高、低煤阶煤层气藏地质特征及控气作用差异性研究

高、低煤阶煤层气地质特征及控气作用差异性是研究煤层气富集成藏的重要组成部分,是煤层气勘探开发理论研究过程中重要的基础性研究领域之一。本文以中国沁水、阜新盆地和美国粉河盆地等典型的含气盆地为例,探讨了高、低煤阶煤层气的储层物性差异,分析了构造控气和水文地质控气作用的差异性。研究表明,高煤阶气藏含气量高,CH4百分含量高,δ13C1值大于-38.75‰,储层渗透率变化小,储层改造难,构造热事件对煤层气的生成、富集贡献大,持续的水动力使气藏遭到破坏,且破坏幅度大,现今地下水格局对气藏的形成具有一定的影响;低煤阶气藏含气量低,CH4百分含量低,δ13C1值大于-49.11‰,储层渗透率变化大,储层易改造,煤热演化史及煤阶影响着煤层气的生成、富集,在煤层气生成过程中活跃的水动力是甲烷生成的主要的水文地质条件之一,但持续的水动力使气藏遭到破坏,且破坏幅度小,而合适的地层水矿化度则是低煤阶煤层气生成的重要条件,地下水格局对气藏的调整和改造起到决定性的影响。     

Application of MODFLOW and geographic information system to groundwater flow simulation in North China Plain, China

MODFLOW is a groundwater modeling program. It can be compiled and remedied according to the practical applications. Because of its structure and fixed data format, MODFLOW can be integrated with Geographic Information Systems (GIS) technology for water resource management. The North China Plain (NCP), which is the politic, economic and cultural center of China, is facing with water resources shortage and water pollution. Groundwater is the main water resource for industrial, agricultural and domestic usage. It is necessary to evaluate the groundwater resources of the NCP as an entire aquifer system. With the development of computer and internet information technology it is also necessary to integrate the groundwater model with the GIS technology. Because the geological and hydrogeological data in the NCP was mainly in MAPGIS format, the powerful function of GIS of disposing of and analyzing spatial data and computer languages such as Visual C and Visual Basic were used to define the relationship between the original data and model data. After analyzing the geological and hydrogeological conditions of the NCP, the groundwater flow numerical simulation modeling was constructed with MODFLOW. On the basis of GIS, a dynamic evaluation system for groundwater resources under the internet circumstance was completed. During the process of constructing the groundwater model, a water budget was analyzed, which showed a negative budget in the NCP. The simulation period was from 1 January 2002 to 31 December 2003. During this period, the total recharge of the groundwater system was 49,374 × 10⁶ m³ and the total discharge was 56,530 × 10⁶ m³ the budget deficit was −7,156 × 10⁶ m³. In this integrated system, the original data including graphs and attribution data could be stored in the database. When the process of evaluating and predicting groundwater flow was started, these data were transformed into files that the core program of MODFLOW could read. The calculated water level and drawdown could be displayed and reviewed online.     

高效铝合金牺牲阳极的研究

在铝中添加合金元素Zn,Mg,In,Ga,Ca,利用正交设计方法,研制出一种高效的铝合金牺牲阳极,它在海水中的电流效率达95.6％,电位为-1.09V(SCE)。并研究了合金元素In,Ga,Ca对铝合金电化学性能的影响及阳极活化机理。     

珠江三角洲晚第四纪沉积特征

本文主要研究珠江三角洲的第四纪地层;晚更新世玉木亚间冰期、全新世中期(大西洋期)海侵阶段的地貌景观及珠江三角洲晚第四纪以来的沉积形成过程。     

温度和盐度骤变条件下凡纳滨对虾的行为变化研究

以视频记录分析的方法,研究凡纳滨对虾Litopenaeus vannamei在温度和盐度骤变条件下的运动行为、摄食行为及相关生理活动的变化。结果表明,当温度由29℃骤降至18和23℃时,对虾的活动频率、游走速度和颚舟片的摆动频率明显下降,索饵时间显著增加(p<0.05);当温度由29℃骤升至36℃时,对虾的活动频率、游走速度和颚舟片的摆动频率显著升高(p<0.05),索饵时间没有显著差异(p>0.05)。当盐度由30骤降至5和10时,对虾表现出强烈的逃避行为,活动频率、游走速度和颚舟片的摆动频率均显著升高(p<0.05),并且在观察时间内没有发生摄食行为。     

