Carboxylic monoacids in the air of mayombe forest (Congo): Role of the forest as a source or sink

In the tropical rain forests of the Congo during the dry season, from June to September 1987, carboxylic acid partial pressures (P _gas) in the air above the canopy, at ground level, and at the boundary layer, were estimated from water samples such as fog and rainwater. The concentrations of these acids were also measured in the sap of tree leaves. Tree leaves act as a sink or as a source if the acid P _gas is greater of lower than the acid concentrations in molecular form in sap. For each of these soluble gases, there is a value of P _gas where the exchange is nul. This is called the compensation point. Values of the compensation point for some tree leaves were evaluated according to Henry's law. Henry's law coefficients at ppm levels were redetermined for formic (HCOOH), acetic (CH₃COOH), propionic (CH₃CH₂COOH), and isobutyric (CH₃CH(CH₃)COOH) acids.By comparison of P _gas and compensation points, it is concluded that the forest was a potential source for these acids. The soil-or the litter-acts as a significant source of a carboxylic acid of C₃ or C₄ atoms in the aliphatic chain. This carboxylic acid, not yet fully characterized, could play an important role in the rain acidity in forested zones of the equatorial areas.The direct emission of these carboxylic acids by vegetation was the main source in the boundary layer above the forest. The average emissions were 3.1×10⁹, 7.8×10⁹, and 8.4×10⁹ molecules cm^-2 s^-1 for HCOOH, CH₃COOH, and CH₃CH₂COOH, respectively. The savanna is an exogenous source of HCOOH and CH₃CH₂COOH during moderately rainy days for 30% of the time. The ozonolysis of isoprene seems to be a small source of HCOOH.     

Seasonal Variability of Carbon Dioxide in the Rivers and Lagoons of Ivory Coast (West Africa)

We report partial pressure of CO₂ (pCO₂) and ancillary data in three rivers (Bia, Tanoé, and Comoé) and five lagoons (Tendo, Aby, Ebrié, Potou, and Grand-Lahou) in Ivory Coast (West Africa), during four cruises covering the main climatic seasons. The three rivers were oversaturated in CO₂ with respect to atmospheric equilibrium, and the seasonal variability of pCO₂ was due to dilution during the flooding period. Surface waters of the Potou, Ebrié, and Grand-Lahou lagoons were oversaturated in CO₂ during all seasons. These lagoons behaved similarly to the oligohaline regions of macrotidal estuaries that are CO₂ sources to the atmosphere due to net ecosystem heterotrophy and inputs of riverine CO₂ rich waters. The Aby and Tendo lagoons were undersaturated in CO₂ with respect to the atmosphere because of their permanent haline stratification (unlike the other lagoons) that seemed to lead to higher phytoplankton production and export of organic carbon below the pycnocline.     

Comparative phylogeography of African rain forest trees: A review of genetic signatures of vegetation history in the Guineo-Congolian region

The biogeographic history of the African rain forests has been contentious. Phylogeography, the study of the geographic distribution of genetic lineages within species, can highlight the signatures of historical events affecting the demography and distribution of species (i.e. population fragmentation or size changes, range expansion/contraction) and, thereby, the ecosystems they belong to. The accumulation of recent data for African rain forests now enables a first biogeographic synthesis for the region. In this review, we explain which phylogeographic patterns are expected under different scenarios of past demographic change, and we give an overview of the patterns detected in African rain forest trees to discuss whether they support alternative hypotheses regarding the history of the African rain forest cover. The major genetic discontinuities in the region support the role of refugia during climatic oscillations, though not necessarily following the classically proposed scenarios. We identify in particular a genetic split between the North and the South of the Lower Guinean region. Finally we provide some perspectives for future study.     

Interactions of mercury with different molecular weight fractions of humic substances in aquatic systems

Interactions of mercury (Hg) with different molecular weight fractions of humic substances (HS) play an important role in controlling distribution, diffusion, speciation, and bioavailability of Hg in natural systems. This study suggests that Hg prefers to associate with higher molecular weight fractions of HS and this association particularly predominates at low pH and high ionic strengths of the medium. The concentrations of aggregated HS (with higher molecular weight) become high at lower pH (acidic condition) and high ionic strength. Molecular weight of HS gradually decreases with the increasing pH (basic condition) and low ionic strength of the medium. The disaggregation property of HS which involves the release of monomers from the surface of the aggregates produces HSs of different intermediate molecular weight with different Hg complexing capacity. Distribution of Hg in different molecular weight fractions of HS is dependent on aggregational and disaggregational properties of HS in aquatic medium. Association of Hg with high molecular weight fraction of HS may alter distribution and bioavailability of Hg in a system as the bioreactivity of organic matter decrease along a continuum of size in aquatic medium.     

Projected changes in extreme precipitation intensity and dry spell length in Côte d’Ivoire under future climates

This study analyzes projected changes in seasonal extreme precipitation intensity and dry spell length in the investigation area (Côte d’Ivoire) under RCP4.5 and RCP8.5 forcing scenarios. To this end, a multi-model ensemble of fourteen CORDEX-Africa regional climate model simulations is used during the three stages of the West African Monsoon (WAM) season (April–June (AMJ), July–September (JAS), and October–December (OND)). The results indicate that Côte d’Ivoire is subject to a robust increase of cumulative intensity of precipitation associated with an amplification of extreme precipitation events during the WAM. In particular during JAS, a substantial increase in extreme precipitation reaching up to 50–60% compared to the reference mean value prevails in the western and coastal areas in the far future and under the RCP8.5 scenario. In addition, AMJ season is dominated by an increase in dry spell length of about 12% and 17% in the near future and 20% and 30% in the far future in the entire country under RCP4.5 and RCP8.5 scenarios, respectively, albeit considerable uncertainties. OND considered as the post-monsoon season is mostly characterized by a robust decrease in dry spell length more marked in the southwest in the RCP8.5 scenario during the far future. These results suggest that agricultural production and particularly cocoa plantations in the southwestern regions could be at the risk of flooding events and that water stress remains a threat for cocoa, coffee, and other cash crop plantations in the eastern regions.     

