Attenuation of landfill leachate at two uncontrolled landfills

Attenuation characteristics of landfill leachate were examined for two uncontrolled landfills in Korea. The two landfills containing municipal wastes without appropriate bottom liner and leachate treatment system have different landfill age, waste volume, and most importantly different hydrogeologic settings. One landfill (Cheonan landfill) is situated in an open flat area while the other (Wonju landfill) is located in a valley. Variations of various parameters including dissolved organic carbon (DOC), dissolved oxygen (DO), alkalinity, pH, electrical conductivity (EC), redox potential (ORP), ammonia (NH₃), nitrate (NO₃⁻), sulfate (SO₄²⁻), and chloride (Cl⁻) were examined along groundwater flow path. All these parameters were analyzed every month for a year. In the interior of the landfills, typical anaerobic conditions revealed by low DO and NO₃ concentrations, negative ORP values, high NH₃, alkalinity, and Cl⁻ concentrations were observed. Generally, higher levels of contaminants (DOC, NH₃, and Cl⁻) were detected in the dry season while they were greatly lowered in the wet season. Significantly, large decrease of Cl^- concentration in the wet season indicates that the dilution or mixing is one of dominant attenuation mechanisms of leachate. But detailed variation behaviors in the two landfills are different and they were largely dependent on permeability of surface and subsurface layers. The intermediately permeable surface of the landfills receives part of direct rainfall infiltration but most rainwater is lost to fast runoff. The practically impermeable surface of clayey silt (paddy field) at immediately adjacent to the Cheonan landfill boundary prevented direct rainwater infiltration and hence redox condition of the ground waters were largely affected by that of the upper landfill and the less permeable materials beneath the paddy fields prohibited dispersion of the landfill leachate into down gradient area. In the Wonju landfill, there are three different permeability divisions, the landfill region, the sandy open field and the paddy field. Roles of the landfill and paddy regions are very similar to those at the Cheonan. The very permeable sandy field receiving a large amount of rainwater infiltration plays a key role in controlling redox condition of the down gradient area and contaminant migration. This paper reports details of the attenuation and redox conditions of the landfill leachates at the two uncontrolled landfills.     

Unstable Climate Oscillations during the Late Holocene in the Eastern Bransfield Basin, Antarctic Peninsula

Core A9-EB2 from the eastern Bransfield Basin, Antarctic Peninsula, consists of pelagic (diatom ooze-clay couplets and bioturbated diatom ooze) and hemipelagic (bioturbated mud) sediments interbedded with turbidites (homogeneous mud and silt–clay couplets). The cyclic and laminated nature of these pelagic sediments represents alternation between the deposition of diatom-rich biogenic sediments and of terrigenous sediments. Sediment properties and geochemical data explain the contrasting lamination, with light layers being finer-grained and relatively rich in total organic carbon and biogenic silica content. Also, the high-resolution magnetic susceptibility (MS) variations highlight distinct features: high MS values coincide with clastic-rich sections and low MS values correspond to biogenic sections. The chronology developed for core A9-EB2 accounts for anomalous ages associated with turbidites and shows a linear sedimentation rate of approximately 87 cm/10³ yr, which is supported by an accumulation rate of 80 cm/10³ yr calculated from ²¹⁰Pb activity. The late Holocene records clearly identify Neoglacial events of the Little Ice Age (LIA) and Medieval Warm Period (MWP). Other unexplained climatic events comparable in duration and amplitude to the LIA and MWP events also appear in the MS record, suggesting intrinsically unstable climatic conditions during the late Holocene in the Bransfield Basin of Antarctic Peninsula.     