甲醛对Nessler法和次氯酸酚盐法测定养殖水体总氨氮的影响

水体中含一定浓度的甲醛 ,用 Nessler法测得的总氨氮 (TAN)浓度远远高于实际浓度 ,差异百分数最高达 4 5 0 .0 6 % ;用次氯酸酚盐法测得的总氨氮 (TAN)浓度则明显低于实际浓度 ,差异百分数最高可达 84 .77%。甲醛浓度范围为 10～ 4 0 mg/ L、TAN浓度为 1～ 10 mg/ L,通过双因素有重复观察值的交叉实验 ,得到如下矫正式 :(1)用 Nessler法测 TAN时 ,Y=4 .0 5 2 9- 0 .0 72 4 x1+ 0 .2 0 6 4x2 ,标准误差为 1.3381;(2 )用次氯酸酚盐法测 TAN时 ,Y=0 .1196 + 0 .0 345 x1+ 1.0 0 2 2 x2 ,标准误差为 0 .4 6 2 7。 Y为 TAN实际浓度 (mg/ L) ,x1为甲醛浓度 (mg/ L) ,x2 为测得的 TAN浓度(mg/ L )。比较含氨氮水体与不含氨氮水体中的甲醛浓度 ,方差分析结果表明 ,没有显著差异。     

The distribution and geological significance of carbazole compounds in Silurian paleo-pools of the Tarim Basin,Northwest China

The results presented in this paper indicated that the carbazole-type compounds have high thermal stability and also show stability in oxidation and bio-degradation. This kind of compounds still has high concentrations and a complete distribution in the analyzed dry asphalt samples, showing that they are particularly useful in the study of hydrocarbon migration of the paleo-pools. The difference in the contents of nitrogen compounds in the Silurian dry asphalts from the Awati, Tabei and Tazhong areas is attributed to the difference in the extent of oxidation and （or） bio-degradation for the areas; the Awati and Tabei areas underwent relatively strong oxidation and bio-degradation. During the first stage of hydrocarbon pool formation in the Silurian system in the Tazhong and Tabei areas of the Tarim Basin （at the end of the Silurian period） and at the second stage in the Awati area （in Permian）, the hydrocarbons experienced a long-distance migration.     

Mechanism for the rapid motion of the Qianjiangping landslide during reactivation by the first impoundment of the Three Gorges Dam reservoir, China

The first impoundment of the Three Gorges Dam reservoir in China started from a water surface elevation of 95 m on June 1, 2003 and reached 135 m on June 15, 2003. Shortly after the water level reached 135 m, many slopes began to deform and some landslides occurred. The Qianjiangping landslide is the largest one; it occurred on the early morning of July 14, 2003 and caused great loss of lives and property. Field investigation revealed that, although failure occurred after the reservoir reached 135 m, the stability of the slope was already reduced by preexisting sheared bedding planes. To study the mechanism of the rapid motion of this reactivated landslide, two soil samples were taken from a yellow clay layer and a black silt layer in the sliding zone, respectively, and a series of ring shear tests were conducted on the samples. One series of ring shear tests simulates the creep deformation behavior, while the other series simulates different shear rates. Conclusions drawn from analysis of the ring shear tests indicate that the mechanism of the rapid motion of the reactivated landslide was caused by the rate effect of the black silt layer during the motion phase after the creep failure. The yellow clay layer did not play any important role in the rapid motion in the 2003 event.     

粤西地区县域城镇化发展探讨——以广东省高州市为例

受地理条件、经济基础等因素的制约,粤西地区面临着城镇化进程滞后、整体发展层次偏低等一系列问题。加速推进县域城镇化是加快粤西地区经济发展,缩小与发达地区差距的内在要求和必然选择。以高州市为例,全面总结了粤西地区县域城镇化发展的特点及存在的主要问题,并在系统分析其城镇化发展机制的基础上,提出通过完善城镇体系,加强产业集聚,提升建设品位,增强城镇自我发展能力等促进县域城镇化发展。     

A study on the geochemical characteristics of Upper Permian continental marginal arc volcanic rocks in the northern segment of South Lancangjiang Belt

1IntroductionThe northern segment of the South LancangjiangBelt refers to the terrain about200km east of theYunxian-Lingcang granite in the South LancangjiangBelt(Fig.1).During the seventh Five-Year Plan peri-od,Mo Xuanxue et al.(1993)undertook the resear…