Shocked quartz in polymict impact breccia from the Upper Cretaceous Yallalie impact structure in Western Australia

Yallalie is a ~12 km diameter circular structure located ~200 km north of Perth, Australia. Previous studies have proposed that the buried structure is a complex impact crater based on geophysical data. Allochthonous breccia exposed near the structure has previously been interpreted as proximal impact ejecta; however, no diagnostic indicators of shock metamorphism have been found. Here we report multiple (27) shocked quartz grains containing planar fractures (PFs) and planar deformation features (PDFs) in the breccia. The PFs occur in up to five sets per grain, while the PDFs occur in up to four sets per grain. Universal stage measurements of all 27 shocked quartz grains confirms that the planar microstructures occur in known crystallographic orientations in quartz corresponding to shock compression from 5 to 20 GPa. Proximity to the buried structure (~4 km) and occurrence of shocked quartz indicates that the breccia represents either primary or reworked ejecta. Ejecta distribution simulated using iSALE hydrocode predicts the same distribution of shock levels at the site as those found in the breccia, which supports a primary ejecta interpretation, although local reworking cannot be excluded. The Yallalie impact event is stratigraphically constrained to have occurred in the interval from 89.8 to 83.6 Ma based on the occurrence of Coniacian clasts in the breccia and undisturbed overlying Santonian to Campanian sedimentary rocks. Yallalie is thus the first confirmed Upper Cretaceous impact structure in Australia.     

Regional modelling of rainfall-induced runoff using hydrological model by incorporating plant cover effects: case study in Kelantan,Malaysia

The objective of this paper is to develop a spatial temporal runoff modelling of local rainfall patterns effect on the plant cover hilly lands in Kelantan River Basin. Rainfall interception loss based on leaf area index, loss/infiltration on the ground surface, and runoff calculation were considered as the main plant cover effects on the runoff volume. In this regard, a hydrological and geotechnical grid-based regional model (integrated model) was performed using Microsoft Excel^® and GIS framework system for deterministic modelling of rainfall-induced runoff by incorporating plant cover effects. The infiltration process of the current model was integrated with the precipitation distribution method and rainfall interception approach while the runoff analysis of integrated model was employed based on loss/infiltration water on the ground surface with consideration of water interception loss by canopy and the remaining surface water. In the following, the spatial temporal analysis of rainfall-induced runoff was performed using 10 days of hourly rainfall events at the end of December 2014 in Kelantan River Basin. The corresponding changes in pressure head and consequent rate of infiltration were calculated during rainfall events. Subsequently, flood volume is computed using local rainfall patterns, along with water interception loss and the remaining surface water in the study area. The results showed the land cover changes caused significant differences in hydrological response to surface water. The increase in runoff volume of the Kelantan River Basin is as a function of deforestation and urbanization, especially converting the forest area to agricultural land (i.e. rubber and mixed agriculture).     

Sedimentology of the continental end‐Permian extinction event in the Sydney Basin,eastern Australia

