Study on the geochemical characteristics of arc-volcanic rocks in the Chiang Rai-Lampang belt of northern Thailand

On the basis of the petrographic characteristics, rock assemblages, petrochemistry, REEs, trace elements and geotectonic settings, the authors described the characteristics of continental marginal arc-volcanic rocks in the Late Permian-Early Triassic (P2-T1) volcanic rocks distributed on the eastern side of the ocean-ridge/oceanic island basalts in the Chiang Mai belt. The volcanic rock assemblage is basaltic andesite-andesite-rhyolite. The volcanic series is dominated by the calc-alkaline series, with the tholeitic series coming next. The chemical composition of the volcanic rocks is characterized by high Al2O3; the REE distribution patterns are of the LREE-enrichment rightward incline type; the large cation elements are highly enriched, and the volcanic rocks are generally enriched in U and Th and depleted in Ti, Cr and P. The petrochemical plot falls within the field of island-arc volcanic rocks, in consistency with the projected points of continental marginal arc-volcanic rocks in the Lancangjiang belt. These continental mar-ginal arc-volcanic rocks, together with ocean-ridge/oceanic island-type volcanic rocks in the Chiang Mai belt, con-stitute the ocean-ridge volcanic rock-arc magmatic rock belts distributed in pairs, indicative of eastward subduction of the oceanic crust in the Chiang Mai belt. This result is of great importance in exploring the evolution of the pa-leo-Tethys in the Chiang Mai belt.     

南澜沧江带北段上二叠统陆缘弧火山岩的厘定

从岩石组合、岩相学特征、岩石化学、稀土元素、微量元素、大地构造环境等诸多方面分析云县-临沧花岗岩东侧的小定西、崴里等地分布的上二叠统P2火山岩具有陆缘弧火山岩特征。火山岩组合以玄武岩-安山岩-英安岩为主,极少量的粗安岩-粗面岩;火山岩系列以钙碱性系列为主,拉斑系列及碱性系列较少;火山岩的化学成分以A l2O3低T iO2为特征,K2O含量显示极强的极性;稀土模式为轻稀土富集右倾斜型;微量元素大阳离子元素富集,亏损T i,C r和部分亏损P,N b;岩石化学投图绝大部分落在岛弧火山岩区,与南澜沧江带南段及北澜沧江带陆缘弧火岩投点相一致。厘定了南澜沧江带北段上二叠统P2陆缘弧火山岩的存在。该陆缘弧火岩带与昌宁-孟连带的洋脊/洋岛型火山岩、蛇绿岩构成了成对分布的洋脊火山岩、蛇绿岩-弧岩浆岩带,指示澜沧江洋壳向东俯冲。该成果对探讨澜沧江带古特提斯的演化具有极重要的作用。     

Geochemical characteristics of island-arc volcanic rocks in the Nan-Nam Pat-Phetchabun zone,northern Thailand

Late Permian-Early Triassic (P₂-T₁) volcanic rocks distributed on the eastern side of ocean-ridge and oceanic-island basalts in the Nan-Uttaradit zone were analyzed from aspects of petrographic characteristics, rock assemblage, REE, trace elements, geotectonic setting, etc., indicating that those volcanic rocks possess the characteristic features of island-arc volcanic rocks. The volcanic rock assemblage is basalt-basaltic andesite-andesite. The volcanic rocks are sub-alkaline, dominated by calc-alkaline series, with tholeiite series coming next. The chemical composition of the volcanic rocks is characterized by low TiO₂ and K₂O and high Al₂O₃ and Na₂O. Their REE patterns are of the flat, weak LREE-enrichment right-inclined type. The trace elements are characterized by the enrichment of large cation elements such as K, Rb and Ba, common enrichment of U and Th, and depletion of Nb, Ta, Zr and Hf. The petrochemical plot falls within the field of volcanic rocks, in consistency with the plot of island-arc volcanic rocks in the Jinsha River zone of China. This island-arc volcanic zone, together with the ocean-ridge/oceanic island type volcanic rocks in the Nan-Uttaradit zone, constitutes the ocean-ridge volcanic rock-island-arc magmatic rock zones which are distributed in pairs, indicating that the oceanic crust of the Nan-Uttaradit zone once was of eastward subduction. This work is of great significance in exploring the evolution of paleo-Tethys in the Nan-Uttaradit zone.     

