Clinoform growth and sediment flux into late Cenozoic Qiongdongnan shelf margin,South China Sea

The South China Sea continental margin in the Qiongdongnan Basin (QDNB) area has incrementally prograded since 10.5 Ma generating a margin sediment prism more than 4km-thick and 150–200 km wide above the well-dated T40 stratigraphic surface. Core and well log data, as well as clinoform morphology and growth patterns along 28 2D seismic reflection lines, illustrate the evolving architecture and margin morphology; through five main seismic-stratigraphic surfaces (T40, T30, T27, T20 and T0) frame 15 clinothems in the southwest that reduce over some 200 km to 8 clinoforms in the northeast. The overall margin geometry shows a remarkable change from sigmoidal, strongly progradational and aggradational in the west to weakly progradational in the east. Vertical sediment accumulation rate increased significantly across the entire margin after 2.4 Ma, with a marked increase in mud content in the succession. Furthermore, an estimate of sediment flux across successive clinoforms on each of the three selected seismic cross sections indicate an overall decrease in sediment discharge west to east, away from the Red River depocenter, as well as a decrease in the percentage of total discharge crossing the shelf break in this same direction. The QDNB Late Cenozoic continental margin growth, with its overall increased sediment flux, responded to the climate-induced, gradual cooling and falling global sea level during this icehouse period.     

Climatically controlled lacustrine clinoforms: Theory and modelling results

Lacustrine basins and their deposits are good paleoclimate recorders and contain rich energy resources. Shelf-margin clinoforms do exist in deep lacustrine basins, but with striking differences from those in deep marine basins, caused by a correlation between the river-derived sediment supply and the lake level. This study uses empirical relationships to calculate the water and sediment discharge from rivers and coeval lake level during wet–dry cycles at 10 s of ky time scale. Sediment supply and lake-level changes are used for a stratigraphic forward model to understand how lacustrine clinoforms develop under different climate conditions. The results show that both wet and dry cycles can be associated with thick deep-water fan deposits, supporting the existing climate-driven lacustrine model proposed based on field data (e.g. Neogene Pannonian Basin and Eocene Uinta Basin). The wet period with high sediment supply and rising lake level creates the highly aggradational shelf, progradational slope and thick bottomset deposits. This is contrary from marine basin settings where the presence of rising shelf-margin trajectory commonly indicates limited deep-water fan deposits. This work suggests marine-based stratigraphic models cannot be directly applied to lacustrine basins.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Time variation of earthquake activity in the Balkan region

Summary Three quantities M, E ^1/2 and E ^2/3 are used for studying the Balkan earthquake provinces. Most of them show a regular trend of activity, for some of them the observation period of 70 years is too short. Some graphs give evidence of the coincidence or migration of activity.     

Transition from storm wave‐dominated outer shelf to gullied upper slope: The mid‐Pliocene Orinoco shelf margin,South Trinidad

Shelf‐edge deltas are a key depositional environment for accreting sediment onto shelf‐margin clinoforms. The Moruga Formation, part of the palaeo‐Orinoco shelf‐margin sedimentary prism of south‐east Trinidad, provides new insight into the incremental growth of a Pliocene, storm wave‐dominated shelf margin. Relatively little is known about the mechanisms of sand bypass from the shelf‐break area of margins, and in particular from storm wave‐dominated margins which are generally characterized by drifting of sand along strike until meeting a canyon or channel. The studied St. Hilaire Siltstone and Trinity Hill Sandstone succession is 260 m thick and demonstrates a continuous transition from gullied (with turbidites) uppermost slope upward to storm wave‐dominated delta front on the outermost shelf. The basal upper‐slope deposits are dominantly mass‐transport deposited blocks, as well as associated turbidites and debrites with common soft‐sediment‐deformed strata. The overlying uppermost slope succession exhibits a spectacular set of gullies, which are separated by abundant slump‐scar unconformities (tops of rotational slides), then filled with debris‐flow conglomerates and sandy turbidite beds with interbedded mudstones. The top of the study succession, on the outer‐shelf area, contains repeated upward‐coarsening, sandstone‐rich parasequences (2 to 15 m thick) with abundant hummocky and swaley cross‐stratification, clear evidence of storm‐swell and storm wave‐dominated conditions. The observations suggest reconstruction of the unstable shelf margin as follows: (i) the aggradational storm wave‐dominated, shelf‐edge delta front became unstable and collapsed down the slope; (ii) the excavated scars of the shelf margin became gullied, but gradually healed (aggraded) by repeated infilling by debris flows and turbidites, and then new gullying and further infilling; and (iii) a renewed storm wave‐dominated delta‐front prograded out across the healed outer shelf, re‐establishing the newly stabilized shelf margin. The Moruga Formation study, along with only a few others in the literature, confirms the sediment bypass ability of storm wave‐dominated reaches of shelf edges, despite river‐dominated deltas being, by far, the most efficient shelf‐edge regime for sediment bypass at the shelf break.     