Oil prices and energy technology innovation: An empirical analysis

To achieve environmental sustainability and reduce their vulnerability to oil shocks, countries can develop new energy technologies. Technological advances reduce the cost of structural changes in the energy economy, and thus also increase the political feasibility of such changes. But what explains international variation in the form and quality of energy technology innovation? We build on previous theories and offer an integrated account: increasing oil prices reinforce existing sectoral innovation systems, both politically and economically, thus allowing public policymakers and private entrepreneurs to profitably invest in new energy technologies. We test this theoretical argument against data on public R&D expenditures and patents in the domain of renewable energy technology for industrialized countries from 1989 to 2007. We find strong support for the interactive hypothesis. Thus, we contribute to literatures on (i) domestic responses to international shocks, (ii) environmental sustainability and energy security, and (iii) the political economy of technology innovation.     

Simulation of the extreme waves generated by typhoon Bolaven (1215) in the East China Sea and Yellow Sea

Record-breaking high waves occurred during the passage of the typhoon Bolaven (1215) (TYB) in the East China Sea (ECS) and Yellow Sea (YS) although its intensity did not reach the level of a super typhoon. Winds and directional wave measurements were made using a range of in-situ instruments mounted on an ocean tower and buoys. In order to understand how such high waves with long duration occurred, analyses have been made through measurement and numerical simulations. TYB winds were generated using the TC96 typhoon wind model with the best track data calibrated with the measurements. And then the wind fields were blended with the reanalyzed synoptic-scale wind fields for a wave model. Wave fields were simulated using WAM4.5 with adjustment of C_d for gust of winds and bottom friction for the study area. Thus the accuracy of simulations is considerably enhanced, and the computed results are also in better agreement with measured data than before. It is found that the extremely high waves evolved as a result of the superposition of distant large swells and high wind seas generated by strong winds from the front/right quadrant of the typhoon track. As the typhoon moved at a speed a little slower than the dominant wave group velocity in a consistent direction for two days, the wave growth was significantly enhanced by strong wind input in an extended fetch and non-linear interaction.     

Improvement of the K-profile Model for the Planetary Boundary Layer based on Large Eddy Simulation Data

Modifications of the widely used K-profile model of the planetary boundary layer (PBL), reported by Troen and Mahrt (TM) in 1986, are proposed and their effects examined by comparison with large eddy simulation (LES) data. The modifications involve three parts. First, the heat flux from the entrainment at the inversion layer is incorporated into the heat and momentum profiles, and it is used to predict the growth of the PBL directly. Second, profiles of the velocity scale and the Prandtl number in the PBL are proposed, in contrast to the constant values used in the TM model. Finally, non-local mixing of momentum was included. The results from the new PBL model and the original TM model are compared with LES data. The TM model was found to give too high PBL heights in the PBL with strong shear, and too low heights for the convection-dominated PBL, which causes unrealistic heat flux profiles. The new PBL model improves the predictability of the PBL height and produces profiles that are more realistic. Moreover, the new PBL model produces more realistic profiles of potential temperature and velocity. We also investigated how each of these three modifications affects the results, and found that explicit representation of the entrainment rate is the most critical.     

Soil temperatures in four metropolitan cities of Korea from 1960 to 2010: implications for climate change and urban heat

