²C values were observed but their solar origin is still debatable. In the present work we compare these fluctuations with an independent record of cosmogenic ¹⁰Be measured in ice from the South Pole to check the solar origin of the observed ¹⁴C/¹²C variations. In order to compare quantitatively the results obtained on ¹⁰Be and ¹⁴C, it is necessary to take into account the different behaviour of these two cosmogenic isotopes, and especially the damping effect of the carbon cycle in the case of ¹⁴C. As an input to a 12-box numerical model we used the relative fluctuations of the ¹⁰Be concentrations record measured in South Pole ice and converted it into a synthetic ¹⁴C record. We took into account the fact that ¹⁰Be modulation is enhanced in polar regions due to the orientation of the geomagnetic field. As expected, the fluctuations of the modelled ¹⁴C record are much smaller (a factor of 20) than those observed for the raw ¹⁰Be record. In addition, the variations are smoother and shifted in time by a few decades. The ¹⁰Be-based ¹⁴C variations closely resemble the ¹⁴C measurements obtained on tree rings (R = 0.81). In particular, it is easy to identify periods of maximal ¹⁴C/¹²C which correspond to solar activity minima centred at about 1060, 1320 (Wolf), 1500 (Spörer), 1690 (Maunder) and 1820 (Dalton) yr A.D. Cross-correlation calculations suggest that there is no significant lag between the ¹⁰Be-based ¹⁴C and the tree-ring ¹⁴C records. Our study strongly suggests the dominance of the solar modulation on the cosmonuclide production variations during the last millennium.     

Post-eruptive lahars at Kali Putih following the 2010 eruption of Merapi volcano,Indonesia: occurrences and impacts

Following the 2010 VEI 4 eruption of Merapi volcano, more than 250 lahars were triggered during two rainy seasons from October 2010 to March 2012. This high number of post-eruption lahars mainly occurred in the Kali (valley) Putih watershed and was mostly associated with high-magnitude rainstorms. A lahar occurring on January 8, 2011, caused significant damage to homes in several communities, bridges, sabo dams, and agricultural crops. The aims of this contribution are to document the impacts of lahars on the Kali Putih watershed and specifically (1) to analyze the lahar frequency during the period of 1969–2012 on an inter-annual and intra-annual basis and to determine the link between the volume of tephra and the frequency of lahars; (2) to detail the lahar trajectory and channel evolution following the January 8th lahar; (3) to map the spatial distribution of the thickness and geomorphic effects of the lahar deposit; and (4) to determine the impacts of the lahar on the infrastructure (sabo dams and roads) and settlements in the distal area of the volcano. The Kali Putih watershed has experienced 62 lahars, which represent 22% of all lahars triggered on 17 rivers at Merapi between 2010 and 2012. The main geomorphic impacts are: (1) excessive sedimentation in valleys, settlements and agricultural areas; (2) undercutting of the river banks by as much as 50 m, accompanied by channel widening; and (3) abrupt changes in the river channel direction in the distal area (15–20 km downstream of the volcano). About 19 sabo dams were damaged, and 3 were totally destroyed. Over 307 houses were damaged, and the National Road Yogyakarta–Semarang was regularly cut (18 times during approximately 25 days). Although the sabo dams on Kali Putih were originally constructed to protect distal areas from lahar damage, they had little effect on the 2010–2012 rain-triggered lahars. The underlying design of those dams along this river is one of the main reasons for the major destruction in this sector of the volcano’s lower slope. The catch basin capacity of the sabo dam was only 1.75?×?10⁶ m³, whereas the total volume of the 2010–2011 lahars exceeded 5?×?10⁶ m³. In order to prepare for future lahars, the government has invested in significant mitigation measures, ranging from structural approaches (e.g., building new sabo dams and developing an early warning system) to non-structural approaches (e.g., contingency and preparedness planning and hazard education).

     

Penetration of bomb radiocarbon in the tropical Indian Ocean measured by means of accelerator mass spectrometry

Radiocarbon measurements performed on seawater samples by means of accelerator mass spectrometry (AMS) enable to reduce by a factor of 2000 the water sample size needed for the¹⁴C measurements. Therefore no chemical treatment on board the oceanographic vessel is required. Seventy-four AMS¹⁴C determinations on samples collected in the tropical-equatorial Indian Ocean during the second leg of the INDIGO program (1986) are presented and compared with the β-counting results obtained during the same campaign and the GEOSECS program (1978). A pronounced reduction of the equatorial¹⁴C deficit suggests that substantial amounts of bomb-¹⁴C are associated with the westward flowing Pacific water which enters the Indian Ocean via passages through the Indonesia archipelago and/or to meridional mixing with¹⁴C-rich water of the southern subtropical gyre.     

Marée de l'écorce: L'effet du dephasage dans l'analyse des observations

Résumé L'amplitude relativeA de la marée de l'écorce se déduit du rapport entre les variations de pesanteur théorique et observée. La comparaison directe de leurs valeurs horaires permet de déterminer ce rapport, mais cette méthode néglige le déphasage éventuel de la marée de l'écorce par rapport aux forces génératrices. L'erreur (négative) qui en résulte sur les valeurs habituelles deA est d'environ 11% (en supposant un déphasage de 1 h), si l'on compare uniquement les amplitudes extrêmes; elle atteint 14% si l'on tient compte de l'ensemble des valeurs horaires.Si l'effet du déphasage se fait peu ressentir aux heures où la marée est importante, on conçoit qu'il introduise une erreur relative considérable sur les valeurs horaires correspondant à une marée faible. Le calcul montre cependant qu'on n'améliore guère lè résultat global en éliminant systématiquement ces dernières.

