Evidence for the loss of snow-deposited MSA to the interstitial gaseous phase in central Antarctic firn

We have examined several MSA (methanesulfonic acid) records from the upper 200 m of the Antarctic ice sheet and in particular the new Dome F profile. At all the four sites studied, concentration profiles exhibit similar patterns as a function of depth. They suggest that snow metamorphism and solid phase migration are responsible for a marked release of gaseous MSA to interstitial firn air as well as probably to the free atmosphere, in particular at extremely low accumulation sites. Snow acidity can also modify MSA concentration. It is proposed that, below the upper few metres where the communication with the free atmosphere is possible, gaseous MSA may remain in the firn layers and be entrapped later in air bubbles at pore close-off, i.e. when firn is transformed into ice. Chemical measurements on the firn core do not take into account the MSA released to the gaseous phase, but this fraction is measurable in ice samples. In spite of these alterations occurring in the firn layers, relative changes of the atmospheric MSA concentration in the past are probably still there deep within the Antarctic ice sheet. However, for glacial periods, different processes have to be considered in relation to modified aerosol properties.     

Impact of mercury emissions from incineration of automobile shredder residue in Japan

Mercury emissions from the incineration of automobile shredder residues (ASRs) were investigated. Continuous monitoring of elemental and reactive gaseous Hg in flue gas was performed in lab-scale and plant-scale ASR incineration. Results of continuous monitoring agreed with those obtained using the JIS K0222 method and Ontario-Hydro method. Before cleaning by air pollutant control devices (APCDs), reactive Hg was the dominant form of that element in both lab-scale and plant-scale results. Emission factors of reactive Hg before APCDs estimated from monitoring results showed large differences between plant-scale and lab-scale emissions. The emission factor in the plant scale was more than 10 times larger than that in the lab-scale, which is explainable by the different Hg contents of ASR. Based on plant-scale monitoring at the stack, emission factors after APCDs were estimated as 0.79 mg-Hg/Mg-ASR for elemental Hg and 6.8 mg-Hg/Mg-ASR for reactive Hg. Using these emission factors, total Hg emissions from ASR incineration were estimated as 2.2 kg/a. An ASR incineration plant investigated in this study used highly effective APCDs. Consequently, these emission factors might result in underestimation of national Hg emissions from ASR incineration. Emission factors estimated from lab-scale monitoring at a fabric filter outlet side might be more appropriate. However, even if emission factors calculated from plant-scale or the lab-scale monitoring are used, estimated emissions are still less than 1.0% of total Hg emissions in Japan. Therefore, Hg emissions from ASR incineration can be evaluated as insignificant. Unless Hg contents of ASR increase extremely, ASR incineration would be a minor source of Hg atmospheric emission in Japan, even if all ASRs were incinerated.     

日本(虫寻)和底栖短桨蟹线粒体DNA 12SrRNA基因序列的初步研究

以相应引物对日本和底栖短桨蟹的线粒体 DNA1 2 S r RNA基因片段进行了 PCR扩增和序列测定 ,分析比较了 2种间序列差异。结果表明 :日本 1 2 S r RNA基因片段长度为 41 4 bp,底栖短桨蟹为 41 5bp,2种的 A,T,G,C含量分别为 1 51 bp(36.47% ) ,1 53bp(36.96% ) ,43bp(1 0 .39% ) ,67bp(1 6.1 8% )和 1 50 bp(36.1 4 % ) ,1 55bp(37.35% ) ,44bp(1 0 .60 % ) ,66bp(1 5.90 % )。 2种间共出现了 3个碱基的缺失 /插入和 38bp的序列差异 ,其碱基转换与碱基颠换比约为 2 .1 7。     

Sio Guyot: A complex volcanic edifice in the western Mid-Pacific Mountains

Sio Guyot, in the westernmost edge of the Mid-Pacific Mountains, is a large, complex volcanic edifice rising to more than 1200 m below sea level. The summit is divided into two flat-topped areas by a WNW-trending sediment-filled trough. Seismic reflection profiles reveal three acoustic units: an upper transparent layer (pelagic cap), a lower opaque layer (reef- and lagoon-derived sediments), and an acoustic (volcanic) basement. Free-air gravity anomalies indicate three eruptive centers or conduits within the main edifice, which apparently was constructed during late Cretaceous time on a broad basement swell or plateau that today is more than 3400 m below sea level (1500 m above regional abyssal depths).     

