Geology, Geochemistry and Minerogenesis of the Shijuligou Zinc–Copper Deposit in Gansu, China

Abstract: The Shijuligou deposit was separated by an arcuate ductile shear zone cross the center of the deposit region, resulting in the difference between the southern and northern ore bodies. The lead (Pb) isotopic data of ores of the Shijuligou copper deposit have averages of 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb in 17.634, 15.444, and 37.312, respectively. It has been shown that ore-forming metals originated from intrusive and extrusive rocks in the upper part of ophiolites. The sulfur isotopic data of pyrite and chalcopyrite in the northern part change from +7.61‰ to +8.09‰ and +4.95‰ to +8.88‰ in the southern part. Isotopes of δ18O in the Shijuligou copper deposit are between +11.1‰ and +18.6‰, with the calculated δ18OH2O at +0.65‰. It is suggested that the mineralized fluid is a mixture of magma fluid, meteorological water, and seawater through circulating and leaching metals from the volcanic rocks. The zircon uranium-lead (U–Pb) dating of gabbro is 457.9±1.2 Ma, and the lower crossing age of the discordant and concordia curves of pyroxene spilite of zircon is 454±15 Ma. It is indicated that the Shijuligou deposit formed in a new ocean crust (ophiolite) of the back-arc basin in the late Ordovician. Mineralization should occur in the intermittence period after strong volcanic activity, and the age should be the late Ordovician. Moreover, the mineralization of ophiolite-hosted massive sulfide deposits in the ancient orogenic belt of the late Ordovician in the northern Qilian Mountains was controlled by the primary fault/fracture, with the forming of a metallogenic hydrothermal system by a mixture of volcanic magma fluid and seawater, which circularly leached the metallogenic metals from the volcanic rocks, resulting in their accumulation. The ore bodies were transformed with morphology and metallogenic elements. Jasperoid is an important sign for prospecting such deposits. There were many island arcs in the continent of China. This study provides evidence for understanding and exploration of ophiolite-hosted massive sulfide deposits in western China, especially in the area of northern Qilian Mountains.     

昆仑古特提斯构造转换与镍钴锰锂关键矿产成矿作用研究

【研究目的】 特提斯构造域研究愈来愈显示为原特提斯、古特提斯和新特提斯三分的特点,其中古特提斯洋的形成演化及其成矿作用的研究较为薄弱。【研究方法】 本文根据东昆仑夏日哈木早泥盆世超大型镍钴硫化物矿床、帕米尔玛尔坎苏晚石炭世大型火山源沉积型富锰矿和西昆仑大红柳滩晚三叠世大型伟晶岩型锂铍矿床发现事实,将它们成矿的构造地质背景演化作为主线关联起来研究,提出它们分别代表了古特提斯裂解、大洋扩张和闭合后碰撞构造转换结果的认识。【研究结果】 认为与古亚洲洋同期的原特提斯洋于志留纪末碰撞闭合后,在冈瓦纳大陆北缘由于地幔柱作用改造的软流圈发生部分熔融而裂解,形成了以夏日哈木与裂解背景幔源镁铁—超镁铁岩有关的超大型岩浆镍钴硫化物矿床;随着进一步扩张,在早石炭世形成了古特提斯成熟大洋,由于大洋中脊喷发提供的成矿物质,在晚石炭纪随着大洋快速扩张向消减的转换,洋底碳酸盐岩沉积中形成了玛尔坎苏大型富菱锰矿矿床;古特提斯洋闭合后于中三叠世进入碰撞造山阶段,于晚三叠世后碰撞阶段地壳重熔形成的S型花岗岩高温热液流体,并造就了大红柳滩大型伟晶岩型锂铍矿床。早晚古生代之交是古特提斯洋裂解的开始,此时秦祁昆洋为代表的原特提斯主洋已经闭合,作为原特提斯洋弧后盆地的古亚洲洋尽管尚未闭合,但夏日哈木镍钴矿床则是原特提斯造山后陆壳再次裂解的产物,并非形成于原特提斯洋岛弧或后碰撞的环境;锰是亲石元素,岩浆作用中不富集,而在外生沉积作用中富集,说明古特提斯早石炭世新生洋壳是富锰的,淋滤出的锰离子在晚石炭世相对宁静洋底深处碱性环境中形成沉积型碳酸锰矿,代表了较为强烈的岩浆作用阶段向相对宁静的沉积环境的转换;大红柳滩S型花岗岩基及其大规模伟晶岩型锂铍矿的产出,则反映了强烈的碰撞造山作用导致的地壳重熔的地球动力学背景,应是古特提斯洋缝合造山后或后碰撞伸展的环境。【结论】 就已有的成矿事实,东昆仑康西瓦—阿尼玛卿古特提斯缝合带与南部巴颜喀拉的西金乌兰—金沙江和羌塘的龙木错—双湖古特提斯缝合带相比,更富有地质意义。     

The Sequence Architecture of Volcanic Basin Fillings- An Example From Xujiaweizi Faulted Depression In Songliao Basin