三江地区南澜沧江带火山岩构造岩浆类型

从火山岩地质，岩石组合，岩石化学，稀土元素，微量元素，大地构造环境等诸方面论述了南澜沧江带可细化为5个火山岩构造岩浆带，即大平掌裂谷火山岩带，大兴山-小街洋脊火山岩带，大兴山-热水塘洋内弧火山岩带，邦沙陆缘弧火山岩带，小定西-民乐陆内弧火山岩带，这种细化对探讨该区的特提斯演化有极重要的作用。     

Newly developed evidence for the original Tethysan island-arc volcanic rocks in the southern segment of the South Lancangjiang Belt

This paper re-describes the characteristics of pre-Ordovician (Pt3) metamorphic volcanic rocks in the Huimin-Manlai region of Yunnan Province from the aspects of petrographic characteristics, rock assemblage, petrochemistry, REE, trace elements, lead isotopes and geotectonic setting. The metamorphic volcanic rocks maintain blasto-intergranular and blasto-andesitic textures; the volcanic rocks are characterized by a basalt-andesite-dacite assemblage; the volcanic rocks are basic-intermediate-intermediate-acid in chemical composition, belonging to semi-alkaline rocks, with calc-alkaline series and tholeiite series coexisting, and they are characterized by low TiO2 contents; their REE distribution patterns are of the LREE-enrichment right-inclined type; the volcanic rocks are enriched in large cation elements and commonly enriched in Th and partly depleted in Ti, Cr and P, belonging to the Gondwana type as viewed from their Pb isotopic composition; petrochemically the data points fall mostly within the field of island-arc volcanic rocks. All these characteristics provided new evidence for the existence of original Tethysan island-arc volcanic rocks in the region studied.     

南澜沧江带南段原特提斯岛弧火山岩新证据

从岩相学特征、岩石组合、岩石化学、稀土元素、微量元素、铅同位素、大地构造环境等诸方面对云南惠民-曼来地区前泥盆纪(Pt3)变质火山岩的特征进行研究,结果表明:该地区变质火山岩保留有变余间粒及变余安山结构;火山岩组合为玄武岩-安山岩-英安岩;火山岩的化学成分:基性—中性—中酸性,属亚碱性,钙碱性系列与拉斑系列并存,以低TiO2为特征;稀土模式为轻稀土富集右倾斜型;微量元素大阳离子元素富集,且普遍富Th,亏损Ti,部分亏损Cr;铅同位素组成属于冈瓦纳型;岩石化学投点绝大部分落在岛弧火山岩区,为该区原特提斯岛弧火山岩的存在提供了新证据。     

西南三江造山带火山岩—构造组合及其意义

岩石构造组合是指表示板块边界或特定的板块内部环境特征的岩石结合。中国西南“三江”造山带的火山岩可划分为五种火山岩－构造组合：洋脊型／准洋脊型组合，岛弧及陆缘弧组合，碰撞型组合，碰撞后组合及陆内拉张型组合。阐述了各种火山岩－构造组合的特点及构造含义。对在造山带火山岩岩石－构造组合分析中经常遇到的一些问题，如“构造岩片”研究方法、地球化学判别图解的使用条件、准洋脊型火山型组合的构造含义、蛇绿岩带－火山弧的成对性、岩浆作用的同步性和滞后性、以及火山岩的深部“探针”作用等问题进行了讨论。     

羌塘东部治多县直根尕卡一带二叠纪栖霞期火山岩地球化学特征及其构造意义

羌塘东部治多县直根尕卡一带二叠纪栖霞期火山岩主要由中基性火山碎屑岩及熔岩组成,火山岩地球化学研究表明,其主元素表现为高TiO_2和低TiO_2两种特征,球粒陨石标准化稀土配分模式为LREE富集型.MORB标准化的微量元素配分型式为大洋隆起型,显示岩浆形成于板内裂谷构造环境.Sr、Nd、Pb同位素地球化学研究表明火山岩显示明显的亏损地幔源区特征.综合研究表明直根尕卡一带二叠纪栖霞期火山岩形成于大陆边缘拉张构造(或陆缘始裂谷)环境,岩浆起源于地幔,属地幔柱作用的产物.     