Upper Permian to Lower Triassic coastal plain successions of the Sydney Basin in eastern Australia have been investigated in outcrop and continuous drillcores. The purpose of the investigation is to provide an assessment of palaeoenvironmental change at high southern palaeolatitudes in a continental margin context for the late Permian (Lopingian), across the end‐Permian Extinction interval, and into the Early Triassic. These basins were affected by explosive volcanic eruptions during the late Permian and, to a much lesser extent, during the Early Triassic, allowing high‐resolution age determination on the numerous tuff horizons. Palaeobotanical and radiogenic isotope data indicate that the end‐Permian Extinction occurs at the top of the uppermost coal bed, and the Permo‐Triassic boundary either within an immediately overlying mudrock succession or within a succeeding channel sandstone body, depending on locality due to lateral variation. Late Permian depositional environments were initially (during the Wuchiapingian) shallow marine and deltaic, but coastal plain fluvial environments with extensive coal‐forming mires became progressively established during the early late Permian, reflected in numerous preserved coal seams. The fluvial style of coastal plain channel deposits varies geographically. However, apart from the loss of peat‐forming mires, no significant long‐term change in depositional style (grain size, sediment‐body architecture, or sediment dispersal direction) was noted across the end‐Permian Extinction (pinpointed by turnover of the palaeoflora). There is no evidence for immediate aridification across the boundary despite a loss of coal from these successions. Rather, the end‐Permian Extinction marks the base of a long‐term, progressive trend towards better‐drained alluvial conditions into the Early Triassic. Indeed, the floral turnover was immediately followed by a flooding event in basinal depocentres, following which fluvial systems similar to those active prior to the end‐Permian Extinction were re‐established. The age of the floral extinction is constrained to 252.54 ± 0.08 to 252.10 ± 0.06 Ma by a suite of new Chemical Abrasion Isotope Dilution Thermal Ionization Mass Spectrometry U‐Pb ages on zircon grains. Another new age indicates that the return to fluvial sedimentation similar to that before the end‐Permian Extinction occurred in the basal Triassic (prior to 251.51 ± 0.14 Ma). The character of the surface separating coal‐bearing pre‐end‐Permian Extinction from coal‐barren post‐end‐Permian Extinction strata varies across the basins. In basin‐central locations, the contact varies from disconformable, where a fluvial channel body has cut down to the level of the top coal, to conformable where the top coal is overlain by mudrocks and interbedded sandstone–siltstone facies. In basin‐marginal locations, however, the contact is a pronounced erosional disconformity with coarse‐grained alluvial facies overlying older Permian rocks. There is no evidence that the contact is everywhere a disconformity or unconformity.     

Flotation Separation of Trace Elements from Alkaline-Earth Matrices by Co(III) Hexamethylenedithiocarbamate before ICP-AES Determination

A method for the selective separation of Ag, Cd, Cr, Cu, Ni, Pb and Zn in traces from solutions of calcite (CaCO₃), dolomite (CaMg(CO₃)₂) and gypsum (CaSO₄.2H₂O) before their determination by inductively coupled plasma-atomic emission spectrometry (ICP-AES) is presented. The expected interferences of Ca and Mg on intensities of trace analytes were removed by collecting the elements of interest with cobalt(III) hexamethylenedithiocar-bamate, Co(HMDTC)₃. The flotation of aqueous solutions (1 l) of calcite, dolomite and gypsum was performed at pH 6.0, by 1.5 mg l⁻¹ Co and 0.6 mmol l⁻¹ HMDTC⁻. To minimise the effect of the reaction between Ca/Mg, which restrains the function of the surfactant, careful selection of the most suitable foaming reagent was necessary. The accuracy of the method was established by analysing natural alkaline-earth minerals by the standard addition method as well as using the dolomite reference materials GBW 07114 and GSJ JDo-1. The ICP-AES limits of detection following flotation on different minerals were found to be 0.080 μg g⁻¹ for Cd, 0.105 μg g⁻¹ for Ag, 0.142 μg g⁻¹ for Cu, 0.195 μg g⁻¹ for Cr, 0.212 μg g⁻¹ for Ni, 0.235 μg g⁻¹ for Zn and 0.450 μg g⁻¹ for Pb.     

Conjunctive use of surface water and groundwater via the bank infiltration method

The bank infiltration (BI) technique may be a viable option if the local climate, hydrological, and geological conditions are conducive. This study was specifically conducted to explore the possibility of using BI to source the polluted surface water in conjunction with groundwater. Three major factors were considered for evaluation: (1) investigation on the contribution of surface water through BI, (2) input of local groundwater, and (3) water quality characteristics of water supply. Initially, the geophysical method was employed to define the subsurface geology and hydrogeology, and isotope techniques were performed to identify the source of groundwater recharge and interaction between surface water and groundwater. The physicochemical and microbiological parameters of the local surface water bodies and groundwater were analyzed before and during water abstraction. Extracted water revealed a 5 %–98 % decrease in turbidity, as well as HCO₃ ⁺, SO₄ ^?, NO₃ ^?, Al, As, and Ca concentration reduction compared with those of Langat river water. However, water samples from test wells during pumping show high concentrations of Fe²⁺ and Mn²⁺. In addition, amounts of Escherichia coli, total coliform, and Giardia were significantly reduced (99.9 %). Pumping test results indicate that the two wells (DW1 and DW2) were able to sustain yields.     