The basin filling geometric pattern of volcanic eruptive rocks depends on both of the eruptive locations in a basin and structural styles of fault terraces. It is divided into three types by eruptive locations and occurrences of eruptive rocks, including the pattern of eruption along fault and occurrence (PEAFO), the pattern of eruption on footwall of a fault and occurrence (PEOFO) and the pattern of eruption on hangingwall of fault and occurrence (PEOHO) in Xujiaweizi fault depression of Songliao basin, Northeast of China. Those basin filling patterns of volcanic eruptive rocks are of specific geometric characteristics controlling or affecting sedimentation, geometry of sedimentary body and sequence architecture during a sequence evolution. The study shows that the volcanic rocks developed at different stages of lowstand, transgressive and highstand can give different controls or affects on the sequence architecture.     

新疆北部晚古生代大规模岩浆成矿的地球动力学背景和战略找矿远景

新疆北部石炭-二叠纪存在大规模岩浆成矿作用,但对成矿地球动力学机制缺乏系统认识。在前人工作和我们近年来工作的基础上,文中扼要总结了我们新的初步认识,旨在为深化研究奠定思想基础。文中指出新疆北部泥盆-石炭纪岩浆活动和成矿作用是板块构造的直接产物。石炭纪的板块消减及有关的岩浆作用可能一直持续到三叠纪。地幔柱岩浆作用的起始时间不详,可能在晚石炭世,但集中表现在二叠纪。两种岩浆构造体系在时间上的叠加和空间上的并存造就了成矿作用的集中爆发以及成矿类型上的时空变化。与之有关的成矿作用和相应的成矿类型主要有：赋存于晚泥盆世-早石炭世海相火山岩中的磁铁矿床（有火山岩浆喷溢成因的可能,但更具有夕卡岩型铁矿的特征）、泥盆纪末到早三叠世与中酸性侵入岩有关的斑岩型（夕卡岩型）铜（钼）矿床以及早二叠世与镁铁超镁铁质侵入岩有关的岩浆铜镍硫化物矿床。后者与南疆塔里木盆地已知溢流玄武岩在时代上（（280±5）Ma）的一致性意味着包括该溢流玄武岩的基性大火成岩省可能分布很广泛,波及北疆的相当地域。如这一推论能够证实,那么与之有成因联系的钒钛磁铁矿和铜镍硫化物矿化点/矿床的分布就不应只局限于已知造山带,应该分布更广。这里造山带的“成矿专属性”很有可能只是构造暴露而已。这一思路有助于我们研究新疆北部晚古生代岩浆成矿作用以及与岩浆作用有关的成矿作用,并对寻找同类矿床有战略指导意义。     

Discussion and reassessment of the method used for accepting or rejecting data observed by a Bowen ratio system

The Bowen ratio energy balance method often produces extremely inaccurate magnitudes of the flux due to resolution limits of the instruments. We analysed the criteria used for rejecting inaccurate data observed using a Bowen ratio system and the resolution limit of the sensors to analytically determine the reliable values of the Bowen ratio (β) and the latent and sensible heat fluxes. The formula used to calculate the error limit of the Bowen ratio (β) was corrected based on the theory of error analysis. An example was proposed for the common case with 0.2 °C resolution limit of temperature measurement and 0.08 kP_a resolution limit of water vapour pressure measurement, to show the steps of accepting or rejecting data observed by a Bowen ratio system. The acceptance or rejection of data observed by a Bowen ratio system is a dynamic process, which should be performed based on the excluded interval of the Bowen ratio and the qualitative relationships among the data observed by a Bowen ratio system. The excluded interval of the Bowen ratio can be structured based on the accuracy of the sensors used. Data are excluded first if they do not satisfy the qualitative relationships between the vapour pressure difference, the temperature difference, Bowen ratio, and the available energy, whereas the data in the rejection region range of the Bowen ratio are excluded second. It is necessary to improve the accuracy of the temperature and humidity probes to improve the acceptance rate for data collected using the Bowen ratio system, apart from improving the observed precision of available energy. Copyright © 2013 John Wiley & Sons, Ltd.     

东秦岭杨斜金矿区石英闪长玢岩锆石U-Pb年代学、地球化学特征及地质意义

杨斜中型金矿床是东秦岭杨斜-丰北河地区典型的石英脉型金矿床,成矿与区内石英闪长玢岩密切相关,具中高温蚀变特征及矿物组成。LA-ICP-MS锆石U-Pb测年结果表明,石英闪长玢岩锆石²⁰⁶Pb/²³⁸U加权平均年龄为149.5±2.7 Ma,谐和年龄为149.5±2.1 Ma,属晚侏罗世。岩石地球化学研究显示,石英闪长玢岩具有高SiO₂(65.53%~65.76%)、高Al₂O₃(15.65%~15.87%)、富碱(N₂O+K₂O=8.07%~8.30%)及贫MgO(1.37%~1.40%)特征,属于高钾钙碱性准铝质系列岩石;相对富集Rb、Ba、K、Pb、Sr等大离子亲石元素和LREE,亏损Nb、Ta、Ti等高场强元素和HREE;其高Sr、高Sr/Y、低Y和低Yb值及正Eu异常等特征参数,与典型埃达克质岩一致,岩浆应起源于加厚下地壳的部分熔融。综合研究认为,杨斜金矿属岩浆期后热液型金矿床,成岩成矿时代一致,形成于秦岭造山带晚侏罗世-早白垩世陆内俯冲向伸展转换的构造环境。     