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Summary The relative amplitudeA of the earth tide is deduced from the ratio of the theoretical variations of gravity to the observed. The direct comparison of their hourly values allows the determination of this ratio, but this method neglects the eventual dephasing of the earth tide over the generating forces. The resulting (negative) error on the usual values ofA is about 11% (supposing a dephasing of 1 hour), if only extreme amplitudes are compared; it reaches 14% if the totality of the hourly values is taken into account.If the effect of the dephasing is slight at the hours when the tide has a great value, it is conceivable that it introduces a noticeable relative error on the hourly readings corresponding to a low value. The computation shows nevertheless that the total result is little improved by systematic elimination of the latter.

     

利用步长模拟对青藏高原涡度方差测量法的质量评价

利用痕迹模拟方法对青藏高原两处地方涡度方差的测量数据进行了质量分析，揭示了其空间和时间结构。分析表明高达1/3的测量没有达到必要的数据正确假设。尽管这样对潜热、CO2、动量通量的测量基本通过测试，可以适用于基础研究，但是经常发现特定的风矢量违背基本假设条件。感热通量的测量允许使用不间断的连续测量法，然而由于局地地形的影响少量评估指数未能合理解释，但能够指示出组织结构及用于导出边界层中尺度流体模型假说。     

Aquifer Storage Recovery (ASR) of chlorinated municipal drinking water in a confined aquifer

About 1.02 × 10⁶ m³ of chlorinated municipal drinking water was injected into a confined aquifer, 94–137 m below Roseville, California, between December 2005 and April 2006. The water was stored in the aquifer for 438 days, and 2.64 × 10⁶ m³ of water were extracted between July 2007 and February 2008. On the basis of Cl⁻ data, 35% of the injected water was recovered and 65% of the injected water and associated disinfection by-products (DBPs) remained in the aquifer at the end of extraction. About 46.3 kg of total trihalomethanes (TTHM) entered the aquifer with the injected water and 37.6 kg of TTHM were extracted. As much as 44 kg of TTHMs remained in the aquifer at the end of extraction because of incomplete recovery of injected water and formation of THMs within the aquifer by reactions with free-chlorine in the injected water. Well-bore velocity log data collected from the Aquifer Storage Recovery (ASR) well show as much as 60% of the injected water entered the aquifer through a 9 m thick, high-permeability layer within the confined aquifer near the top of the screened interval. Model simulations of ground-water flow near the ASR well indicate that (1) aquifer heterogeneity allowed injected water to move rapidly through the aquifer to nearby monitoring wells, (2) aquifer heterogeneity caused injected water to move further than expected assuming uniform aquifer properties, and (3) physical clogging of high-permeability layers is the probable cause for the observed change in the distribution of borehole flow. Aquifer heterogeneity also enhanced mixing of native anoxic ground water with oxic injected water, promoting removal of THMs primarily through sorption. A 3 to 4-fold reduction in TTHM concentrations was observed in the furthest monitoring well 427 m downgradient from the ASR well, and similar magnitude reductions were observed in depth-dependent water samples collected from the upper part of the screened interval in the ASR well near the end of the extraction phase. Haloacetic acids (HAAs) were completely sorbed or degraded within 10 months of injection.     

Projected climate change impacts on spatial distribution of bioclimatic zones and ecoregions within the Kailash Sacred Landscape of China,India, Nepal

Rapidly accelerating climate change in the Himalaya is projected to have major implications for montane species, ecosystems, and mountain farming and pastoral systems. A geospatial modeling approach based on a global environmental stratification is used to explore potential impacts of projected climate change on the spatial distribution of bioclimatic strata and ecoregions within the transboundary Kailash Sacred Landscape (KSL) of China, India and Nepal. Twenty-eight strata, comprising seven bioclimatic zones, were aggregated to develop an ecoregional classification of 12 ecoregions (generally defined by their potential dominant vegetation type), based upon vegetation and landcover characteristics. Projected climate change impacts were modeled by reconstructing the stratification based upon an ensemble of 19 Earth System Models (CIMP5) across four Representative Concentration Pathways (RCP) emission scenarios (i.e. 63 impact simulations), and identifying the change in spatial distribution of bioclimatic zones and ecoregions. Large and substantial shifts in bioclimatic conditions can be expected throughout the KSL area by the year 2050, within all bioclimatic zones and ecoregions. Over 76 % of the total area may shift to a different stratum, 55 % to a different bioclimatic zone, and 36.6 % to a different ecoregion. Potential impacts include upward shift in mean elevation of bioclimatic zones (357 m) and ecoregions (371 m), decreases in area of the highest elevation zones and ecoregions, large expansion of the lower tropical and sub-tropical zones and ecoregions, and the disappearance of several strata representing unique bioclimatic conditions within the KSL, with potentially high levels of biotic perturbance by 2050, and a high likelihood of major consequences for biodiversity, ecosystems, ecosystem services, conservation efforts and sustainable development policies in the region.