This study was conducted to reveal the trends of the air temperature and soil temperature for 51 years (1960–2010) and their relationship in four of Korea’s largest metropolitan cities (Seoul, Incheon, Busan and Daejeon). Also, the trends of the air and soil temperatures between the studied metropolitan cities and a rural area (Chupungryong) were compared to examine the effect of urban heat. Among the metropolitan cities, the long-term mean soil temperatures (depth 0.0, 0.5, 1.0, 1.5, 3.0, 5.0 m) were lowest (13.34–14.80 °C) in Seoul and highest (16.24–16.54 °C) in Busan, which is mainly the effect of the latitude. The soil temperature exponentially increased with depth in the three cities except for Busan and was closely related to the air temperature. The soil temperatures responded well to the air temperature change (maximum correlation coefficients 0.88–0.98) but this response was slightly delayed with depth. The air and soil temperatures increased at the rates of 0.24–0.40 and 0.11–0.73 °C/decade, respectively, for the period. The increasing rate of the soil temperature was the largest in Daejeon as 0.39–0.73 °C/decade, which was almost 2–4 times greater than those of the other cities (0.11–0.40 °C/decade), and it rose with depth. The increase of the soil temperature was coincident with the increase of the air temperature, which indicates that the soil temperature was largely affected by the increasing of the air temperature. In contrast, the increase in air temperature in Chupungryong (0.06 °C/decade) was significantly lower than in the metropolitan cities. In addition, the increase of the soil temperature in the rural area (0.13 °C/decade) was also much lower than that in the inland cities (0.20–0.27 °C/decade) while it showed no substantial difference from that in the coastal cities (0.11–0.15 °C/decade). Therefore, it is inferred that the soil temperature of the metropolitan cities increased with the increase of the air temperature due to global warming as well as the anthropogenic urban heat.     

Experimental study on moisture evaporation of lime wastes and marine clay: implications for landfill storage management

A large quantity of by-product lime wastes with high water content produced from chemicals manufacturing processes has been stacked in an open area in Incheon, Korea. Highly alkaline leachate and fine dust emanating from the stacked lime wastes caused an environmental concern in the city. So evaporative drying and stabilization of the fine-grained wastes and use of the on site marine clay as a natural geomembrane liner using drying hardening were considered as a part of a landfill construction plan. Treatment of the lime wastes and marine clay was focused on maximizing the evaporative drying and the density. Evaporation experiments were conducted in field condition to understand evaporation characteristics and to evaluate actual evaporation rate of the lime wastes and marine clay. Local Class A pan evaporation data from a nearby weather station for last 30 years indicated that mean annual and monthly evaporations were 1,178.5 and 98.2 mm, respectively. Relative evaporations of the sludge lime, cake lime, and marine clay compared with the pan evaporation were 114.9, 61.9, and 119.0%, respectively. Estimates of annual evaporations from storage surfaces in the field based on the relative evaporation data were 1,353.6, 729.1, and 1,402.2 mm for the sludge lime, cake lime, and the marine clay, respectively. And annual net evaporations considering rainfall effect were estimated as between 879.9 and 1,082.9 mm for the lime sludge, between 473.9 and 583.3 mm for the lime cake, and between 981.5 and 1,191.9 mm for the marine clay. It was expected that the actual field evaporation rate would be varied with the moisture contents of the lime and the clay. Results of these experiments will provide useful implications for the drying behavior of the by-product lime and the marine clay and landfill or management plan of the storages.     

Sequential tracer tests for determining water seepage paths in a large rockfill dam, Nakdong River basin, Korea

The rockfill dam of this study has a clay core, filter zone, and sandy gravel shell, and it is located in the Nakdong River basin in Korea. Filling the reservoir began in August 1994 and it was full by April 1998. When the reservoir level was approximately 150 m, three settlement holes were found in the dam crest. To determine possible seepage paths and potential damaged areas within the rockfill dam, 15 tracer tests were performed during two periods. During the two test periods, six and nine tracer tests were conducted when the average water levels of the reservoir were 145 m and 142 m, respectively. Rhodamine WT (RWT) and bromide ion were used as tracers. For each test, 1800 to 4000 L of tracer solution were injected into the riprap for about 5 h. The 15 injection points were uniformly distributed from the right to left sides of the embankment and the two tracers were injected alternately. Tracer concentrations were monitored at 26 observation wells, which were divided into four groups by their geographical positions: right side of the crest, left side of the crest, right side of the dam toe, and left side of the dam toe. For each tracer test, more than 30 water samples were taken during a period of 96 h at each observation well. Based the breakthrough curves obtained from the sequential tracer tests, it was inferred that the most probable seepage paths and potential damaged area were in the left side of the crest (tongue wing zone) and, to a lesser extent, in the right side of the dam abutment.