基于FlowCam影像和YOLOv3深度学习模型的多纹膝沟藻检测

海洋中的有害藻华,包括微藻形成的赤潮和褐潮以及大型藻类形成的绿潮和金潮,已成为一类突出的海洋生态灾害问题。2021年11—12月,山东半岛东北部海域发生多纹膝沟藻(Gonyaulax polygramma)形成的大规模赤潮,导致海带养殖严重受损,亟待构建有针对性的赤潮监测预警体系。本文以多纹膝沟藻为对象,尝试应用流式影像仪(FlowCam)结合卷积神经网络模型YOLOv3,分别对含有多纹膝沟藻的浓缩海水样品、含有多纹膝沟藻和链状亚历山大藻(Alexandrium catenella)的浓缩海水样品,以及含有多纹膝沟藻活细胞及空壳的浓缩海水样品进行了检测实验,探究了基于藻种影像的深度学习模型在赤潮原因种检测方面的应用潜力。结果表明,在以FlowCam获取的影像数据集训练3万次后,YOLOv3对多纹膝沟藻表现出较好的识别能力,对浓缩海水样品中目标藻种识别的平均精度为88.2%;当样品中存在与多纹膝沟藻形态相似的链状亚历山大藻时,模型对多纹膝沟藻识别的平均精度下降为76.6%,对两种微藻同时进行训练和检测,可将对多纹膝沟藻识别的平均精度提高至84.6%。对于低温下出现脱壳现象的多纹膝沟藻,模型对海水中活细胞识别的平均精度为86.7%,对空壳识别的平均精度87.8%,将多纹膝沟藻活细胞与空壳分别识别的平均精度均值(87.3%)高于将两者统一作为多纹膝沟藻进行检测的识别精度(84.2%),整体识别精度提升3.1%。综合相关结果可以看出,FlowCam与深度学习模型相结合在赤潮监测和研究中具有重要应用潜力。     

福建省近海海底麻坑的地貌特征及其与海洋工程的联动效应

为科学开发利用海洋资源、防范海底地质灾害和保护生态环境,文章梳理福建省近海海底麻坑的类型和成因,并分析海洋工程与灾害性地貌的联动效应。研究结果表明:受板块挤压和海平面波动等的影响,福建省近海海底地形和沉积环境复杂多变,流体活动形成的海底麻坑主要包括单元麻坑、圆形麻坑、拉长形麻坑、链状麻坑和复合麻坑5种类型,在北部泥质区、南部砂质区、河口区和海湾区有不同分布,其成因主要包括海相生物气、生物气和海陆生物混合热解气;应高度重视海洋工程与海底麻坑等灾害性地貌的联动效应,避免发生海底地质灾害和破坏海洋生态环境。     

中国锰矿资源特征及潜力预测

中国的锰矿资源丰富,截止到2016年,保有储量达15.5亿t,位居世界第六位。中国锰矿主要集中分布在南方的泛扬子古陆、北部的燕辽、西部的天山和祁连山等地区。中新元古代、早古生代（寒武纪、奥陶纪）、晚古生代-早中生代是中国锰矿形成的重要时代。在锰矿成矿规律研究的基础上,提出了如下方案：（1）以成矿作用作为一级分类要素,含矿岩系作为二级分类要素的8种成因类型划分方案;（2）根据锰资源潜力评价工作需要,将成因类型和工业类型相结合,以成矿作用和预测要素为一级要素,含矿岩系为二级要素的3种预测类型划分方案。其中,海相沉积型、风化壳型和古天然气渗漏沉积型锰矿是中国具有找矿潜力的主要锰矿床类型。基于此,将全国锰矿划分为11个Ⅲ级锰矿成矿带,对优选出的7个主要锰矿远景区的含锰层位、成矿特征、主攻类型、资源潜力进行了分析。最后,针对目前中国锰矿资源面临的问题,提出了下一步工作部署的建议和意见。     

澜沧5.9,6.7级强余震前后的重力变化

1988年11月6日澜沧——耿马地震后,使用2台Worden重力仪在7.6级地震震中附近的大塘乡下扎二进行了定点场地重力测量,本文对这次重力测量的结果进行了初步分析,认为观测期间在竹塘附近发生的二次强余震(11月27日,M=5.9,11月30日,M=6.7),震前引起了约30×10~(-8)ms~(-2)的重力变化,并且认为这二次强余震的孕育过程可以用DD模式来进行解释,据此初步估算这二次强余震之前的最大应力值约4×10~7达因/厘米~2,应变值约4×10~(-5),震源体的隆起约12厘米。