Scattering of Semidiurnal Internal Kelvin Wave at Step Bottom Topography

A three-dimensional, multi-level model was used to study the energy dissipation of semidiurnal internal Kelvin waves due to their interaction with bottom topography. A simplified topography consisting of a channel with an additional shallow bay was used to clarify the wave’s scattering process. When the first mode semidiurnal internal wave given at an open boundary arrives at the bay mouth, higher-mode internal waves are generated at a step bottom of the bay mouth. As a result, the energy of the first mode internal Kelvin wave is effectively decayed. The decay rate of the internal Kelvin wave depends on both the width and length of the additional bay. The maximum decay rate was found when a resonance condition occurs the bay, that is, the bay length is equal to a quarter of wave length of the first mode internal wave on the shallow region. The decay rate in the wide bay cases is higher than that in a narrow case, due to a contribution from the scattering due to the Poincare wave that emanates from the corners of the bay head. The decay rate with the additional bay is 1.1–1.8 times that of the case without the additional bay. The decay rate due to the scattering process is found to be of the same order as that of the internal and bottom friction.     

Branching and joining of the Tsushima Current around the Oki Islands

We discussed the branching and joining of the Tsushima Current around the Oki Islands, based on ADCP and CTD measurements carried out in June 1990 by the quadrireciprocal method (Katoh, 1988). The volume transport of the northeastward current northwest of the Izumo Coast was about 2 Sv. The triple-branch structure of the Tsushima Current was obscure there. This northeastward current divided into the eastward and northward currents, with volume transports of 0.5 Sv and 1.5 Sv, respectively, at the west entrance of the Oki Strait. Most of the first branch of the Tsushima Current seemed to be separated again from the other confluent branches and to pass through the Oki Strait as this eastward current. The northward current was composed of the second and the third branches of the Tsushima Current. It detoured the Oki Islands, and almost all of it returned south to the Tajima Coast. In the vicinity of the Tajima Coast, the eastward current was abruptly strengthened through the confluence of the southward one which was originated from the northward current west of the Oki Islands. This showed that the first branch finally joined the compound of the second and the third branches detouring the Oki Islands. Between the Oki Strait and the Tajima Coast, the two-layer structure of currents was clearly found.     

Effects of scattering and resonance on energy dissipation of an internal tide in a narrow shelf

The effects of scattering and resonance on the energy dissipation of an internal tide were investigated using a two-dimensional model which is a reassembled version of the theoretical generation model devised by Rattray et al. (1969) for internal tide. The basic character of the scattering process at the step bottom was first investigated with a wide shelf model. When the internal wave incited from a deep region (Region II) into the shallow shelf region (Region I), a passing wave into the shallow region, a reflected wave into the deep region, and a beam-like wave, i.e. a scattered wave (SW), emanated at the step bottom. The SW, which consists of the superposition of numerous internal modes, propagated upward/downward into both regions. The general properties of the SW were well expressed around the shelf edge, even in the present model with viscosity effect. The amplitude of the SW decreased dramatically when the depth of the velocity maximum of the incident internal wave in Region II corresponded with the depth of the shelf edge. In the narrow shelf model, where the decay distance of the internal wave in Region I is longer than the shelf width, the incident internal wave reflected at the coast to form a standing wave. When the internal wave in Region I is enhanced by the resonance, the energy of the SW in Region II is also intensified. Furthermore, the energy of the modes in Region II predominated when the velocity maximum is identical to that of the dominant mode in Region I. These results suggest that the spatial scale of shelf region is a very important factor governing the energy dissipation of the internal tide through reflection and scattering in a narrow shelf.     

Topographic Effect of Izu Ridge on the Distribution of the North Pacific Intermediate Water South of Japan

The topographic effect of the Izu Ridge on the horizontal distribution of the North Pacific Intermediate Water (NPIW) south of Japan has been studied using observational data obtained by the Seisui-Maru of Mie University (Mie Univ. data) and those compiled by Japan Oceanographic Data Center (JODC data). Both data sets show that water of salinity less than 34.1 psu on potential density () surface of 26.8 is confined to the eastern side of the Izu Ridge, while water of salinity less than 34.2 psu is confined to the southern area over the Izu Ridge at a depth greater than 2000 m and to the southeastern area in the Shikoku Basin. It is also shown by T-S analysis of Mie Univ. data over the Izu Ridge that water of salinity less than 34.2 psu dominates south of 30°N, where the depth of the Izu Ridge is deeper than 2000 m and NPIW can intrude westward over the Izu Ridge. JODC data reveal that relatively large standard deviations of the salinity on surface of 26.7, 26.8 and 26.9 are detected along the mean current path of the Kuroshio and the Kuroshio Extension. Almost all of the standard deviations are less than 0.05 psu in other area with the NPIW, which shows that the time variation in the salinity can be neglected. This observational evidence shows that the topographic effect of the Izu Ridge on the horizontal distribution of the NPIW, which is formed east of 145°E by the mixing of the Kuroshio water and the Oyashio water, is prominent north of 30°N with a depth shallower than 2000 m.