东昆仑巴颜喀拉浊积盆地二叠纪火山岩

东昆仑巴颜喀拉浊积盆地内沿扎拉依-哥琼尼洼断裂带及约古宗列断裂带的断夹块内出露有一套二叠纪马尔争组火山岩, 火山岩呈构造岩片形式产出, 扎拉依-哥琼尼洼断裂带火山岩岩石组合主要为玄武岩、玄武安山岩, 少量玄武岩具枕状构造, 岩石SiO₂含量均匀, TiO₂的含量较高, ALK的含量较低, 为拉斑系列的玄武岩, 玄武岩稀土总量较高, 稀土配分曲线为轻稀土富集型, 与洋岛型火山岩的稀土配分曲线相一致, 火山岩大离子亲石元素较富集, 高场强元素及重稀土元素较平坦, 稀土、微量元素特征及构造环境判别显示其形成于较富集的洋岛环境, 少数为洋中脊的构造环境.约古宗列断裂带火山岩岩石组合为玄武岩、玄武安山岩, 岩石SiO₂含量较高, TiO₂含量较低, 均 < 1%, 为钙碱性系列火山岩, 玄武安山岩的稀土配分曲线与扎拉依-哥琼尼洼断裂带一致, 而英安岩的轻稀土富集程度高, 与岛弧高钾安山岩的稀土配分曲线相吻合, 构造环境判别显示其形成于岛弧构造环境.根据扎拉依-哥琼尼洼断裂带两侧火山岩成分的差异以及断裂带两侧巴颜喀拉群碎屑物成分的差异, 可以把巴颜喀拉山三叠纪浊积盆地进一步划分为北亚带和南亚带.      

从岛弧向裂谷的变迁—来自阿吾拉勒地区火山岩的证据

阿吾拉勒地区早、中石炭世火山岩以碱性系列为主，少部分属钙碱性系列；稀土元素具有岛弧和活动陆缘区橄榄安粗岩和高钾安山岩的特征：微量元素具有大陆型岛弧火山岩的特征。由此证明本区在早、中石炭世处于内弧环境。二叠纪火山岩属碱性系列；稀土元素和微量元素明显有板内碱性玄武岩的特征。     

确定南澜沧江缝合带的火山岩地球化学证据

本文着重根据火山岩的主量元素、稀土元素和微量元素特征厘定了我国西南“三江”地区昌宁－孟连带Ｃ１—Ｐ２火山岩和南澜沧江带Ｐ—Ｔ３火山岩的构造－岩浆类型。昌宁－孟连火山岩带为洋脊／准洋脊型－洋岛型玄武岩、蛇绿混杂岩带,代表澜沧江洋或古特提斯的残迹;南澜沧江火山岩带是一个陆缘火山弧带,是澜沧江洋盆向东俯冲消减、碰撞以及陆内俯冲过程的产物。两带火山岩是成对分布的古特提斯缝合带的产物。     

甘肃北山北带北亚带西缘泥盆纪火山岩地球化学特征

分布于甘肃北山北亚带西缘（双沟山—马鞍山北一带）的泥盆纪火山岩主要为一套浅变质的安山岩、英安岩、流纹岩,局部见少量玄武岩。岩石硅碱成分显示为钙碱性系列,钠质类型;稀土总量为（65．48×10^-6～196．69×10^-6）。属轻稀土富集型,稀土配分型式为右倾曲线;微量元素配分型式类似于岛弧及活动大陆边缘特征,具明显的ULE富集和Nb、Ti等的亏损;同时,从基性到中性熔岩的εNd（t）均为正值（6．46～6．59）,暗示其源区类似亏损地幔源区。Y-Nb和Rb-（Y＋Nb）构造判别图解显示本区中酸性火山岩形成于岛弧环境。综合分析火山岩的岩石学、地球化学特征,并结合区域构造背景,认为该套火山岩产于活动大陆边缘岛弧带环境,属俯冲型火山作用,形成于俯冲造山带的构造背景。     