Estimates of snow accumulation and volume in the Swiss Alps under changing climatic conditions

Summary ¶Snow is a key feature of mountain environments in terms of the controls it exerts on hydrology, vegetation, and in terms of its economic significance (e.g. for the ski industry). Its quantification in a changing climate is thus important for various environmental and economic impact assessments. Based on observational analysis, surface energy balance modeling, and the latest data from high-resolution regional climate models, this paper investigates the possible changes in snow volume and seasonality in the Swiss Alps. An average warming of 4°C as projected for the period 2071–2100 with respect to current climate suggests that snow volume in the Alps may respond by reductions of at least 90% at altitudes close to 1000m, by 50% at 2000m, and 35% at 3000m. In addition, the duration of snow cover is sharply reduced in the warmer climate, with a termination of the season 50–60 days earlier at high elevations above 2000–2500m and 110–130 days earlier at medium elevation sites close to the 1000m altitude. The shortening of the snow season concerns more the end (spring) rather than the beginning (autumn), so that it should be expected that snow melt will intervene much earlier in the season than under current conditions. The results of this study are of relevance to the estimations of the impacts that the projected warming may have on the amount and timing of water in hydrological basins, on the start of the vegetation season, and on the financial status of many mountain resorts.     

Geochemical Processes Controlling the Formation of As-Rich Waters Within a Tailings Impoundment (Carnoulès, France)

The distribution of arsenic (As(III), As(V)) and iron (Fe(II), Fe(III)) species was monitored during 1 year in a borehole drilled in the Carnoulès tailings impoundment which contains As-rich pyrite. The concentrations of total As and Fe in subsurface waters exhibited strong variations over one year, which were controlled by dissolved oxygen concentrations. At high oxygen levels, extremely high As (up to 162 mM) and Fe (up to 364 mM) concentrations were reached in the borehole, with the oxidised species predominant. As and Fe concentrations decreased 10-fold under oxygen-deficient conditions, as a result of pH increase and subsequent precipitation of As(V) and Fe(III). From drill core sections, it appeared that at low dissolved oxygen levels, As(III) was primarily released into water by the oxidation of As-rich pyrite in the unsaturated zone. Subsequent As and Fe precipitation was promoted during transport to the saturated zone; this reaction resulted in As enrichments in the sediment below the water table compared to the original content in pyrite, together with the formation of As-rich (up to 35 wt% As) ferruginous material in the unsaturated zone. High amounts of As(V) were released from these secondary phases during leaching experiments with oxygenated acid sulfate-rich waters; this process is believed to contribute to As(V) enrichment in the subsurface waters of the Carnoulès tailings during periods of high dissolved oxygen level.     

Future extreme events in European climate: an exploration of regional climate model projections

This paper compares how well satellite versus weather station measurements of climate predict agricultural performance in Brazil, India, and the United States. Although weather stations give accurate measures of ground conditions, they entail sporadic observations that require interpolation where observations are missing. In contrast, satellites have trouble measuring some ground phenomenon such as precipitation but they provide complete spatial coverage of various parameters over a landscape. The satellite temperature measurements slightly outperform the interpolated ground station data but the precipitation ground measurements generally outperform the satellite surface wetness index. In India, the surface wetness index outperforms station precipitation but this may be reflecting irrigation, not climate. The results suggest that satellites provide promising measures of temperature but that ground station data may still be preferred for measuring precipitation in rural settings.     

Recent climatic trends in the tropical Atlantic

A homogeneous monthly data set of sea surface temperature (SST) and pseudo wind stress based on in situ observations is used to investigate the climatic trends over the tropical Atlantic during the last five decades (1964–2012). After a decrease of SST by about 1 °C during 1964–1975, most apparent in the northern tropical region, the entire tropical basin warmed up. That warming was the most substantial (>1 °C) in the eastern tropical ocean and in the longitudinal band of the intertropical convergence zone. Surprisingly, the trade wind system also strengthened over the peirod 1964–2012. Complementary information extracted from other observational data sources confirms the simultaneity of SST warming and the strengthening of the surface winds. Examining data sets of surface heat flux during the last few decades for the same region, we find that the SST warming was not a consequence of atmospheric heat flux forcing. Conversely, we suggest that long-term SST warming drives changes in atmosphere parameters at the sea surface, most notably an increase in latent heat flux, and that an acceleration of the hydrological cycle induces a strengthening of the trade winds and an acceleration of the Hadley circulation. These trends are also accompanied by rising sea levels and upper ocean heat content over similar multi-decadal time scales in the tropical Atlantic. Though more work is needed to fully understand these long term trends, especially what happens from the mid-1970’s, it is likely that changes in ocean circulation involving some combination of the Atlantic meridional overtuning circulation and the subtropical cells are required to explain the observations.