Cost-effectiveness of the Baltic Sea Action Plan

The governments around the Baltic Sea have agreed on a new set of targets for nutrient load reductions. The major motive for this is new and better knowledge about the link between nutrient loads and water transparency in different parts of the sea. The Baltic Sea Action Plan (BSAP) defines target for transparency in different marine basins, the load reductions necessary to meet transparency targets and a scheme for the distribution of the abatement burden between countries adjacent to the sea.     

An upgraded version of the Eta model

Upgrades implemented over a number of years in an open source version of the Eta model, posted at the CPTEC web site http://etamodel.cptec.inpe.br/, are summarized and examples of benefits are shown. The version originates from the NCEP’s Workstation Eta code posted on the NCEP web site http://www.emc.ncep.noaa.gov/mmb/wrkstn_eta, which differs from the NCEP’s latest operational Eta by having the WRF-NMM nonhydrostatic option included. Most of the upgrades made resulted from attention paid to less than satisfactory performance noted in several Eta results, and identification of the reasons for the problem. Others came from simple expectation that including a feature that is physically justified but is missing in the code should help. The most notable of the upgrades are the introduction of the so-called sloping steps, or discretized shaved cells topography; piecewise-linear finite-volume vertical advection of dynamic variables; vapor and hydrometeor loading in the hydrostatic equation, and changes aimed at refining the convection schemes available in the Eta. Several other modifications have to do with the calculation of exchange coefficients, conservation in the vertical diffusion, and diagnostic calculation of 10-m winds. Several examples showing improved performance resulting from the dynamics changes are given. One includes a case of unrealistically low temperatures in several mountain basins generated by a centered vertical advection difference scheme’s unphysical advection from below ground, removed by its replacement with a finite-volume scheme. Another is that of increased katabatic winds in the Terra Nova Bay Antarctica region. Successful forecast of the severe downslope zonda wind case in the lee of the highest peaks of the Andes is also shown, and some of the recent successful verification results of the use of the upgraded model are pointed out. The code is used at numerous places, and along with setup information it is available for outside users at the CPTEC Eta web site given above.     

The impact of health financing and CO<Subscript>2</Subscript> emission on health outcomes in Sub-Saharan Africa: A cross-country analysis

The current paper examines the relationship between health financing (public and out-of-pocket health financing), CO₂ emission and health outcomes in 35 Sub-Saharan African countries for the period of 1995–2012. The panel unit root and cointegration tests are conducted as pre-tests, followed by the estimation of the parameters using the FM-OLS and DOLS techniques. The findings of the study show the importance of public health financing as one of the major factors that lead to better health outcomes, whereas the out-of-pocket expenditure is found to be harmful to population health since it leads to increase under-5 mortality rate. Although the results show a negative relationship between CO₂ and health outcomes, still these results remain inclusive. In addition, the findings reveal the importance of socioeconomic factors such as income and education as key determinants of health outcomes.     

Groundwater management by riverbank filtration and an infiltration channel: the case of Obrenovac, Serbia

The Vi? Bare groundwater source is used to supply water to the population and industry of Obrenovac, one of the municipalities of Belgrade (the capital of Serbia). It is a typical riverbank filtration site; exploitation is performed through 30 drilled wells and two radial wells located in the meander of the Sava River. The established hydraulic connection between the river and tapped aquifer is so great that the river regime has a dominant influence on the aquifer. As a consequence of this, water-delivery reduction occurs in the dry months (summer–autumn), when the population needs water the most. Based on the data associated with the river’s gauges, precipitation, quantity of pumped water and groundwater-level fluctuation, a simulation of the groundwater regime for non-steady-state flow conditions has been undertaken through a numerical model. To overcome problems of water shortage during the dry season, the possibility of artificial recharge using an infiltration channel, made up of two connected parts, was analyzed. During the dry months, 80 % of the wells receive water partly from the infiltration channel. In this way, possibilities for extracting additional water are created. The application of this concept is discussed.