Submarine hydrothermal activity and gold-rich mineralization at Brothers Volcano, Kermadec Arc, New Zealand

Brothers volcano, of the Kermadec intraoceanic arc, is host to a hydrothermal system unique among seafloor hydrothermal systems known anywhere in the world. It has two distinct vent fields, known as the NW Caldera and Cone sites, whose geology, permeability, vent fluid compositions, mineralogy, and ore-forming conditions are in stark contrast to each other. The NW Caldera site strikes for ??600?m in a SW?CNE direction with chimneys occurring over a ??145-m depth interval, between ??1,690 and 1,545?m. At least 100 dead and active sulfide chimney spires occur in this field and are typically 2?C3?m in height, with some reaching 6?C7?m. Their ages (at time of sampling) fall broadly into three groups: <4, 23, and 35?years old. The chimneys typically occur near the base of individual fault-controlled benches on the caldera wall, striking in lines orthogonal to the slopes. Rarer are massive sulfide crusts 2?C3?m thick. Two main types of chimney predominate: Cu-rich (up to 28.5?wt.% Cu) and, more commonly, Zn-rich (up to 43.8?wt.% Zn). Geochemical results show that Mo, Bi, Co, Se, Sn, and Au (up to 91?ppm) are correlated with the Cu mineralization, whereas Cd, Hg, Sb, Ag, and As are associated with the dominant Zn-rich mineralization. The Cone site comprises the Upper Cone site atop the summit of the recent (main) dacite cone and the Lower Cone site that straddles the summit of an older, smaller, more degraded dacite cone on the NE flank of the main cone. Huge volumes of diffuse venting are seen at the Lower Cone site, in contrast to venting at both the Upper Cone and NW Caldera sites. Individual vents are marked by low-relief (??0.5?m) mounds comprising predominately native sulfur with bacterial mats. Vent fluids of the NW Caldera field are focused, hot (??300°C), acidic (pH????2.8), metal-rich, and gas-poor. Calculated end-member fluids from NW Caldera vents indicate that phase separation has occurred, with Cl values ranging from 93% to 137% of seawater values. By contrast, vent fluids at the Cone site are diffuse, noticeably cooler (??122°C), more acidic (pH?1.9), metal-poor, and gas-rich. Higher-than-seawater values of SO₄ and Mg in the Cone vent fluids show that these ions are being added to the hydrothermal fluid and are not being depleted via normal water/rock interactions. Iron oxide crusts 3?years in age cover the main cone summit and appear to have formed from Fe-rich brines. Evidence for magmatic contributions to the hydrothermal system at Brothers includes: high concentrations of dissolved CO₂ (e.g., 206?mM/kg at the Cone site); high CO₂/³He; negative ??D and ??¹⁸O_H2O for vent fluids; negative ??³⁴S for sulfides (to ?4.6??), sulfur (to ?10.2??), and ??¹⁵N₂ (to ?3.5??); vent fluid pH values to 1.9; and mineral assemblages common to high-sulfidation systems. Changing physicochemical conditions at the Brothers hydrothermal system, and especially the Cone site, occur over periods of months to hundreds of years, as shown by interlayered Cu?+?Au- and Zn-rich zones in chimneys, variable fluid and isotopic compositions, similar shifts in ³He/⁴He values for both Cone and NW Caldera sites, and overprinting of ??magmatic?? mineral assemblages by water/rock-dominated assemblages. Metals, especially Cu and possibly Au, may be entering the hydrothermal system via the dissolution of metal-rich glasses. They are then transported rapidly up into the system via magmatic volatiles utilizing vertical (??2.5?km long), narrow (??300-m diameter) ??pipes,?? consistent with evidence of vent fluids forming at relatively shallow depths. The NW Caldera and Cone sites are considered to represent stages along a continuum between water/rock- and magmatic/hydrothermal-dominated end-members.     