新疆卡拉麦里姜巴斯套组火山岩地球化学特征与构造意义

通过对新疆卡拉麦里姜巴斯套组火山岩野外地质特征、岩石学和高精度同位素年代学的研究,发现姜巴斯套组火山岩具典型双峰式组合,岩石类型包括玄武岩-酸性火山碎屑岩-玄武粗面安山岩;得到玄武粗面安山岩LA-ICP-MS锆石U-Pb年龄为（319.8±2）Ma（加权均方偏差值为3）,表明姜巴斯套组火山岩形成于早石炭世谢尔普霍夫阶。对火山岩地球化学特征的研究表明,姜巴斯套组火山岩钙碱性系列、高钾钙碱性系列和钾玄岩系列岩石兼而有之,岩石的稀土元素配分曲线均为轻稀土元素富集型,无明显Eu异常,玄武岩和玄武粗面安山岩具有K正异常和Sr负异常,酸性火山碎屑岩表现出Nb、Ta和Ti显著亏损。总体来说,姜巴斯套组火山岩富集大离子亲石元素,相对亏损高场强元素。玄武岩和玄武粗面安山岩表现出大陆裂谷（大陆板内拉张区域）岩石特征;酸性火山碎屑岩表现出岛弧或者活动大陆边缘岩石属性。总之,姜巴斯套组火山岩形成于卡拉麦里洋盆闭合碰撞造山后的拉张伸展环境,卡拉麦里地区在早石炭世末期就进入了碰撞后的陆内伸展拉伸阶段。     

青海鄂拉山地区陆相火山岩地球化学特征及构造环境

鄂拉山岩浆岩带晚三叠世火山岩为中-中酸性火山岩组合,由玄武安山岩、安山岩、英安岩、流纹岩及少量火山碎屑岩等组成,岩石蚀变强烈,成层性差,柱状节理发育,具典型的陆相喷发特点.火山岩属铝饱和类型,里特曼指数(δ)及岩石学等显示具钙碱性特征, (FeO/MgO)、K2 O/Na2O显示可能具有陆缘岛弧环境的特性;轻稀土元素分馏程度高且富集,δEu小于1,为弱负异常,稀土元素配分模式曲线与岛弧型稀土元素配分模式图相似;微量元素Rb、Ba、Th等元素明显富集,而Ti、Y、Yb、Sc、Cr等元素较亏损.Nb/Zr、La/Nb、Th/Ta、Th×Ta/Hf2等特征反映鄂拉山组火山岩产于陆缘火山弧环境.结合区域地质背景、岩石地球化学及构造环境等特征,认为鄂拉山地区晚三叠世火山岩产于大陆碰撞与陆缘弧并存的环境.     

南澜沧江结合带火山岩岩浆成因——洋脊洋岛与弧岩浆作用的性质

在对滇西南昌宁—孟连带石炭—二叠纪火山岩和南澜沧江带二叠—三叠纪火山岩的微量元素和稀土元素研究的基础上,划分了岩浆作用类型和岩浆演化系列,探讨了岩浆源区成分特点。昌宁—孟连带玄武质岩浆的演化主要受部分熔融和分离结晶作用控制;这些岩浆可以划分为３个岩浆演化系列：（１）稀土曲线平坦型的洋脊型拉斑玄武岩浆演化系列,其岩浆起源于亏损型地幔;（２）稀土曲线中等富集型的准洋脊型拉斑玄武岩浆演化系列,其岩浆起源于过渡型地幔;（３）稀土曲线强烈富集型的洋岛型碱性玄武岩浆演化系列,其岩浆起源于富集型地幔。南澜沧江带弧火山岩的岩浆成因主要受分离结晶作用控制,也可以划分为３个岩浆演化系列：（１）二叠纪低钾拉斑—中钾钙碱性岩浆演化系列;（２）中南段的晚三叠世低钾拉斑—中钾钙碱性岩浆演化系列;（３）北段的晚三叠世钾玄岩—高钾钙碱性岩浆演化系列     

山西吕梁地区吕梁群变基性火山岩原岩形成年龄、地球化学特征及形成环境

华北克拉通古元古代中期构造环境及演化至今尚存有争议,该时期相关岩浆作用的成因研究可为这些问题的解决提供重要证据。本文对华北克拉通中部山西吕梁地区古元古代中期形成的吕梁群近周营组基性火山岩开展综合研究,获得2 180±19 Ma 的形成年龄,岩石地球化学低TiO₂、高Al₂O₃ 和K₂O,属钙碱性系列。微量元素富集Rb、Ba、Th、U、Sr 等大离子亲石元素,亏损Nb、Ta、Ti 和P等高场强元素,富集Pb,具轻稀土略富集、铕弱异常的右倾稀土模式,与典型消减带弧岩浆产物特征一致。同位素组成显示正ε_Nd（t）= 1.0～2.6 和ε_Hf（t）= 1.8～9.2, 指示它们来源于亏损地幔,低的Ti/Y（246～385）和Ce/Y 值（0.99～1.77）进一步揭示,地幔源区受到俯冲流体的交代和沉积物的参与,是楔尖晶石二辉橄榄岩与石榴石二辉橄榄岩过渡带略亏损地幔区发生部分熔融,并经历了橄榄石、单斜辉石等矿物分离结晶作用而形成。结合同期埃达克岩-高镁安山岩-富Nb玄武岩-安山岩组合以及弧花岗岩类的出现提出,2 200 Ma 华北中部带已演化至活动大陆边缘弧的构造环境。     

西藏冈底斯带石炭纪陆缘裂陷作用：火山岩和地层学证据

冈底斯作为重要的中、新生代岛弧岩浆岩带,历来是青藏高原最热门的地质研究领域,但是对晚古生代火山岩的性质及其形成的构造背景仍缺乏研究。本文在区域地质调查资料的基础上,对冈底斯带石炭纪火山-沉积岩系进行了系统的地层学和岩石地球化学研究,测量了重点剖面,对火山岩进行了常量、微量元素和Sr、Nd、Pb同位素地球化学测试。研究表明,石炭系与下伏泥盆系或前寒武系之间普遍存在不整合或岩性、沉积相的突变面,代表重要的构造转换面。石炭纪的沉积环境大致有两次滨海-深海或深水斜坡-滨海沉积演化旋回,深海-深水斜坡沉积或冰海相含砾板岩与两次火山活动伴生。石炭纪火山岩主要为安山玄武岩和英安岩、流纹岩类,略具双峰式火山岩特点。安山玄武岩类的成分与典型MORB和岛弧玄武岩相比,具有MgO含量低,TiO2、Al2O3、P2O5含量高等特点,稀土和微量元素为LREE和LILE富集型分配模式,与大陆拉斑玄武岩相似。石炭纪酸性火山岩的稀土和微量元素地球化学特征与陆内流纹岩相似。岩石地球化学示踪和地层学研究表明,冈底斯带石炭纪为伸展背景下的冈瓦纳陆缘裂陷环境。火山岩的源区地幔具有典型的Dupal异常,发生过复杂的混合作用,涉及到原始地幔、富集地幔EMII和地壳成分等,说明发生过冈瓦纳古陆壳俯冲、再循环进入古老地幔等过程。玄武岩类成分的某些特殊性,可能与源区混合作用有关。     

东昆仑造山带诺木洪郭勒早古生代火山活动

诺木洪郭勒一带发育早古生代火山岩, 可明显分为2种类型: 一类为基性火山岩组合, 岩石主要为具枕状构造的玄武岩, SiO₂碱度均较低, 为拉斑系列玄武岩, 稀土、微量元素特征及构造环境判别显示其形成于洋中脊的构造环境; 另一类为中基性火山岩组合, 火山岩岩石类型复杂, 熔岩和火山碎屑岩均较发育, 熔岩成分从基性到中酸性均有, 火山岩SiO₂成分变化较大, 既有亚碱性, 又有碱性, 亚碱性系列岩石多属钙碱性系列.稀土、微量元素特征及构造环境判别其形成于火山弧的环境.      