Architecture and recognition criteria of ancient shelf ridges; an example from Campanian Almond Formation in Hanna Basin,USA

Shelf ridges are sedimentary bodies formed on the continental shelf due to transgressive reworking (tidal or storm) of lowstand deposits. Common on modern shelves, they are under‐represented in the geological record due to a lack of recognition criteria and facies model. This article proposes a new facies and architectural model for shelf ridges, linked to their inception–evolution–abandonment cycle and the process regime of the basin. The model is mainly based on new outcrop data and interpretations from three sandstone bodies of the Almond Formation, an overall transgressive interval during the infill of the Campanian Western Interior Seaway. Building from the case study, and ancient and modern examples, six characteristics are proposed for the recognition of ancient shelf ridges. Shelf ridges: (i) are encased between thick marine mudstone intervals; (ii) have a basal unconformity that erodes into marine muds or into the remnants of a previous shoreline; (iii) have a non‐erosional upper boundary that transitions into marine muds; (iv) are characterized by clean and well‐sorted sandstones, often cross‐bedded; (v) contain fully marine ichnofauna; and (vi) present compound architectures with large accretion surfaces and lower order structures. Although shelf ridges have been described in previous studies as generated exclusively by either tidal or storm currents, it is clear, from modern examples and the case study, that these two processes can be recorded and preserved in a single shelf ridge. The stratigraphy of these sandstone bodies is therefore much more complex than previously recognized, bearing the signature of changing tidal and storm intensity through time. Because they are developed during transgressions, shelf ridges are commonly subject to strong changes in process regime as sea‐level changes can easily affect the oceanographic conditions and the morphology of the basin. For this reason, shelf ridges can provide the best record of shelf process variability during transgressions.     

Thermohaline convection in flowing groundwater

Geothermal activity creates destabilising temperature gradients which are significant in some aquifers. Usually, in such aquifers stabilising salinity gradients also exist. The combination of temperature and salinity distribution in the aquifer may induce various types of hydrodynamic instabilities which were identified in a previous article. The present article concerns the effect of anisotropic characteristics of the hydrodynamic dispersion on the growth of instabilities in the aquifer. Three different mechanisms may lead to instability of the flow field: (a) buoyancy forces may induce convection currents; if the difference between the convection velocity of salt, due to the hydraulic gradients, and that of heat is negligible, then this mechanism is generally most effective in planes parallel to the hydraulic velocity of the fluid (velocity due to the hydraulic gradient); (b) the difference between heat and salt effective diffusivities may lead to overstability; this mechanism is most effective in planes perpendicular to the hydraulic velocity; (c) the difference between the convection velocity of salt and that of heat may induce oscillations which are most effective in planes parallel to the hydraulic velocity. The growth of instabilities in an aquifer of unlimited length is different from their growth in an aquifer of limited length. In the latter thermohaline convection develops in planes perpendicular to the hydraulic velocity, whereas in the former it develops in planes forming an angle θ with the hydraulic gradient. The development of convection cells in the flow field is identified by numerical experiments. These experiments identify the convection cell length and the angle formed between the thermohaline convection plane and the hydraulic gradient.     

Provenance of Oligocene lithic and quartz arenites of the East Carpathians: Understanding sediment routing systems on compressional basin margins

We present new sedimentological, petrographical, palaeontological and detrital zircon U–Pb data on late Oligocene–early Miocene sedimentary rocks of the thin-skinned thrust belt of East Carpathians. These data were acquired to reconstruct the sedimentary routing system for two compositionally different turbidite fans made of the regionally extensive Kliwa and Fusaru formations. On the eastern margin of the Moldavides foreland basin, large low-gradient river systems draining the East European Platform provided well-sorted quartz-rich sand forming deltas on wide shallow shelves and thick Kliwa submarine fans. Due to the westward subduction of a thinned continental plate, the western basin margin was characterized by short, steep-gradient routing systems where sediment transport to deep water was mainly through hyperpycnal flows. The Getic and Bucovinian nappes of the East Carpathians and the exhumed Cretaceous–Early Palaeogene orogenic wedge fed Fusaru fans with poorly sorted lithic sand. The Fusaru fans trend northwards in the foredeep basin having an elongate depocentre, interfingering and then overlapping on the distal part of the Kliwa depositional system due to the eastward advance of the Carpathian fold-and-thrust belt. A smaller sediment input is supplied by southern continental areas (i.e. Moesian Platform, North Dobrogea and potentially the Balkans). In general, the sandstone interfingering between distinct basin floor fan systems is less well documented because the facies would be similar and there are not many systems that have a distinct sediment provenance like Kliwa and Fusaru systems. This case study improves the understanding of regional palaeogeography and sedimentary routing systems and provides observations relevant here or elsewhere on the interfingering turbidite fan systems.