内蒙古额济纳地区奥陶纪火山岩地球化学特征及其地质意义

内蒙古额济纳地区广泛出露的奥陶纪火山岩是中亚造山带南缘中段早古生代地质事件的重要响应,对研究及认识古亚洲洋的演化有着重要的启示.对内蒙古额济纳旗呼仍巴斯克地区咸水湖组火山岩与白云山组凝灰岩进行了岩石学、同位素年代学和全岩主、微量元素地球化学研究.结果显示:咸水湖组为一套基性-酸性熔岩及其同质的火山碎屑岩组合,白云山组凝灰岩为酸性凝灰岩;火山岩与凝灰岩皆属于亚碱性系列岩石,主要表现出钙碱性系列的演化趋势,具有富钙,富铝,贫镁,较大的TFeO/MgO比值的特征,稀土元素配分曲线呈右倾斜型,同时富集大离子亲石元素（LILE）和轻稀土元素（LREE）,亏损高场强元素（HFSE）;咸水湖组流纹岩样品的SHRIMP锆石U-Pb同位素谐和年龄为462±3 Ma（MSWD=1.6）,显示其形成时代为中奥陶世晚期.通过分析比对认为,不同于其西部希热哈达、伊哈托里等地区的岛弧环境,额济纳旗呼仍巴斯克地区奥陶纪火山岩形成于陆缘弧构造背景,揭示了中-晚奥陶世蒙古国境内Zoolen大洋向内蒙古额济纳地区明水-旱山陆块北缘俯冲作用的存在.      

Geology and geochemistry of the Neoproterozoic Tuludimtu Ophiolite suite,western Ethiopia

The Kemashi Domain, a lithotectonic subdivision of the Neoproterozoic Tuludimtu Orogenic Belt of western Ethiopia, consists of a suite of mafic–ultramafic volcanic and plutonic rocks, and interbedded deep marine sediments, mainly graphite-bearing pelitic schists and phyllites, and graphitic quartzites and cherts. Pillow structures indicate submarine extrusion of the volcanics, whilst partings within some of the basalts may represent sheeted dykes. An associated mélange unit, composed of blocks of the same rock types as above, set in a fine schistose matrix, also occurs. This assemblage is interpreted as a dismembered ophiolite—the Tuludimtu Ophiolite—formed in a deep oceanic environment. A turbiditic sequence is also present in the domain.The Tuludimtu Ophiolite underwent intense compression during the Neoproterozoic Pan African Orogeny, resulting in early recumbent folding and westwards-directed thrusting, followed by reactivation of steeper zones of the thrusts as N–S orogen-parallel strike-slip shear zones, accompanied by refolding of early folds into upright horizontal folds. This was followed by development of deep crustal NNW–SSE orogen-transecting shear zones, which were reactivated as brittle faults during orogenic collapse of the Tuludimtu Belt. Metamorphism to lower greenschist facies grade accompanied orogenesis.Major, trace and REE geochemistry of volcanic and some plutonic igneous rocks, has been employed to define the tectonic setting of the terrane. Tectonic discrimination diagrams, utilising REE and HFSE, indicate a wide distribution spectrum but with the majority of samples plotting in arc basalt and MORB fields, suggesting derivation from sources similar to N-MORB and depleted MORB (typical of many arc basalts). Most of the samples exhibit a slight depletion of immobile elements, relative to N-MORB values and also show depletion of Zr, Ti, Nb and Y, implying that their source had been depleted by an earlier melting episode. Overall, the geochemistry typifies spreading centre basalts with some compositional features transitional to those of arc basalts, a characteristic of back-arc basalts.Lithological association, structural style and geochemistry of the rock assemblage in the Kemashi Domain thus define an ophiolite interpreted to have formed within a deep marine environment. This is thought to have been due to rifting of continental crust within a back-arc basin regime in a continental margin type extensional setting. Comparison with other ophiolitic terranes within the Arabian Nubian Shield, suggests that many of these terranes may represent back-arc basin type tectonic settings, similar to the Kemashi Domain. This supports the multi-stage accretion model for closure of the Mozambique Ocean, for which the Pacific Ocean may be a present day analogue.